Search Results - "Wang, Qu"

Calcium Hydride Cation Dimer Catalyzed Hydrogenation of Unactivated 1‐Alkenes and H2 Isotope Exchange: Competitive Ca−H−Ca Bridges and Terminal Ca−H Bonds by Qu, Zheng‐Wang, Zhu, Hui, Grimme, Stefan

“…Recently, it was shown that the double Ca−H−Ca bridged calcium hydride cation dimer complex [LCaH2CaL]2+ (macrocyclic ligand L=NNNN‐tetradentate Me4TACD)…”
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Reactivity of Frustrated Lewis Pair: Carbocation versus Radical Intermediates by Qu, Zheng‐Wang, Zhu, Hui, Grimme, Stefan

“…Recent reports of radical formation within frustrated Lewis pairs (FLPs) suggested that single‐electron transfer (SET) could play an important role in their…”
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HFIP‐Assisted Single C−F Bond Activation of Trifluoromethyl Ketones using Visible‐Light Photoredox Catalysis by Ghosh, Soumen, Qu, Zheng‐Wang, Pradhan, Suman, Ghosh, Avisek, Grimme, Stefan, Chatterjee, Indranil

“…A visible light photoredox catalytic method for the selective cleavage of single strong C−F bond in trifluoromethyl ketones is reported. Single electron…”
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Structure-Based Pharmacophore Modeling, Virtual Screening, Molecular Docking, ADMET, and Molecular Dynamics (MD) Simulation of Potential Inhibitors of PD-L1 from the Library of Marine Natural Products by Luo, Lianxiang, Zhong, Ai, Wang, Qu, Zheng, Tongyu

“…In the past decade, several antibodies directed against the PD-1/PD-L1 interaction have been approved. However, therapeutic antibodies also exhibit some…”
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Mechanism of Borane‐Catalyzed Oligomerization of Arylallenes and Arylacetylenes by Qu, Zheng‐Wang, Zhu, Hui, Grimme, Stefan

“…Recently, it was shown that Piers’ borane [HB(C6F5)2]2 can induce rapid oligomerization reactions of arylacetylenes and arylallenes. Using phenylallene…”
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Improved Hydrogen Production of Au-Pt-CdS Hetero-Nanostructures by Efficient Plasmon-Induced Multipathway Electron Transfer by Ma, Liang, Chen, Kai, Nan, Fan, Wang, Jia-Hong, Yang, Da-Jie, Zhou, Li, Wang, Qu-Quan

“…The design of new functional materials with excellent hydrogen production activity under visible‐light irradiation has critical significance for solving the…”
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Photoredox Catalyzed Single C−F Bond Activation of Trifluoromethyl Ketones: A Solvent Controlled Divergent Access of gem‐Difluoromethylene Containing Scaffolds by Ghosh, Soumen, Qu, Zheng‐Wang, Roy, Sourav, Grimme, Stefan, Chatterjee, Indranil

“…Selective defluorinative functionalization of trifluoromethyl ketones is a long‐standing challenge owing to the exhaustive mode of the process. To meet the…”
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Biodegradable near-infrared-photoresponsive shape memory implants based on black phosphorus nanofillers by Xie, Hanhan, Shao, Jundong, Ma, Yufei, Wang, Jiahong, Huang, Hao, Yang, Na, Wang, Huaiyu, Ruan, Changshun, Luo, Yanfeng, Wang, Qu-Quan, Chu, Paul K., Yu, Xue-Feng

“…In this paper, we propose a new shape memory polymer (SMP) composite with excellent near-infrared (NIR)-photoresponsive shape memory performance and…”
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Controlled Growth of Hierarchical Bi2Se3/CdSe‐Au Nanorods with Optimized Photothermal Conversion and Demonstrations in Photothermal Therapy by Liu, Xiao‐Dan, Chen, Bei, Wang, Gang‐Gang, Ma, Song, Cheng, Li, Liu, Wei, Zhou, Li, Wang, Qu‐Quan

“…Integrating multiple mechanisms to maximize photothermal conversion efficiency is a significant strategy but remains challenging to construct therapeutic…”
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Metabolizable Ultrathin Bi2Se3 Nanosheets in Imaging-Guided Photothermal Therapy by Xie, Hanhan, Li, Zhibin, Sun, Zhengbo, Shao, Jundong, Yu, Xue-Feng, Guo, Zhinan, Wang, Jiahong, Xiao, Quanlan, Wang, Huaiyu, Wang, Qu-Quan, Zhang, Han, Chu, Paul K.

“…Poly(vinylpyrrolidone)‐encapsulated Bi2Se3 nanosheets with a thickness of 1.7 nm and diameter of 31.4 nm are prepared by a solution method. Possessing an…”
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Alkali Metal Species in the Reversible Activation of H2 by Xu, Maotong, Jupp, Andrew R., Qu, Zheng‐Wang, Stephan, Douglas W.

“…MP(tBu)2 (M=Li, Na, K), KH and KN(SiMe3)2 are shown to activate HD reversibly. In the case of MP(tBu)2 this leads to isotopic scrambling and the formation of…”
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Discrimination of the Enantiotopic Faces of Structurally Unbiased Carbenium Ions Employing a Cyclohexadiene‐Based Chiral Hydride Source by Wolff, Benedikt, Qu, Zheng‐Wang, Grimme, Stefan, Oestreich, Martin

“…An enantioselective reduction of simple carbenium ions with cyclohexadienes containing a hydridic C−H bond at an asymmetrically substituted carbon atom is…”
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Reactions of a Dilithiomethane with CO and N2O: An Avenue to an Anionic Ketene and a Hexafunctionalized Benzene by Xu, Maotong, Wang, Tongtong, Qu, Zheng‐Wang, Grimme, Stefan, Stephan, Douglas W.

“…Synthesis of value‐added products from simple C1 feedstocks is an attractive alternative avenue to traditional fossil fuels. Hexa‐substituted benzene…”
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Mechanistic Insights for Nitromethane Activation into Reactive Nitrogenating Reagents by Qu, Zheng‐Wang, Zhu, Hui, Grimme, Stefan

“…Recently, it was found that nitromethane (CH3NO2) can be activated into a useful nitrogenating reagent for the synthesis of amide and nitrile compounds. In…”
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Reduction of Phosphine Oxide by Using Chlorination Reagents and Dihydrogen: DFT Mechanistic Insights by Zhu, Hui, Qu, Zheng‐Wang, Grimme, Stefan

“…Extensive DFT calculations provide detailed mechanistic insights into the metal‐free reduction of phosphine oxide Ph3P=O by using chlorination reagents O=CClX…”
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Catalytic Isomerization of Unprotected Mesoionic N‐Heterocyclic Olefins and Their Lewis Adducts by Qu, Zheng‐Wang, Zhu, Hui, Streubel, Rainer, Grimme, Stefan

“…Recently, novel C5‐position‐unprotected mesoionic N‐heterocyclic olefins (mNHOs) demonstrated interesting reactivity with various Lewis acids during…”
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Acid‐Catalyzed Carbene Transfer from Diazo Compounds: Carbocation versus Carbene as Key Intermediate by Qu, Zheng‐Wang, Zhu, Hui, Grimme, Stefan

“…An efficient mechanism for the acid‐catalyzed formal carbene transfer from diazo compounds to nucleophilic substrates is disclosed by DFT calculations. In…”
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A Spatial-Temporal Positioning Algorithm Using Residual Network and LSTM by Wang, Rongrong, Luo, Haiyong, Wang, Qu, Li, Zhaohui, Zhao, Fang, Huang, Jingyu

“…With the ever-increasing demand for location-based services in the indoor environments, Wi-Fi-based positioning technology has attracted much attention in…”
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The Inhibitors of CDK4/6 from a Library of Marine Compound Database: A Pharmacophore, ADMET, Molecular Docking and Molecular Dynamics Study by Luo, Lianxiang, Wang, Qu, Liao, Yinglin

“…CDK4/6 (Cyclin-dependent kinases 4/6) are the key promoters of cell cycle transition from G1 phase to S phase. Thus, selective inhibition of CDK4/6 is a…”
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Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides by Wang, Tongtong, Xu, Maotong, Jupp, Andrew R., Qu, Zheng‐Wang, Grimme, Stefan, Stephan, Douglas W.

“…The frustrated Lewis pair (FLP) derived from 2,6‐lutidine and B(C6F5)3 is shown to mediate the catalytic hydrogenation of CO2 using H2 as the reductant and a…”
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