Search Results - "Wilson, David J. D."

The Tandem Photoredox Catalysis Mechanism of [Ir(ppy)2(dtb-bpy)]+ Enabling Access to Energy Demanding Organic Substrates by Connell, Timothy U, Fraser, Catherine L, Czyz, Milena L, Smith, Zoe M, Hayne, David J, Doeven, Egan H, Agugiaro, Johnny, Wilson, David J. D, Adcock, Jacqui L, Scully, Andrew D, Gómez, Daniel E, Barnett, Neil W, Polyzos, Anastasios, Francis, Paul S

“…We report the discovery of a tandem catalytic process to reduce energy demanding substrates, using the [Ir­(ppy)2(dtb-bpy)]+ (1 + ) photocatalyst. The…”
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A conceptual framework for the development of iridium() complex-based electrogenerated chemiluminescence labels by Chen, Lifen, Hayne, David J, Doeven, Egan H, Agugiaro, Johnny, Wilson, David J. D, Henderson, Luke C, Connell, Timothy U, Nai, Yi Heng, Alexander, Richard, Carrara, Serena, Hogan, Conor F, Donnelly, Paul S, Francis, Paul S

“…Translation of the highly promising electrogenerated chemiluminescence (ECL) properties of Ir( iii ) complexes (with tri- n -propylamine (TPrA) as a…”
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Are N-Heterocyclic Carbenes “Better” Ligands than Phosphines in Main Group Chemistry? A Theoretical Case Study of Ligand-Stabilized E2 Molecules, L-E-E-L (L = NHC, phosphine; E = C, Si, Ge, Sn, Pb, N, P, As, Sb, Bi) by Wilson, David J. D, Couchman, Shannon A, Dutton, Jason L

“…A theoretical examination of the L-E-E-L class of molecules has been carried out (E = group 14, group 15 element; L = N-heterocyclic carbene, phosphine), for…”
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Air-Stable Thermoluminescent Carbodicarbene-Borafluorenium Ions by Hollister, Kimberly K, Molino, Andrew, Breiner, Grace, Walley, Jacob E, Wentz, Kelsie E, Conley, Ashley M, Dickie, Diane A, Wilson, David J. D, Gilliard, Robert J

“…Borenium ions, originally synthesized as fundamentally important laboratory curiosities, have attracted significant attention due to their applications in…”
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Heterobimetallic N‑Heterocyclic Carbene Complexes: A Synthetic, Spectroscopic, and Theoretical Study by Pell, Thomas P, Wilson, David J. D, Skelton, Brian W, Dutton, Jason L, Barnard, Peter J

“…A new synthetic methodology has been developed for the preparation of heterobimetallic group 11 and group 12 complexes of a symmetrical bis-NHC “pincer”…”
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Electrochemiluminescent Ruthenium(II) N‑Heterocyclic Carbene Complexes: a Combined Experimental and Theoretical Study by Barbante, Gregory J, Francis, Paul S, Hogan, Conor F, Kheradmand, Peyman R, Wilson, David J. D, Barnard, Peter J

“…A series of four Ru(II) complexes of the form [Ru(bpy)2(C∧N)]2+ (where C∧N is a bidentate pyridine-functionalized imidazolylidene- or benzimidazolylidene-based…”
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Understanding Electrogenerated Chemiluminescence Efficiency in Blue-Shifted Iridium(III)-Complexes: An Experimental and Theoretical Study by Barbante, Gregory J., Doeven, Egan H., Kerr, Emily, Connell, Timothy U., Donnelly, Paul S., White, Jonathan M., Lópes, Thais, Laird, Sarah, Wilson, David J. D., Barnard, Peter J., Hogan, Conor F., Francis, Paul S.

“…Compared to tris(2‐phenylpyridine)iridium(III) ([Ir(ppy)3]), iridium(III) complexes containing difluorophenylpyridine (df‐ppy) and/or an ancillary…”
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The Fate of NHC-Stabilized Dicarbon by Georgiou, Dayne C., Stringer, Bradley D., Hogan, Conor F., Barnard, Peter J., Wilson, David J. D., Holzmann, Nicole, Frenking, Gernot, Dutton, Jason L.

“…The attempted synthesis of NHC‐stabilized dicarbon (NHCCCNHC) through deprotonation of a doubly protonated precursor ([NHCCHCHNHC]2+) is reported. Rather…”
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Access to the Parent Tetrakis(pyridine)gold(III) Trication, Facile Formation of Rare Au(III) Terminal Hydroxides, and Preliminary Studies of Biological Properties by Corbo, Robert, Ryan, Gemma F, Haghighatbin, Mohammad A, Hogan, Conor F, Wilson, David J. D, Hulett, Mark D, Barnard, Peter J, Dutton, Jason L

“…In this paper we report on the use of [NO]­[BF4] to access tricationic tetrakis­(pyridine)­gold­(III) from Au powder, a species inaccessible using the more…”
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Persistent Borafluorene Radicals by Yang, Wenlong, Krantz, Kelsie E., Freeman, Lucas A., Dickie, Diane A., Molino, Andrew, Frenking, Gernot, Pan, Sudip, Wilson, David J. D., Gilliard, Robert J.

“…N‐Heterocyclic carbene (NHC)‐ and cyclic (alkyl)(amino)carbene (CAAC)‐stabilized borafluorene radicals have been isolated and characterized by elemental…”
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Do Double-Hybrid Exchange–Correlation Functionals Provide Accurate Chemical Shifts? A Benchmark Assessment for Proton NMR by de Oliveira, Marcelo T, Alves, Júlia M. A, Braga, Ataualpa A. C, Wilson, David J. D, Barboza, Cristina A

“…A benchmark density functional theory (DFT) study of 1H NMR chemical shifts for data sets comprising 200 chemical shifts, including complex natural products,…”
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Reactions of 9‑Carbene-9-Borafluorene Monoanion and Selenium: Synthesis of Boryl-Substituted Selenides and Diselenides by Wentz, Kelsie E, Molino, Andrew, Freeman, Lucas A, Dickie, Diane A, Wilson, David J. D, Gilliard, Robert J

“…Reactions of 9-carbene-9-borafluorene monoanion (1) with elemental selenium and selenium-containing reagents are reported. When compound 1 is reacted with grey…”
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Unusually Strong Electrochemiluminescence from Iridium-Based Redox Polymers Immobilized As Thin Layers or Polymer Nanoparticles by Carrara, Serena, Stringer, Bradley, Shokouhi, Alireza, Ramkissoon, Pria, Agugiaro, Johnny, Wilson, David J. D, Barnard, Peter J, Hogan, Conor F

“…A new class of redox metallopolymer based on cyclometalated iridium­(III) centers is described, with unusually intense luminescence properties in aqueous…”
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Thiols as Hydrogen Bond Acceptors and Donors: Spectroscopy of 2‑Phenylethanethiol Complexes by Lobo, Isabella A, Robertson, Patrick A, Villani, Luigi, Wilson, David J. D, Robertson, Evan G

“…Evidence and understanding of sulfur-centered hydrogen bonding, especially where the donor is a thiol, lags far behind that for conventional OH interactions…”
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Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic “Switch” Based on Boron–Oxygen Interactions by Yang, Wenlong, Krantz, Kelsie E., Freeman, Lucas A., Dickie, Diane A., Molino, Andrew, Kaur, Aishvaryadeep, Wilson, David J. D., Gilliard, Robert J.

“…The first examples of N‐heterocyclic carbene (NHC) and cyclic(alkyl)(amino) carbene (CAAC) stabilized borepinium and borafluorenium heterocycles are reported…”
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Evaluation of the σ‑Donating and π‑Accepting Properties of N‑Heterocyclic Boryl Anions by Romeo, Lorenzo J, Kaur, Aishvaryadeep, Wilson, David J. D, Martin, Caleb D, Dutton, Jason L

“…The relative σ-donating and π-accepting capacities of a range of synthetically relevant boryl anions have been evaluated by examining the geometric,…”
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Stepwise Reduction at Magnesium and Beryllium: Cooperative Effects of Carbenes with Redox Non-Innocent α‑Diimines by Freeman, Lucas A, Walley, Jacob E, Obi, Akachukwu D, Wang, Guocang, Dickie, Diane A, Molino, Andrew, Wilson, David J. D, Gilliard, Robert J

“…In the past two decades, the organometallic chemistry of the alkaline earth elements has experienced a renaissance due in part to developments in ligand…”
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Reactions of Imines, Nitriles, and Isocyanides with Pentaphenylborole: Coordination, Ring Expansion, C–H Bond Activation, and Hydrogen Migration Reactions by Huang, Kexuan, Couchman, Shannon A, Wilson, David J. D, Dutton, Jason L, Martin, Caleb D

“…The reactions of pentaphenylborole with imines, isocyanides, and acetonitrile were investigated experimentally and theoretically. On the basis of literature…”
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Recent Advances in the Field of Main-Group Mono- and Diatomic "Allotropes" Stabilised by Neutral Ligands by Wilson, David J. D., Dutton, Jason L.

“…The study of ligand stabilised mono‐ and diatomic zero oxidation state complexes is a young and fascinating topic. This area merges the fields of…”
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Photochemically and Thermally Generated BN-Doped Borafluorenate Heterocycles via Intramolecular Staudinger-Type Reactions by Tra, Bi Youan E., Molino, Andrew, Hollister, Kimberly K., Sarkar, Samir Kumar, Dickie, Diane A., Wilson, David J. D., Gilliard, Robert J.

“…A series of BN-incorporated borafluorenate heterocycles, bis­(borafluorene-phosphinimine)­s (11–15), have been formed via intramolecular Staudinger-type…”
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