Search Results - "Wildermuth, Raphael"

9‐Membered Carbocycles: Strategies and Tactics for their Synthesis by Huber, Tatjana, Wildermuth, Raphael E., Magauer, Thomas

“…Many natural products comprising a nine‐membered carbocyclic core structure exhibit interesting biological effects. However, only a minority have succumbed to…”
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Total Synthesis of (+)‐Cornexistin by Steinborn, Christian, Wildermuth, Raphael E., Barber, David M., Magauer, Thomas

“…Herein, we describe the first total synthesis of (+)‐cornexistin as well as its 8‐epi‐isomer starting from malic acid. The robust and scalable route features a…”
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Convergent Assembly of the Tetracyclic Meroterpenoid (−)-Cyclosmenospongine by a Non-Biomimetic Polyene Cyclization by Speck, Klaus, Wildermuth, Raphael, Magauer, Thomas

“…The cationic cyclization of polyenes constitutes a powerful and elegant transformation, which has been utilized by nature's biosynthetic machinery for the…”
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Frontispiece: 9‐Membered Carbocycles: Strategies and Tactics for their Synthesis by Huber, Tatjana, Wildermuth, Raphael E., Magauer, Thomas

“…The frontispiece shows a map of the small Italian town Palmanova in the 17th century. Palmanova was built up by the Venetians in 1593 as a fortress and has the…”
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Evolution of a Strategy for the Total Synthesis of (+)‐Cornexistin by Wildermuth, Raphael E., Steinborn, Christian, Barber, David M., Mühlfenzl, Kim S., Kendlbacher, Mario, Mayer, Peter, Wurst, Klaus, Magauer, Thomas

“…Herein is given a full account of the evolution of the first total synthesis of (+)‐cornexistin. Initial efforts were based on masking the reactive maleic…”
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A modular synthesis of tetracyclic meroterpenoid antibiotics by Wildermuth, Raphael, Speck, Klaus, Haut, Franz-Lucas, Mayer, Peter, Karge, Bianka, Brönstrup, Mark, Magauer, Thomas

“…Stachyflin, aureol, smenoqualone, strongylin A, and cyclosmenospongine belong to a family of tetracyclic meroterpenoids, which, by nature of their unique…”
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Total Synthesis of (+)‐Cornexistin by Steinborn, Christian, Wildermuth, Raphael E., Barber, David M., Magauer, Thomas

“…Herein, we describe the first total synthesis of (+)‐cornexistin as well as its 8‐epi‐isomer starting from malic acid. The robust and scalable route features a…”
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Convergent Assembly of the Tetracyclic Meroterpenoid (−)-Cyclosmenospongine by a Non-Biomimetic Polyene Cyclization by Speck, Klaus, Wildermuth, Raphael, Magauer, Thomas

“…The cationic cyclization of polyenes constitutes a powerful and elegant transformation, which has been utilized by nature's biosynthetic machinery for the…”
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A Negishi cross-coupling reaction enables the total synthesis of (+)-stachyflin by Haut, Franz-Lucas, Speck, Klaus, Wildermuth, Raphael, Möller, Kristof, Mayer, Peter, Magauer, Thomas

“…We present a full account on the development of the total synthesis of the antiviral meroterpenoid (+)-stachyflin. The decalin subunit is rapidly accessed by…”
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