Search Results - "Ward, Nicholas A. B."
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Triaryl-Like MONO‑, BIS‑, and TRISKITPHOS Phosphines: Synthesis, Solution NMR Studies, and a Comparison in Gold-Catalyzed Carbon–Heteroatom Bond Forming 5-exo-dig and 6-endo-dig Cyclizations
Published in Organometallics (09-05-2016)“…A homologous series of triaryl-like KITPHOS-type monophosphines containing one, two, or three bulky 12-phenyl-9,10-dihydro-9,10-ethenoanthracene (KITPHOS)…”
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ortho,ortho′-Substituted KITPHOS Monophosphines: Highly Efficient Ligands for Palladium-Catalyzed CC and CN Bond Formation
Published in Advanced synthesis & catalysis (04-01-2010)“…ortho,ortho′‐Substitution of the phosphinoalkyne‐derived aryl ring in KITPHOS (11‐dicyclohexylphosphino‐12‐phenyl‐9,10‐ethenoanthracene) monophosphines…”
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Electron-Rich Trialkyl-Type Dihydro-KITPHOS Monophosphines: Efficient Ligands for Palladium-Catalyzed Suzuki–Miyaura Cross-Coupling. Comparison with Their Biaryl-Like KITPHOS Monophosphine Counterparts
Published in Organometallics (25-03-2013)“…The Diels–Alder cycloaddition between dicyclohexylvinylphosphine oxide and anthracene or 9-methylanthracene affords the bulky electron-rich trialkyl-type…”
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Efficient Cycloisomerization of Propargyl Amides by Electrophilic Gold(I) Complexes of KITPHOS Monophosphines: A Comparative Study
Published in Organometallics (27-09-2010)“…Electrophilic gold(I) complexes of diphenyl- and dicyclohexylphosphino-based KITPHOS monophosphines catalyze the 5-exo-dig cycloisomerization of a range of…”
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Palladium-Catalyzed Suzuki–Miyaura Cross-Couplings with 2‑Diethylphosphonato-Substituted Aryl- and Naphthylboronate Esters as the Nucleophilic Partner: A Complementary Approach to the Synthesis of Biaryl Monophosphonates
Published in Organometallics (13-10-2014)“…This paper reports the first examples of Suzuki–Miyaura cross-couplings involving aryl- and naphthylphosphonate-based boronate esters as the nucleophilic…”
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Ruthenium Complexes of κ(P)- and κ(P)-η6-Coordinated KITPHOS Monophosphines: Efficient Catalysts for the Direct Ortho Arylation of 2-Phenylpyridine and N-Phenylpyrazole with Aryl Chlorides
Published in Organometallics (14-11-2011)“…Thermolysis of the P-coordinated KITPHOS monophosphine complex [(p-cymene)RuCl2(KITPHOS)] in chlorobenzene at 120 °C resulted in displacement of the p-cymene…”
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