Search Results - "Wee, Andrew G. H"
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Stereoselective Syntheses of (+)-2-epi-Deoxoprosopinine, (−)-Deoxoprosophylline, (+)-cis-195A, and 2,5-Di-epi-cis-195A from a Common Chiral Nonracemic Building Block
Published in Journal of organic chemistry (15-05-2015)“…Approaches toward the syntheses of alkaloids belonging to the 2,6-disubstituted 3-hydroxypiperidine and cis-decahydroquinoline (cis-DHQ) classes of alkaloids…”
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Nonracemic Bicyclic Lactam Lactones via Regio- and cis-Diastereocontrolled C−H Insertion. Asymmetric Synthesis of (8S,8aS)-Octahydroindolizidin-8-ol and (1S,8aS)-Octahydroindolizidin-1-ol
Published in Journal of organic chemistry (06-11-2009)“…The Rh2(MPPIM)4-catalyzed intramolecular C−H insertion reaction of (S)- and (R)-1-benzyl-5-(α-diazoacetoxy)piperidin-2-one and…”
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An Alkylidene Carbene C–H Activation Approach toward the Enantioselective Syntheses of Spirolactams: Application to the Synthesis of (−)-Adalinine
Published in Journal of organic chemistry (05-02-2016)“…A method based on in situ alkylidene carbene generation-C–H insertion reaction of 5-(3-oxobutyl)pyrrolidin-2-ones and 6-(3-oxobutyl)piperidin-2-ones is…”
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NMR Studies of Amine Species in MEA−CO2−H2O System: Modification of the Model of Vapor−Liquid Equilibrium (VLE)
Published in Industrial & engineering chemistry research (04-03-2009)“…Speciation studies in aqueous monoethanolamine (MEA) solution at different CO2 loadings have been conducted via nuclear magnetic resonance (NMR) spectroscopy…”
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Mapping the Mechanism of the Resorcinol Ring Formation Catalyzed by ArsB, a Type III Polyketide Synthase from Azotobacter vinelandii
Published in Chembiochem : a European journal of chemical biology (15-10-2012)“…Who's first? Aldol cyclization occurs before hydrolysis in the resorcinol ring formation catalyzed by the type III polyketide synthase, ArsB. Synthetic C20‐TKA…”
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Di- and Trisubstituted γ-Lactams via Rh(II)-carbenoid Reaction of N-Cα-Branched, N-Bis(trimethylsilyl)methyl α-Diazoamides. Synthesis of (±)-α-Allokainic Acid
Published in Organic letters (03-12-2010)“…Acyclic N-Cα-branched, N-bis(trimethylsilyl)methyl (N-BTMSM) diazoamides undergo regio-, chemo-, and diastereoselective Rh(II)-carbenoid C−H insertion to give…”
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PpASCL, a moss ortholog of anther-specific chalcone synthase-like enzymes, is a hydroxyalkylpyrone synthase involved in an evolutionarily conserved sporopollenin biosynthesis pathway
Published in The New phytologist (01-12-2011)“…Sporopollenin is the main constituent of the exine layer of spore and pollen walls. Recently, several Arabidopsis genes, including polyketide synthase A…”
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Asymmetric Synthesis of (+)-Isofebrifugine and (−)-Sedacryptine from a Common Chiral Nonracemic Building Block
Published in Organic letters (04-09-2008)“…The stereoselective syntheses of 2-substituted and 2,6-disubstituted 3-hydroxypiperidine alkaloids, (+)-isofebrifugine and (−)-sedacryptine, from a common,…”
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The Bis(trimethylsilyl)methyl Group as an Effective N-Protecting Group and Site-Selective Control Element in Rhodium(II)-Catalyzed Reaction of Diazoamides
Published in Journal of organic chemistry (14-10-2005)“…The intramolecular rhodium(II)−carbenoid-mediated C−H insertion reaction of structurally varied N-bis(trimethylsilyl)methyl,N-substituted diazoamides is…”
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Stereoselective Synthesis of the Nonproteinogenic Amino Acid (2S,3R)-3-Amino-2-hydroxydecanoic Acid from (4S,5S)-4-Formyl-5-vinyl-2-oxazolidinone
Published in Journal of organic chemistry (08-08-2003)“…(4S,5S)-4-Formyl-5-vinyl-2-oxazolidinone (4b), which is readily obtained via a zinc−silver-mediated reductive elimination of α-d-lyxofuranosyl phenyl sulfone…”
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Influences of Catalyst Configuration and Catalyst Loading on Selectivities in Reactions of Diazoacetamides. Barrier to Equilibrium between Diastereomeric Conformations
Published in Organic letters (20-02-2003)“…Stereoelectronic factors present a barrier to equilibrium between diastereomeric conformations resulting in differences in selectivity as a function of…”
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Conformational, steric and electronic effects on the site- and chemoselectivity of the metal-catalyzed reaction of N-bis(trimethylsilyl)methyl, N-(2-indolyl)methyl α-diazoamides
Published in Organic & biomolecular chemistry (21-06-2012)“…The Rh(II)- and Cu(II)-catalyzed reactions of N-bis(trimethylsilyl)methyl, N-(2-indolyl)methyl α-diazoamides are investigated to delineate how conformational,…”
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Comparative Mass Transfer Performance Studies of CO2 Absorption into Aqueous Solutions of DEAB and MEA
Published in Industrial & engineering chemistry research (17-03-2010)“…The mass transfer performance of the absorption of CO2 in an aqueous solution of a new amino alcohol, 4-diethylamino-2-butanol (DEAB), which has been developed…”
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Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the beta-carboline ring system
Published in Chemical communications (Cambridge, England) (01-01-2008)“…The intramolecular metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(TMS)methyl diazoamides proceeds with high conformational control and chemoselectivity…”
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Ceric ammonium nitrate oxidation of N-(p-methoxybenzyl)lactams: competing formation of N-(hydroxymethyl)δ-lactams
Published in ARKIVOC (20-11-2014)Get full text
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Competing Isomerizations: A Combined Experimental/Theoretical Study of Phenylpentenone Isomerism
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (11-05-2006)“…The possible competition of Z/E versus hydrogen-shift isomerization in (E)-5-phenyl-3-penten-2-one (E -1) and (E)-5-phenyl-4-penten-2-one (E-2) was studied,…”
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A Dirhodium(II)−Carbenoid Route to (−)- and (+)-Geissman−Waiss Lactone: Synthesis of (1R,7R,8R)-(−)-Turneforcidine
Published in Journal of organic chemistry (14-12-2001)“…(−)- and (+)-Geissman−Waiss lactone, 4b, was efficiently prepared via the intramolecular C−H insertion reaction of the chiral nonracemic diazoacetates (−)-5a…”
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Porphyrin- and porphyrinoid-based covalent organic frameworks (COFs): From design, synthesis to applications
Published in Coordination chemistry reviews (15-05-2021)“…•Porphyrin and porphyrinoid-based covalent organic frameworks (COFs) are reviewed.•The design and synthesis of porphyrin and porphyrinoid-based COFs are…”
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Physical and transport properties of aqueous amino alcohol solutions for CO2 capture from flue gas streams
Published in Process safety and environmental protection (01-07-2008)“…Densities, viscosities and refractive indices of 4-diethylamino-2-butanol + water mixtures were measured over the entire concentration range of 0-1 mole…”
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