Search Results - "Weinberger, David S."
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Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis
Published in Angewandte Chemie (International ed.) (02-02-2015)“…An expanded family of ruthenium‐based metathesis catalysts bearing cyclic alkyl amino carbene (CAAC) ligands was prepared. These catalysts exhibited…”
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2
Trinuclear Gold Clusters Supported by Cyclic (alkyl)(amino)carbene Ligands: Mimics for Gold Heterogeneous Catalysts
Published in Angewandte Chemie International Edition (18-08-2014)“…The synthesis of air‐ and moisture‐stable trinuclear mixed‐valence gold(I)/gold(0) clusters is described. They promote the catalytic carbonylation of amines…”
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3
Isolation of Neutral Mono- and Dinuclear Gold Complexes of Cyclic (Alkyl)(amino)carbenes
Published in Angewandte Chemie International Edition (19-08-2013)“…The smallest pieces of gold! Thanks to the presence of two π‐accepting cyclic (alkyl)(amino)carbenes (CAACs),complexes featuring one and two atoms of gold in…”
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4
Isolation of a Carborane-Fused Triazole Radical Anion
Published in Angewandte Chemie International Edition (25-10-2013)“…Outside the cage: A change in the redox properties of a triazole fused to a carborane anion through methylation to form a zwitterion enabled facile chemical…”
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5
Synthesis, Structural Characterization, and Carbonyl Addition Reactivity of a Terminal Cerium(III) Acetylide Complex
Published in Organometallics (10-11-2014)“…We report the first structurally characterized terminal Ce(III) acetylide complex, Na[Ce(CCPh)(bdmmp)3] (2), isolated from the salt metathesis of NaCCPh with…”
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Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes
Published in Journal of the American Chemical Society (30-04-2014)“…Two (cAAC)2Cu complexes, featuring a two-coordinate copper atom in the formal oxidation state zero, were prepared by reducing (Et2-cAAC)2Cu+I− with metallic…”
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7
Trinuclear Gold Clusters Supported by Cyclic (alkyl)(amino)carbene Ligands: Mimics for Gold Heterogeneous Catalysts
Published in Angewandte Chemie (18-08-2014)“…The synthesis of air‐ and moisture‐stable trinuclear mixed‐valence gold(I)/gold(0) clusters is described. They promote the catalytic carbonylation of amines…”
Get full text
Journal Article -
8
Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis
Published in Angewandte Chemie (02-02-2015)“…An expanded family of ruthenium‐based metathesis catalysts bearing cyclic alkyl amino carbene (CAAC) ligands was prepared. These catalysts exhibited…”
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Journal Article -
9
Isolation of a Carborane-Fused Triazole Radical Anion
Published in Angewandte Chemie (25-10-2013)“…Außerhalb des Käfigs: Die Redoxeigenschaften eines Triazol‐anellierten Carboran‐Anions werden durch Methylierung und Zwitterionenbildung so verändert, dass die…”
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10
Regulating Oxygen Activity of Perovskites to Promote Activity and Selectivity for Methanol Oxidation to Formaldehyde
Published in ACS catalysis (17-05-2024)“…Rational designs of metal oxides are needed to selectively oxidize methanol (CH3OH) to valuable chemicals like formaldehyde (HCHO) and avoid complete oxidation…”
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11
Isolierung neutraler mono- und dinuklearer Goldkomplexe von cyclischen Alkyl(amino)carbenen
Published in Angewandte Chemie (19-08-2013)Get full text
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12
Isolation of a Carborane‐Fused Triazole Radical Anion
Published in Angewandte Chemie (25-10-2013)Get full text
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13
Stabilization of Coinage Metals With an Oxidation State of Zero
Published 01-01-2014“…Cyclic (alkyl) (amino)carbenes (CAACs) are highly nucleophilic and electrophilic species. By utilizing these properties, neutral mono- and di-nuclear coinage…”
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Dissertation -
14
Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis
Published in Angewandte Chemie (17-12-2014)“…Abstract An expanded family of ruthenium‐based metathesis catalysts bearing cyclic alkyl amino carbene (CAAC) ligands was prepared. These catalysts exhibited…”
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Journal Article -
15
Isolierung neutraler mono‐ und dinuklearer Goldkomplexe von cyclischen Alkyl(amino)carbenen
Published in Angewandte Chemie (19-08-2013)“…Das kleinste Stückchen Gold! Dank der Anwesenheit zweier cyclischer Alkyl‐(amino)carbene (CAACs) konnten Komplexe mit einem bzw. zwei Goldatomen in der…”
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