Search Results - "Werz, Daniel B."

Uncovering the Neglected Similarities of Arynes and Donor–Acceptor Cyclopropanes by Werz, Daniel B., Biju, Akkattu T.

“…Arynes and donor–acceptor (D–A) cyclopropanes are two classes of strained systems having the potential for numerous applications in organic synthesis. The last…”
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A New Golden Age for Donor-Acceptor Cyclopropanes by Schneider, Tobias F., Kaschel, Johannes, Werz, Daniel B.

“…The effective use of ring strain has been applied to considerable advantage for the construction of complex systems. The focus here is directed towards…”
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C-H deuteration of organic compounds and potential drug candidates by Prakash, Gaurav, Paul, Nilanjan, Oliver, Gwyndaf A, Werz, Daniel B, Maiti, Debabrata

“…C-H deuteration has been intricately developed to satisfy the urgent need for site-selectively deuterated organic frameworks. Deuteration has been primarily…”
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Carbopalladation Cascades Using Carbon-Carbon Triple Bonds: Recent Advances to Access Complex Scaffolds by Düfert, Alexander, Werz, Daniel B.

“…Alkynes are one of the most versatile functional groups as synthetic handles. They allow for a direct access to partially or fully substituted alkenes through…”
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The Cyclopropyl Group as a Neglected Donor in Donor–Acceptor Cyclopropane Chemistry by Kreft, Alexander, Jones, Peter G, Werz, Daniel B

“…D–A cyclopropanes bearing a simple cyclopropyl group as donor are shown to undergo a variety of [3+n]-cycloaddition reactions (n = 2–4). This behavior…”
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Kinetic Studies of Donor–Acceptor Cyclopropanes: The Influence of Structural and Electronic Properties on the Reactivity by Kreft, Alexander, Lücht, Alexander, Grunenberg, Jörg, Jones, Peter G., Werz, Daniel B.

“…The kinetics of (3+2) cycloaddition reactions of 18 different donor–acceptor cyclopropanes with the same aldehyde were studied by in situ NMR spectroscopy…”
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Electrocatalytic Activation of Donor–Acceptor Cyclopropanes and Cyclobutanes: An Alternative C(sp3)−C(sp3) Cleavage Mode by Kolb, Simon, Petzold, Martin, Brandt, Felix, Jones, Peter G., Jacob, Christoph R., Werz, Daniel B.

“…We describe the first electrochemical activation of D–A cyclopropanes and D–A cyclobutanes leading after C(sp3)−C(sp3) cleavage to the formation of highly…”
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Ring‐Opening 1‐Amino‐3‐aminomethylation of Donor–Acceptor Cyclopropanes via 1,3‐Diazepanes by Garve, Lennart K. B., Jones, Peter G., Werz, Daniel B.

“…The first ring‐opening reaction of donor–acceptor cyclopropanes to give diamines is reported. For this reaction, a 1,3‐bisfunctionalization was developed using…”
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Synthesis and medical applications of oligosaccharides by Werz, Daniel B, Seeberger, Peter H

“…Our understanding of the different glycoconjugates present on cells, proteins and entire organisms is lagging far behind advances in genomics and proteomics…”
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BOIMPYs: Rapid Access to a Family of Red-Emissive Fluorophores and NIR Dyes by Patalag, Lukas J., Jones, Peter G., Werz, Daniel B.

“…A fundamental, highly fluorescent, and easily accessible scaffold derived from the BODIPY core is reported. The use of benzimidazole as a bridging ligand at…”
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trans‐Carbocarbonation of Internal Alkynes through a Formal anti‐Carbopalladation/C−H Activation Cascade by Reding, Andreas, Jones, Peter G., Werz, Daniel B.

“…An intramolecular Pd‐catalyzed cascade reaction is presented that consists of a formal anti‐carbopalladation of a C−C triple bond followed by C−H activation…”
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Extended Benzene‐Fused Oligo‐BODIPYs: In Three Steps to a Series of Large, Arc‐Shaped, Near‐Infrared Dyes by Patra, Atanu, Patalag, Lukas J., Jones, Peter G., Werz, Daniel B.

“…We present a straightforward, three‐step synthesis engaging an oligomerization and subsequent one‐pot oxidation step to form fully conjugated, benzene‐fused…”
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cis-Selective, Enantiospecific Addition of Donor–Acceptor Cyclopropanes to Activated Alkenes: An Iodination/Michael-Cyclization Cascade by Ahlburg, Nils L, Jones, Peter G, Werz, Daniel B

“…We present a versatile method for the enantiospecific, cis-diastereoselective intermolecular and intramolecular cycloaddition of donor–acceptor cyclopropanes…”
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Synthesis of 2‑Unsubstituted Pyrrolidines and Piperidines from Donor–Acceptor Cyclopropanes and Cyclobutanes: 1,3,5-Triazinanes as Surrogates for Formylimines by Garve, Lennart K. B, Kreft, Alexander, Jones, Peter G, Werz, Daniel B

“…A synthetic procedure to access 2-unsubstituted pyrrolidines and piperidines is presented. In the presence of MgI2 as Lewis acid, donor–acceptor cyclopropanes…”
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Highly scalable photoinduced synthesis of silanols via untraversed pathway for chlorine radical (Cl•) generation by Saha, Argha, Ali, Wajid, Werz, Daniel B., Maiti, Debabrata

“…The emergence of visible light-mediated synthetic transformations has transpired as a promising approach to redefine traditional organic synthesis in a…”
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Intramolecular trans-Carbocarbonation of Internal Alkynes by a Cascade of Formal anti-Carbopalladation/Cyclopropanol Opening by Reding, Andreas, Jones, Peter G, Werz, Daniel B

“…An intramolecular cascade reaction consisting of a formal anti-carbopalladation terminated by the ring-opening of a cyclopropanol unit is presented. The…”
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Ring-Opening 1,3-Halochalcogenation of Cyclopropane Dicarboxylates by Wallbaum, Jan, Garve, Lennart K. B, Jones, Peter G, Werz, Daniel B

“…Donor–acceptor cyclopropanes with two geminal carboxylic esters are reacted with chalcogenyl chlorides and bromides to afford ring-opened products bearing the…”
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Optical Manipulation of Gb3 Enriched Lipid Domains: Impact of Isomerization on Gb3‐Shiga Toxin B Interaction by Socrier, Larissa, Ahadi, Somayeh, Bosse, Mathias, Montag, Cindy, Werz, Daniel B., Steinem, Claudia

“…The plasma membrane is a complex assembly of proteins and lipids that can self‐assemble in submicroscopic domains commonly termed “lipid rafts”, which are…”
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Activation of Aryl Thiocyanates Followed by Aryne Insertion: Access to 1,2-Thiobenzonitriles by Pawliczek, Martin, Garve, Lennart K. B, Werz, Daniel B

“…Palladium-catalyzed activation of carbon–sulfur bonds allows aryne insertion into aryl thiocyanates to generate new C–SAr and C–CN bonds in one step. The…”
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Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium by Klopsch, Isabel, Finger, Markus, Würtele, Christian, Milde, Bastian, Werz, Daniel B, Schneider, Sven

“…[ReCl3(PPh3)2(NCMe)] reacts with pincer ligand HN­(CH2CH2PtBu2)2 (HPNP) to five coordinate rhenium­(III) complex [ReCl2(PNP)]. This compound cleaves N2 upon…”
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