Search Results - "Wang, Pu‐Sheng"

Palladium-Catalyzed Asymmetric Allylic C–H Functionalization: Mechanism, Stereo- and Regioselectivities, and Synthetic Applications by Wang, Pu-Sheng, Gong, Liu-Zhu

“…Conspectus Asymmetric functionalization of inert C–H bonds is undoubtedly a synthetically significant yet challenging bond-forming process, allowing for the…”
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Access to Chiral Hydropyrimidines through Palladium‐Catalyzed Asymmetric Allylic C−H Amination by Wang, Pu‐Sheng, Shen, Meng‐Lan, Wang, Tian‐Ci, Lin, Hua‐Chen, Gong, Liu‐Zhu

“…A palladium‐catalyzed asymmetric intramolecular allylic C−H amination controlled by a chiral phosphoramidite ligand was established for the preparation of…”
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Enantioconvergent Palladium‐Catalyzed Alkylation of Tertiary Allylic C−H Bonds by Nong, Zhong‐Sheng, Chen, Xin‐Ran, Wang, Pu‐Sheng, Hong, Xin, Gong, Liu‐Zhu

“…Enantioconvergent catalysis enables the conversion of racemic molecules into a single enantiomer in perfect yield and is considered an ideal approach for…”
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Palladium‐Catalyzed Branch‐ and Z‐Selective Allylic C−H Amination with Aromatic Amines by Liu, Rui, Shen, Meng‐Lan, Fan, Lian‐Feng, Zhou, Xiao‐Le, Wang, Pu‐Sheng, Gong, Liu‐Zhu

“…Allylamines are important building blocks in the synthesis of bioactive compounds. The direct coupling of allylic C−H bonds and commonly available amines is a…”
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Light-Mediated Chiral Phosphate Catalysis for Asymmetric Dicarbofunctionalization of Enamides by Shen, Yang, Shen, Meng-Lan, Wang, Pu-Sheng

“…A light-mediated asymmetric dicarbofunctionalization of enamides with carboxylic-acid-derived redox-active esters (RAEs) and indoles has been established by…”
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Nucleophile Coordination Enabled Regioselectivity in Palladium‐Catalyzed Asymmetric Allylic C−H Alkylation by Fan, Lian‐Feng, Luo, Shi‐Wei, Chen, Shu‐Sen, Wang, Tian‐Ci, Wang, Pu‐Sheng, Gong, Liu‐Zhu

“…Branched selectivity in asymmetric allylic C−H alkylation is enabled by using 2‐acylimidazoles as nucleophiles in the presence of a chiral…”
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Nucleophile-Dependent Z/E- and Regioselectivity in the Palladium-Catalyzed Asymmetric Allylic C–H Alkylation of 1,4-Dienes by Lin, Hua-Chen, Xie, Pei-Pei, Dai, Zhen-Yao, Zhang, Shuo-Qing, Wang, Pu-Sheng, Chen, Yu-Gen, Wang, Tian-Ci, Hong, Xin, Gong, Liu-Zhu

“…The asymmetric allylic alkylation (AAA), which features employing active allylic substrates, has historical significance in organic synthesis. The allylic C–H…”
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Chiral Counteranion Strategy for Asymmetric Oxidative C(sp3)H/C(sp3)H Coupling: Enantioselective α-Allylation of Aldehydes with Terminal Alkenes by Wang, Pu-Sheng, Lin, Hua-Chen, Zhai, Yu-Jia, Han, Zhi-Yong, Gong, Liu-Zhu

“…The first enantioselective α‐allylation of aldehydes with terminal alkenes has been realized by combining asymmetric counteranion catalysis and…”
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Pd‐Catalyzed Asymmetric Allylic C—H Functionalization by Wang, Pu‐Sheng, Gong, Liu‐Zhu

“…Comprehensive Summary Pd‐catalyzed asymmetric allylic C—H functionalization has emerged as a powerful tool to access chiral, densely functionalized molecules…”
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Asymmetric Allylic C–H Oxidation for the Synthesis of Chromans by Wang, Pu-Sheng, Liu, Peng, Zhai, Yu-Jia, Lin, Hua-Chen, Han, Zhi-Yong, Gong, Liu-Zhu

“…An enantioselective intramolecular allylic C–H oxidation to generate optically active chromans has been accomplished under the cooperative catalysis of a…”
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Palladium-catalyzed asymmetric allylic C-H alkylation of 1,4-dienes and glycine Schiff bases by Wang, Tian-Ci, Wang, Pu-Sheng, Gong, Liu-Zhu

“…A highly regio- and enantioselective allylic C-H alkylation of 1,4-dienes with glycine Schiff bases has been established by chiral palladium-phosphoramidite…”
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An Organocatalytic Asymmetric Allylic Alkylation Allows Enantioselective Total Synthesis of Hydroxymetasequirin‑A and Metasequirin‑B Tetramethyl Ether Diacetates by Wang, Pu-Sheng, Zhou, Xiao-Le, Gong, Liu-Zhu

“…The first highly stereoselective organocatalytic intermolecular allylic alkylation of allylic alcohols with 1,3-dicarbonyls has been developed to allow the…”
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Palladium-catalyzed Asymmetric Allylic C–H Oxidation for the Formal Synthesis of Gonytolide C by Liu, Peng, Wang, Pu-Sheng

“…For the synthesis of Gonytolide C, an enantioselective intramolecular allylic C–H oxidation was applied to afford the chiral chroman framework in good yield…”
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An Enantioselective Multicomponent Carbonyl Allylation of Aldehydes with Dienes and Alkynyl Bromides Enabled by Chiral Palladium Phosphate by Shen, Hong‐Cheng, Wang, Pu‐Sheng, Tao, Zhong‐Lin, Han, Zhi‐Yong, Gong, Liu‐Zhu

“…An enantioselective multicomponent carbonyl allylation reaction of 1,3‐butadienes, alkynyl bromides and aldehydes has been established, leading to the…”
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Differentially expressed lncRNAs and mRNAs identified by NGS analysis in colorectal cancer patients by Li, Meng, Zhao, Lian‐mei, Li, Suo‐lin, Li, Jing, Gao, Bo, Wang, Fei‐fei, Wang, Sheng‐pu, Hu, Xu‐hua, Cao, Jian, Wang, Gui‐ying

“…Long noncoding RNAs (lncRNAs) play an important role in gene regulation, but their impact on the pathogenesis of colorectal cancer and the biological function…”
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Enantioselective concomitant creation of vicinal quaternary stereogenic centers via cyclization of alkynols triggered addition of azlactones by Han, Zhi-Yong, Guo, Rui, Wang, Pu-Sheng, Chen, Dian-Feng, Xiao, Han, Gong, Liu-Zhu

“…An asymmetric cyclization of alkynols triggered addition of azlactones catalyzed by a combined catalyst system consisting of a chiral gold phosphate and a…”
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Enantioselective Relay Catalytic Cascade Intramolecular Hydrosiloxylation and Mukaiyama Aldol Reaction by Wang, Pu-Sheng, Li, Kang-Nan, Zhou, Xiao-Le, Wu, Xiang, Han, Zhi-Yong, Guo, Rui, Gong, Liu-Zhu

“…Cascading chemistry! The first practical relay catalytic cascade intramolecular hydrosiloxylation of arylacetylene and asymmetric Mukaiyama aldol reaction has…”
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Modular access to chiral cyclopentanes via formal [2+2+1] annulation enabled by palladium/chiral squaramide relay catalysis by Fan, Lian-Feng, Liu, Rui, Wang, Pu-Sheng, Gong, Liu-Zhu

“…An enantio- and diastereodivergent [2+2+1] annulation reaction of allyl ketones, acidic methylene compounds, and nitroalkenes to assemble highly functionalized…”
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Asymmetric Photocatalytic C(sp3)–H Bond Addition to α‑Substituted Acrylates by Dai, Zhen-Yao, Nong, Zhong-Sheng, Song, Shun, Wang, Pu-Sheng

“…Asymmetric functionalization of inert C­(sp3)–H bonds is a straightforward approach to realize versatile bond-forming events, allowing the precise assembly of…”
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Light-Mediated Asymmetric Aliphatic C–H Alkylation with Hydrogen Atom Transfer Catalyst and Chiral Phosphoric Acid by Dai, Zhen-Yao, Nong, Zhong-Sheng, Wang, Pu-Sheng

“…In the presence of tetrabutylammonium decatungstate and chiral spiro phosphoric acid, a light-mediated asymmetric C–H functionalization of unactivated…”
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