Search Results - "Weismann, Daniel"
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High-Spin Cyclopentadienyl Complexes: A Single-Molecule Magnet Based on the Aryl-Iron(II) Cyclopentadienyl Type
Published in Chemistry : a European journal (18-04-2011)“…The mononuclear high‐spin iron(II) complex 1, coordinated by a pentaisopropylcyclopentadienide and an aryl group (see graphic), has been prepared and…”
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Stable and Persistent Acyclic Diaminocarbenes with Cycloalkyl Substituents and Their Transformation to β‐Lactams by Uncatalysed Carbonylation with CO
Published in Chemistry : a European journal (28-01-2019)“…Four new acyclic diaminocarbenes (ADACs), viz. [(cyclo‐CnH2n−1)2N]2C (n=5–7) and iPr2N‐C‐N(cyclo‐C6H11)2, were synthesised by reacting the corresponding…”
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Cover Feature: Stable and Persistent Acyclic Diaminocarbenes with Cycloalkyl Substituents and Their Transformation to β‐Lactams by Uncatalysed Carbonylation with CO (Chem. Eur. J. 6/2019)
Published in Chemistry : a European journal (28-01-2019)“…Acyclic diaminocarbenes (ADACs) are ambiphilic, which makes them suitable for the activation of fundamentally important small molecules. For example, most of…”
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New Stable and Persistent Acyclic Diaminocarbenes
Published in Chemistry : a European journal (28-09-2015)“…The portfolio of acyclic diaminocarbenes (ADACs) has been substantially expanded, owing to the synthesis of eleven new formamidinium salts, mostly of the type…”
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Iron-Mediated Coupling of Two Ethyl Anions to Form a 2-Butyne Ligand
Published in European journal of inorganic chemistry (01-07-2014)“…The σ‐aryliron complexes [5CpFe(C6H3iPr2‐2,6)] (2, 5Cp = η5‐C5iPr5) and [4CpFe(C6H3iPr2‐2,6)] (6, 4Cp = η5‐C5HiPr4) are available from the halides…”
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Cyclopentadiene Alkylation and Nickel Complexes with Tri-, Tetra-, or Pentaisopropylcyclopentadienide or an Even Bulkier Lithium Alkylcyclopentadienide
Published in Organometallics (12-12-2011)“…Phase transfer catalysis has been adapted to the synthesis of triisopropylcyclopentadiene isomers 1 in high yield and purity. Alkylation of sodium…”
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Dibenzo[c,g]fluorenyliron: An Organometallic Relative of Pentahelicene
Published in Angewandte Chemie (International ed.) (14-04-2008)“…Close relatives! The Pd‐catalyzed hydrogenation of the “isolated” CC double bonds of dibenzo[c,g]fluorenide coordinated to an FeII center confirms that the…”
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Exploring the Concept of Aromaticity on Complexes of a Fourfold Benzannulated Cyclopentadienyl Ligand
Published in Chemistry : a European journal (25-01-2010)“…The ligand dibenzo[c,g]fluorenide (Dbf−), combines a cyclopentadienide ligand and 1,1′‐binaphthyl fragment in one molecule. Preliminary investigations…”
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Reactive Sigma-Aryliron Complexes or Iron-Promoted Coupling of Two Phenyl Anions to One Bis(cyclohexadienylidene) Ligand: Synthesis, Structure, Mass Spectrometry, and DFT Calculations
Published in Organometallics (22-02-2010)“…A reaction of the bulky alkylcyclopentadienyliron(II) high-spin complex [Cp′′′Fe(μ-Br)]2 (1a) (Cp′′′ = C5H2(CMe3)3-1,2,4) with phenylmagnesium bromide produced…”
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Dibenzo[c,g]fluorenyleisen: ein metallorganischer Verwandter von Pentahelicen
Published in Angewandte Chemie (14-04-2008)Get full text
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Dibenzo[c,g]fluorenyleisen: ein metallorganischer Verwandter von Pentahelicen
Published in Angewandte Chemie (14-04-2008)“…Familiäre Verhältnisse: Die Pd‐katalysierte Hydrierung der „isolierten“ CC‐Doppelbindungen von FeII‐koordiniertem Dibenzo[c,g]fluorenid bestätigt die…”
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