Search Results - "Wiedemaier, Fabian"

Elucidating the role of amine donors in manganese catalyzed transfer hydrogenation by Wiedemaier, Fabian, Belaj, Ferdinand, Mösch-Zanetti, Nadia C.

“…[Display omitted] •Mechanistic studies on manganese catalyzed transfer hydrogenation of ketones.•Amine motif in the ligand is crucial for catalytic…”
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The crucial role of ligand deprotonation in manganese catalyzed hydrogenation reactions by Wiedemaier, Fabian, Rath, Marko, Reisenhofer, Antonia, Dupé, Antoine, Belaj, Ferdinand, Mösch-Zanetti, Nadia C.

“…[Display omitted] •Mechanistic studies on manganese catalyzed hydrogenation of ketones.•NH-motif in the ligand is crucial for catalytic activity.•Hammett…”
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Cover Feature: Influence of Charge Delocalization on Manganese Catalyzed Transfer Hydrogenation (ChemCatChem 7/2024) by Wiedemaier, Fabian, Hofer, Christa, Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.

“…The Cover Feature shows an anionic manganese compound with the negative charge delocalized towards the hydride, which is crucial for catalytic activity in the…”
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Oxygen Atom Transfer Reactivity of Molybdenum(VI) Complexes Employing Pyrimidine- and Pyridine-2-thiolate Ligands by Ehweiner, Madeleine A, Wiedemaier, Fabian, Belaj, Ferdinand, Mösch-Zanetti, Nadia C

“…Four dioxidomolybdenum­(VI) complexes of the general structure [MoO2L2] employing the S,N-bidentate ligands pyrimidine-2-thiolate (PymS, 1),…”
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Influence of Charge Delocalization on Manganese Catalyzed Transfer Hydrogenation by Wiedemaier, Fabian, Hofer, Christa, Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.

“…Hydrogen transfer reactions promoted by Mn(I)‐based catalysts are a recently emerged field of research. Herein, we demonstrate the crucial effect of charge…”
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Replacement of Molybdenum by Tungsten in a Biomimetic Complex Leads to an Increase in Oxygen Atom Transfer Catalytic Activity by Ćorović, Miljan Z., Wiedemaier, Fabian, Belaj, Ferdinand, Mösch-Zanetti, Nadia C.

“…Upon replacement of molybdenum by tungsten in DMSO reductase isolated from the Rhodobacteraceae family, the derived enzyme catalyzes DMSO reduction faster. To…”
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Nature-Inspired Homogeneous Catalytic Perchlorate Reduction Using Molybdenum Complexes by Ehweiner, Madeleine A, Wiedemaier, Fabian, Lajin, Bassam, Schachner, Jörg A, Belaj, Ferdinand, Goessler, Walter, Mösch-Zanetti, Nadia C

“…Inspired by the reactivity of (per)­chlorate reducing molybdoenzymes and encouraged by the lack of molybdenum-containing functional models thereof, two…”
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