Search Results - "Watson, Paul G."

Trithiatetrazocine Cations, [RCN4S3]+; Planar Sulfur−Nitrogen 10π Aromatics by Knapp, Carsten, Watson, Paul G, Lork, Enno, Friese, Daniel H, Mews, Rüdiger, Decken, Andreas

“…The reaction of bicyclic sulfur−nitrogen heterocyles RCN5S3 (R = F3C, Ph, Me2N, 2-FC6H4, 2,6-F2C6H3) with [Hg(SO2)2][AsF6]2 in liquid SO2 yielded the…”
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Structure of the SO2F- Anion, a Problem Case1 by Lork, Enno, Mews, Rüdiger, Viets, Detlef, Watson, Paul G, Borrmann, Tobias, Vij, Ashwani, Boatz, Jerry A, Christe, Karl O

“…Recently, room-temperature crystal structures of SO2F- in its K+ and Rb+ salts were published in Z. Anorg. Allg. Chem. 1999, 625, 385 and claimed to represent…”
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Lithium Fluoroarylamidinates:  Syntheses, Structures, and Reactions by Knapp, Carsten, Lork, Enno, Watson, Paul G, Mews, Rüdiger

“…Lithium fluoroarylamidinates [(ArFC(NSiMe3)2Li) n ·xD] (ArF = 4-CF3C6H4, n = 2, D = OEt2, x = 1 (2a); n = 1, D = TMEDA, x = 1 (4a); ArF = 2-FC6H4, n = 2, D =…”
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Reactions of Arylthiazylamides with Internal and External Fluoro Electrophiles − Formation of Products with Unusual Structures by Lork, Enno, Mews, Rüdiger, Shakirov, Makhmut M., Watson, Paul G., Zibarev, Andrey V.

“…The heteroatom reactivity of the title anions [as (Me2N)3S+ and Cs+ salts] toward both internal and external fluoro electrophiles has been investigated. The…”
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Fluorothiazynes, 50 years old and still exciting: electrophilic attack at the thiazyl nitrogen of NSF2NS(O)F2 by Mews, Rüdiger, Borrmann, Tobias, Hoppenheit, Reinhard, Lork, Enno, Parsons, Simon, Petersen, Jan, Schröter, Markus, Stohrer, Wolf-Dieter, Waterfeld, Alfred, Watson, Paul G.

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TAS+(Z)-Me3CNSN- and TAS+(E)-Me3SiNSN-:  Does the Anion−Cation Interaction Influence the Configuration? by Borrmann, Tobias, Zibarev, Andrey V, Lork, Enno, Knitter, Gerd, Chen, Shan-Jia, Watson, Paul G, Cutin, Edgardo, Shakirov, Makhmut M, Stohrer, Wolf-Dieter, Mews, Rüdiger

“…TAS+ salts (TAS = (Me2N)3S) of the sulfur diimide anions Me3XNSN- (X = C (1a), Si (1b)) were prepared by Si−N bond cleavage from the corresponding sulfur…”
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Syntheses and Structures of Bis(azole)difluorosulfuranes by Wessel, Jens, Behrens, Ulrich, Lork, Enno, Watson, Paul G, Schröter, Markus, Mews, Rüdiger

“…Bis(imidazole)sulfur difluoride (4), bis(pyrazole)sulfur difluoride (6), and bis(1,2,4-triazole)sulfur difluoride (8) are formed in the reactions of…”
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Coordination chemistry in and of sulfur dioxide by Mews, Rüdiger, Lork, Enno, Watson, Paul G., Görtler, Bernd

“…The review describes the syntheses of metal salts with weakly interacting anions (AlCl 4  −, AsF 6  −, SbF 6  −) in the poorly coordinating solvent SO 2. The…”
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The crystal structures of NSF 3 and (NSF 2N(CH 3)CH 2–) 2: How short is the ‘Crystallographic’ N S triple bond? by Borrmann, Tobias, Lork, Enno, Mews, Rüdiger, Parsons, Simon, Petersen, Jan, Stohrer, Wolf-Dieter, Watson, Paul G.

“…NSF 3 is considered the archetype of a compound with a sulfur(VI)–nitrogen triple bond. We report the first determination of its crystal structure. The SN bond…”
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The crystal structures of NSF3 and (NSF2N(CH3)CH2–)2: How short is the ‘Crystallographic’ NS triple bond? by Borrmann, Tobias, Lork, Enno, Mews, Rüdiger, Parsons, Simon, Petersen, Jan, Stohrer, Wolf-Dieter, Watson, Paul G.

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CAI: FROM THE EDUCATIONAL TECHNOLOGIST'S POINT OF VIEW by WATSON, PAUL G.

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[P 3N 3F 5NS(O)Cl] − and [{P 4N 4F 6(NS(Cl)N)} 2] 2−, the first chloro imino- and chloro bis(imino) sulfinates by Kingston, Melanie, Lork, Enno, Viets, Detlef, Watson, Paul G., Mews, Rüdiger

“…In CH 3CN solution at −30 °C, [TAS] +[P 3N 3F 5NS(O)F] − ( 2) is formed from TASF and P 3N 3F 5NSO, the compound readily decomposes to give P 3N 3F 6 and [TAS]…”
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Trithiatetrazocine cations, [RCN4S3]+; planar sulfur-nitrogen 10pi aromatics by Knapp, Carsten, Watson, Paul G, Lork, Enno, Friese, Daniel H, Mews, Rüdiger, Decken, Andreas

“…The reaction of bicyclic sulfur-nitrogen heterocyles RCN 5S 3 (R = F 3C, Ph, Me 2N, 2-FC 6H 4, 2,6-F 2C 6H 3) with [Hg(SO 2) 2][AsF 6] 2 in liquid SO 2 yielded…”
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Three-coordinate sulphur(VI)-nitrogen species: an attempt to breathe some new life into an old topic by Mews, Rüdiger, Watson, Paul G., Lork, Enno

“…The review describes the syntheses, structures and reaction chemistry of three-coordinate nitrogen-containing sulphur(VI) compounds including the sulphur…”
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Über die Bildung von Trithiatetrazocin‐Derivaten aus bicyclischen Kohlenstoff‐Schwefel‐Stickstoff‐Heterocyclen, RCN 5 S 3 by Knapp, Carsten, Lork, Enno, Maggiulli, Roberto, Watson, Paul G., Mews, Rüdiger, Borrmann, Tobias, Stohrer, Wolf‐Dieter, Behrens, Ulrich

“…F 3 CCN 5 S 3 ( 1a ) bildet mit AsF 5 ein 1:1‐Addukt F 3 CCN 5 S 3 ˙ AsF 5 ( 2 ), welches sich in CDCl 3 ‐Lösung langsam zum kationischen, achtgliedrigem Ring…”
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Arylthiazylamides: Syntheses, Structures, and Bonding Properties by Borrmann, Tobias, Lork, Enno, Mews, Rüdiger, Stohrer, Wolf-Dieter, Watson, Paul G., Zibarev, Andrey V.

“…Air‐sensitive, thermally unstable tris(dimethylamino)sulfonium (TAS) salts (3) of the title anions [ArNSN]− have been prepared from corresponding…”
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Molecular complexes of octafluoronaphthalene with acyclic and heterocyclic sulfur–nitrogen compounds by Bagryanskaya, Irina Yu, Gatilov, Yuri V., Lork, Enno, Mews, Rüdiger, Shakirov, Makhmut M., Watson, Paul G., Zibarev, Andrey V.

“…Mismatched molecular 1:1 complexes were prepared from C 10F 8 and sulfur diimides ArNSNAr 1 and ArNSN–SiMe 3. Mismatched molecular 1:1 complexes were…”
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F 3 CCN 5 S 3 , A BICYCLIC MULTIFUNCTIONAL SULFUR-NITROGEN LIGAND by Knapp, Carsten, Borrmann, Tobias, Lork, Enno, Watson, Paul G., Stohrer, Wolf-Dieter, Mews, Rüdiger

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The first N-alkyl- N′-polyfluorohetaryl sulfur diimide by Lork, Enno, Mews, Rüdiger, Shakirov, Makhmut M., Watson, Paul G., Zibarev, Andrey V.

“…The first N-alkyl- N′-polyfluorohetaryl sulfur diimide Z-AdNSN- E-Het F (Ad=adamant-1-yl, Het F=2,3,5,6-tetrafluoropyrid-4-yl) was prepared by trapping of…”
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Fluorothiazynes, 50 years old and still exciting: electrophilic attack at the thiazyl nitrogen of NSF 2NS(O)F 2 by Mews, Rüdiger, Borrmann, Tobias, Hoppenheit, Reinhard, Lork, Enno, Parsons, Simon, Petersen, Jan, Schröter, Markus, Stohrer, Wolf-Dieter, Waterfeld, Alfred, Watson, Paul G.

“…One of the most interesting compounds in sulfur nitrogen fluorine chemistry is N SF 2 N S( O)F 2 ( 3) (reported by Glemser and Höfer 30 years ago): in the NS…”
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