Search Results - "Wilcox, Craig S"

Minimal Protein Folding Model To Measure Hydrophobic and CH-π Effects on Interactions between Nonpolar Surfaces in Water by Bhayana, Brijesh, Wilcox, Craig S

“…In the balance: A synthetic molecule that exhibits two‐state folding behavior in water is described. Quantitative experiments reveal that the microscopic…”
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Synthesis of Dibenzazepinones by Palladium-Catalyzed Intramolecular Arylation of o-(2′-Bromophenyl)anilide Enolates by Pan, Xiaohong, Wilcox, Craig S

“…A new approach for the convenient synthesis of dibenzazepinones is reported. The key step is the formation of the seven-membered ring through…”
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Photonic Crystal Carbohydrate Sensors:  Low Ionic Strength Sugar Sensing by Asher, Sanford A, Alexeev, Vladimir L, Goponenko, Alexander V, Sharma, Anjal C, Lednev, Igor K, Wilcox, Craig S, Finegold, David N

“…We developed a carbohydrate sensing material, which consists of a crystalline colloidal array (CCA) incorporated into a polyacrylamide hydrogel (PCCA) with…”
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High Ionic Strength Glucose-Sensing Photonic Crystal by Alexeev, Vladimir L, Sharma, Anjal C, Goponenko, Alexander V, Das, Sasmita, Lednev, Igor K, Wilcox, Craig S, Finegold, David N, Asher, Sanford A

“…We demonstrate a colorimetric glucose recognition material consisting of a crystalline colloidal array embedded within a polyacrylamide−poly(ethylene glycol)…”
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Total Synthesis of a 28-Member Stereoisomer Library of Murisolins by Curran, Dennis P, Zhang, Qisheng, Richard, Cyrille, Lu, Hejun, Gudipati, Venugopal, Wilcox, Craig S

“…Total syntheses of two 16-member libraries of murisolin isomers are reported. In the first library, fluorous PMB (p-methoxybenzyl) groups encode…”
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A Molecular Torsion Balance Study: A Nearby Anionic Group Exerts Little Influence on Hydrophobic Interactions between Nonpolar Surfaces by Ling, Xiujun, Wilcox, Craig S.

“…Polar groups have a solvent ordering effect on water and therefore may affect hydrophobic binding energies for nearby lipophilic surfaces. This would mean that…”
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Asymmetric solution-phase mixture aldol reaction using oligomeric ethylene glycol tagged chiral oxazolidinones by Turkyilmaz, Serhan, Wilcox, Craig S.

“…[Display omitted] •Oligomeric ethylene glycol (OEG) derivatives act as chromatographic sorting tags.•Chiral oxazolidinones tagged with OEGs of varying length…”
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Synthesis and NMR Analysis of a Conformationally Controlled β‑Turn Mimetic Torsion Balance by Lypson, Alyssa B, Wilcox, Craig S

“…The molecular torsion balance concept was applied to a new conformationally controlled scaffold and synthesized to accurately evaluate pairwise amino acid…”
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Measurements of Molecular Electrostatic Field Effects in Edge-to-Face Aromatic Interactions and CH-π Interactions with Implications for Protein Folding and Molecular Recognition by Kim, Eun-il, Paliwal, Sunil, Wilcox, Craig S

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Design and Synthesis of a Novel Cyclophane as Host for Aryl Phosphate by Miyake, Muneharu, S. Wilcox, Craig

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Rotational Isomers of N‑Methyl‑N‑arylacetamides and Their Derived Enolates: Implications for Asymmetric Hartwig Oxindole Cyclizations by Mandel, Jérémie, Pan, Xiaohong, Hay, E. Ben, Geib, Steven J, Wilcox, Craig S, Curran, Dennis P

“…The rotational preferences of N-(2-bromo-4,6-dimethylphenyl)-N-methyl 2-phenylpropanamide were studied as a model of precursors for Hartwig asymmetric oxindole…”
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A Mild Synthesis of Unsymmetrical Bisalkoxysilanes through Catalyzed Alcoholysis of Hydridosilanes Containing C−C Multiple Bonds and Aryl Halides by Scott, Colleen N, Wilcox, Craig S

“…The synthesis of unsymmetrical bisalkoxysilanes containing unsaturated C−C bonds and alkyl and aryl bromides has been developed. This method is a modification…”
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Benzil-Tethered Precipitons for Controlling Solubility:  A Round-Trip Energy-Transfer Mechanism in the Isomerization of Extended Stilbene Analogues by Ams, Mark R, Wilcox, Craig S

“…We are investigating photoresponsive molecules called “precipitons” that undergo a solubility change co-incident with isomerization. Isomerization can be…”
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Chemistry of synthetic receptors and functional group arrays. 16. Enantioselective and diastereoselective molecular recognition of alicyclic substrates in aqueous media by a chiral, resolved synthetic receptor by Webb, Thomas H, Suh, Hongsuk, Wilcox, Craig S

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Solution-Phase Parallel Synthesis with Oligoethylene Glycol Sorting Tags. Preparation of All Four Stereoisomers of the Hydroxybutenolide Fragment of Murisolin and Related Acetogenins by Gudipati, Venugopal, Curran, Dennis P, Wilcox, Craig S

“…The principles of the oligoethylene glycol (OEG) mixture synthesis are illustrated with the synthesis of all four possible stereoisomers of a hydroxybutenolide…”
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Precipiton Reagents:  Precipiton Phosphines for Solution-Phase Reductions by Bosanac, Todd, Wilcox, Craig S

“…Several Precipiton phosphines were prepared and employed in the Staudinger reaction and in the reduction of secondary ozonides. Both amines and aldehdyes were…”
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Precipitons-Functional Protecting Groups to Facilitate Product Separation: Applications in Isoxazoline Synthesis by Bosanac, Todd, Yang, Jaemoon, Wilcox, Craig S.

“…Imagine—after a homogeneous reaction is complete, the chemist adds a catalyst or exposes the reaction mixture to soft UV light and pure product precipitates…”
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Molecular recognition in aqueous media. Conformationally restricted water-soluble cyclophanes derived from 6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine by Cowart, Marlon D, Sucholeiki, Irving, Bukownik, Rudolf R, Wilcox, Craig S

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Solution-Phase Mixture Synthesis with Double-Separation Tagging: Double Demixing of a Single Mixture Provides a Stereoisomer Library of 16 Individual Murisolins by Wilcox, Craig S., Gudipati, Venugopal, Lu, Hejun, Turkyilmaz, Serhan, Curran, Dennis P.

“…Two tags are better than one: Sixteen individual stereoisomers of murisolin (see scheme) are synthesized together and isolated in pure form with the aid of a…”
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Use of Precipitons for Copper Removal in Atom Transfer Radical Polymerization by Honigfort, Mical E, Brittain, William J, Bosanac, Todd, Wilcox, Craig S

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