Search Results - "Whaley, C."
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Nickel−Iron Dithiolato Hydrides Relevant to the [NiFe]-Hydrogenase Active Site
Published in Journal of the American Chemical Society (27-05-2009)“…The ferrous dithiolato carbonyl Fe(S2C3H6)(CO)2(dppe) (1) condenses with NiCl2(dppe) to give [FeNi(pdt)(μ-Cl)(CO)(dppe)2]BF4 ([2Cl]+). The corresponding…”
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Synthesis and Biodegradation Studies of Low‐Dispersity Poly(acrylic acid)
Published in Macromolecular rapid communications. (01-07-2022)“…Poly(acrylic acid) (PAA) is produced on an industrial scale and widely‐used in applications such as personal care products and cleaning formulations that end…”
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Characterization of a Diferrous Terminal Hydride Mechanistically Relevant to the Fe-Only Hydrogenases
Published in Journal of the American Chemical Society (23-11-2005)“…Reduction of diferrous dithiolato complexes with hydride donor reagents affords the first example of the previously elusive terminal diferrous hydride,…”
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Comment on ‘Licence to save: a UK survey of anti-VEGF use for the eye in 2015
Published in Eye (London) (01-02-2018)Get full text
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Use of person-centered goals to direct interdisciplinary care for military service members and Veterans with chronic mTBI and co-occurring psychological conditions
Published in Frontiers in neurology (16-11-2022)“…To explore the use of person-centered goals (PCGs) to direct interdisciplinary care to support PCG attainment in military service members and Veterans (SM/Vs)…”
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FTIR time-series of biomass burning products (HCN, C 2 H 6 , C 2 H 2 , CH 3 OH, and HCOOH) at Reunion Island (21° S, 55° E) and comparisons with model data
Published in Atmospheric chemistry and physics (07-11-2012)“…Reunion Island (21° S, 55° E), situated in the Indian Ocean at about 800 km east of Madagascar, is appropriately located to monitor the outflow of biomass…”
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Vibrational Analysis of the Model Complex (μ-edt)[Fe(CO)3]2 and Comparison to Iron-Only Hydrogenase: The Activation Scale of Hydrogenase Model Systems
Published in Inorganic chemistry (05-04-2010)“…Research on simple [FeFe] hydrogenase model systems of type (μ-S2R)[Fe(CO)3]2 (R = C2H4 (edt), C3H6 (pdt)) which have been shown to function as robust…”
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Vibrational analysis of the model complex (mu-edt)[Fe(CO)(3)](2) and comparison to iron-only hydrogenase: the activation scale of hydrogenase model systems
Published in Inorganic chemistry (05-04-2010)“…Research on simple [FeFe] hydrogenase model systems of type (mu-S(2)R)[Fe(CO)(3)](2) (R = C(2)H(4) (edt), C(3)H(6) (pdt)) which have been shown to function as…”
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The iron-site structure of [Fe]-hydrogenase and model systems: an X-ray absorption near edge spectroscopy study
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2010)“…The [Fe]-hydrogenase is an ideal system for studying the electronic properties of the low spin iron site that is common to the catalytic centres of all…”
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A multiwavelength infrared study of NGC 891
Published in Monthly notices of the Royal Astronomical Society (01-05-2009)“…We present a multiwavlength infrared (IR) study of the nearby, edge-on, spiral galaxy NGC 891. We have examined 20 independent, spatially resolved IR images of…”
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Observed and simulated time evolution of HCl, ClONO2, and HF total column abundances
Published in Atmospheric chemistry and physics (01-04-2012)“…Time series of total column abundances of hydrogen chloride (HCl), chlorine nitrate (ClONO2 ), and hydrogen fluoride (HF) were determined from ground-based…”
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12
Observed and simulated time evolution of HCl, ClONO 2 , and HF total column abundances
Published in Atmospheric chemistry and physics (12-04-2012)“…Time series of total column abundances of hydrogen chloride (HCl), chlorine nitrate (ClONO2), and hydrogen fluoride (HF) were determined from ground-based…”
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Favorable Protonation of the (μ-edt)[Fe2(PMe3)4(CO)2(H-terminal)]+ Hydrogenase Model Complex Over Its Bridging μ-H Counterpart: A Spectroscopic and DFT Study
Published in European Journal of Inorganic Chemistry (01-03-2011)“…The mechanism of hydrogen production in [FeFe] hydrogenase remains elusive. However, a species featuring a terminal hydride bound to the distal Fe is thought…”
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Identification of anti-inflammatory targets for Huntington's disease using a brain slice-based screening assay
Published in Neurobiology of disease (01-07-2011)“…Abstract Huntington's disease (HD) is a late-onset, neurodegenerative disease for which there are currently no cures nor disease-modifying treatments. Here we…”
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Toronto area ozone: Long-term measurements and modeled sources of poor air quality events
Published in Journal of geophysical research. Atmospheres (16-11-2015)“…The University of Toronto Atmospheric Observatory and Environment Canada's Centre for Atmospheric Research Experiments each has over a decade of ground‐based…”
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Investigation of CO, C2H6 and aerosols in a boreal fire plume over eastern Canada during BORTAS 2011 using ground- and satellite-based observations, and model simulations
Published in Atmospheric chemistry and physics (01-01-2013)“…We present the results of total column measurements of CO, C2H6 and fine mode aerosol optical depth (AOD) during the "Quantifying the impact of BOReal forest…”
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Coordination Chemistry of [HFe(CN)2(CO)3]− and Its Derivatives: Toward a Model for the Iron Subsite of the [NiFe]-Hydrogenases
Published in Inorganic chemistry (18-05-2009)“…The photoreaction of Fe(CO)5 and cyanide salts in MeCN solution affords the dianion [Fe(CN)2(CO)3]2−, conveniently isolated as [K(18-crown-6)]2[Fe(CN)2(CO)3]…”
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Investigation of CO, C 2 H 6 and aerosols in a boreal fire plume over eastern Canada during BORTAS 2011 using ground- and satellite-based observations and model simulations
Published in Atmospheric chemistry and physics (18-10-2013)“…We present the results of total column measurements of CO, C2H6 and fine-mode aerosol optical depth (AOD) during the "Quantifying the impact of BOReal forest…”
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Sex differences in the association between parental monitoring and substance use initiation among adolescents
Published in Addictive behaviors (01-11-2021)“…•Parental monitoring (PM) was associated with lower odds of substance use initiation.•Males (vs. females) had higher odds of cigarette and cigar use…”
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MS2(Me2PC2H4PMe2)2 (M = Mo, W): Acid−Base Properties, Proton Transfer, and Reversible Protonolysis of Sulfido Ligands
Published in Inorganic chemistry (23-01-2006)“…The acid−base reactivity of MS2(dmpe)2, where M = Mo (1) and W (2) and dmpe = Me2PCH2CH2PMe2, was examined. Compounds 1 and 2 arise via the one-pot reaction of…”
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