Search Results - "Wassenaar, Jeroen"
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Reactivity within a confined self-assembled nanospace
Published in Chemical Society reviews (01-01-2008)“…Confined nanospaces in which reactions can take place, have been created by various approaches such as molecular capsules, zeolites and micelles. In this…”
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Catalyst selection based on intermediate stability measured by mass spectrometry
Published in Nature chemistry (01-05-2010)“…The power of natural selection through survival of the fittest is nature's ultimate tool for the improvement and advancement of species. To apply this concept…”
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Asymmetric Synthesis of the Roche Ester and its Derivatives by Rhodium-INDOLPHOS-Catalyzed Hydrogenation
Published in Advanced synthesis & catalysis (07-07-2008)“…(S)‐3‐Hydroxy‐2‐methylpropionate, known as the Roche ester, and several of its derivatives were successfully synthesized through asymmetric rhodium‐catalyzed…”
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INDOLPhosphole and INDOLPhos Palladium−Allyl Complexes in Asymmetric Allylic Alkylations
Published in Organometallics (11-05-2009)“…The new INDOLPhosphole ligands 3a,b are obtained in good yield in a two-step synthetic sequence from 3-methylindole, (S)-BINOL, and the corresponding…”
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Hybrid bidentate phosphorus ligands in asymmetric catalysis: privileged ligand approach vs. combinatorial strategies
Published in Organic & biomolecular chemistry (21-03-2011)“…In this perspective the development of chiral phosphorus ligands for asymmetric catalysis is discussed, with a special focus on hybrid bidentate phosphorus…”
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Rhodium-Catalyzed Asymmetric Hydroformylation with Taddol-Based IndolPhos Ligands
Published in Organometallics (28-06-2010)“…A small library of Taddol-based IndolPhos ligands 2a−g and their use in asymmetric hydroformylation (AHF) reactions are reported. Moderate to good…”
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Asymmetric Hydroformylation Using Taddol-Based Chiral Phosphine−Phosphite Ligands
Published in Organometallics (25-01-2010)“…A small library of 17 modular and easily accessible phenol-derived chiral phosphine−phosphite ligands was evaluated in the asymmetric Rh-catalyzed…”
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Asymmetric Hydrogenation of Enamides, α-Enol and α-Enamido Ester Phosphonates Catalyzed by IndolPhos-Rh Complexes
Published in Journal of organic chemistry (06-11-2009)“…The scope of the IndolPhos-Rh-catalyzed asymmetric hydrogenation of enamides, α-enol and α-enamido ester phosphonates, has been investigated. In addition,…”
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INDOLPhos: novel hybrid phosphine-phosphoramidite ligands for asymmetric hydrogenation and hydroformylation
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2007)“…Hybrid bidentate phosphine-phosphoramidite ligands are prepared in a modular 2-step sequence and their rhodium complexes display high selectivity in rhodium…”
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Asymmetric Hydrogenation with Highly Active IndolPhos-Rh Catalysts: Kinetics and Reaction Mechanism
Published in Chemistry : a European journal (11-06-2010)“…The mechanism of the IndolPhos–Rh‐catalyzed asymmetric hydrogenation of prochiral olefins has been investigated by means of X‐ray crystal structure…”
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Enantioselective Synthesis of Tunable Chiral Clickphine P,N-Ligands and Their Application in Ir-Catalyzed Asymmetric Hydrogenation
Published in Journal of organic chemistry (03-04-2015)“…A small library of highly tunable chiral Clickphine P,N-ligands has been prepared in an enantioselective fashion by CuI-catalyzed asymmetric propargylic…”
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Palladium-(N-Heterocyclic Carbene) Hydrogenation Catalysts
Published in Angewandte Chemie International Edition (18-03-2005)“…Low‐valent palladium compounds with N‐heterocyclic carbenes (NHCs) formed from [Pd(NHC)(η2‐alkene)2] (see example) are amazingly selective catalysts for the…”
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Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity
Published in Inorganic chemistry (19-07-2010)“…The high-yielding synthesis and detailed characterization of two well-defined, linkage isomeric tripodal, tetradentate all-phosphorus ligands 1-3 is described…”
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Versatile New C 3-Symmetric Tripodal Tetraphosphine Ligands; Structural Flexibility to Stabilize CuI and RhI Species and Tune Their Reactivity
Published in Inorganic chemistry (19-07-2010)“…The high-yielding synthesis and detailed characterization of two well-defined, linkage isomeric tripodal, tetradentate all-phosphorus ligands 1−3 is described…”
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Palladium-(N-Heterocyclic Carbene) Hydrogenation Catalysts
Published in Angewandte Chemie (18-03-2005)“…Niedervalente Palladiumverbindungen mit N‐heterocyclischen Carbenen (NHCs) ausgehend von [Pd(NHC)(η2‐Alken)2] (siehe Bild) sind erstaunlich selektive…”
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Palladium–(N‐Heterocyclic Carbene) Hydrogenation Catalysts
Published in Angewandte Chemie (18-03-2005)Get full text
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