Search Results - "Wang, David Y."
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Enantioselective Photoredox Catalysis Enabled by Proton-Coupled Electron Transfer: Development of an Asymmetric Aza-Pinacol Cyclization
Published in Journal of the American Chemical Society (27-11-2013)“…The first highly enantioselective catalytic protocol for the reductive coupling of ketones and hydrazones is reported. These reactions proceed through neutral…”
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Olefin Isomerization by Iridium Pincer Catalysts. Experimental Evidence for an η3-Allyl Pathway and an Unconventional Mechanism Predicted by DFT Calculations
Published in Journal of the American Chemical Society (15-08-2012)“…The isomerization of olefins by complexes of the pincer-ligated iridium species ( tBuPCP)Ir ( tBuPCP = κ3-C6H3-2,6-(CH2P t Bu2)2) and ( tBuPOCOP)Ir ( tBuPOCOP…”
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3
Net Oxidative Addition of C(sp3)-F Bonds to Iridium via Initial C-H Bond Activation
Published in Science (American Association for the Advancement of Science) (24-06-2011)“…Carbon-fluorine bonds are the strongest known single bonds to carbon and as a consequence can prove very hard to cleave. Alhough vinyl and aryl C-F bonds can…”
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Assessment of the Electronic Factors Determining the Thermodynamics of “Oxidative Addition” of C–H and N–H Bonds to Ir(I) Complexes
Published in Journal of the American Chemical Society (13-01-2016)“…A study of electronic factors governing the thermodynamics of C–H and N–H bond addition to Ir(I) complexes was conducted. DFT calculations were performed on…”
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5
Origin of Regioselectivity in the Dehydrogenation of Alkanes by Pincer–Iridium Complexes: A Combined Experimental and Computational Study
Published in ACS catalysis (01-10-2021)“…PCP-pincer (κ3-2,6-C6H3(CH2PR2)2) iridium complexes have been reported to catalyze the transfer dehydrogenation of n-alkanes with high regioselectivity for the…”
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Synthesis and Characterization of Carbazolide-Based Iridium PNP Pincer Complexes. Mechanistic and Computational Investigation of Alkene Hydrogenation: Evidence for an Ir(III)/Ir(V)/Ir(III) Catalytic Cycle
Published in Journal of the American Chemical Society (07-05-2014)“…New carbazolide-based iridium pincer complexes (carbPNP)Ir(C2H4), 3a, and (carbPNP)Ir(H)2, 3b, have been prepared and characterized. The dihydride, 3b,…”
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Olefin Hydroaryloxylation Catalyzed by Pincer–Iridium Complexes
Published in Journal of the American Chemical Society (09-10-2013)“…Aryl alkyl ethers, which are widely used throughout the chemical industry, are typically produced via the Williamson ether synthesis. Olefin hydroaryloxylation…”
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Preparation, characterization, stability, and controlled release of chitosan-coated zein/shellac nanoparticles for the delivery of quercetin
Published in Food chemistry (30-06-2024)“…[Display omitted] •Quercetin-loaded zein/shellac nanoparticles with chitosan coatings (QZSC) were prepared.•QZSC with a ratio of 4:1 of zein and chitosan…”
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Using Smart Meter Data to Improve the Accuracy of Intraday Load Forecasting Considering Customer Behavior Similarities
Published in IEEE transactions on smart grid (01-03-2015)“…With the deployment of advanced metering infrastructure (AMI), an avalanche of new energy-use information became available. Better understanding of the actual…”
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Cyclic Boronates Inhibit All Classes of β-Lactamases
Published in Antimicrobial agents and chemotherapy (01-04-2017)“…β-Lactamase-mediated resistance is a growing threat to the continued use of β-lactam antibiotics. The use of the β-lactam-based serine-β-lactamase (SBL)…”
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Cleavage of Ether, Ester, and Tosylate C(sp3)–O Bonds by an Iridium Complex, Initiated by Oxidative Addition of C–H Bonds. Experimental and Computational Studies
Published in Journal of the American Chemical Society (03-04-2013)“…A pincer-ligated iridium complex, (PCP)Ir (PCP = κ3-C6H3-2,6-[CH2P(t-Bu)2]2), is found to undergo oxidative addition of C(sp3)–O bonds of methyl esters…”
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Crotonases: Nature’s Exceedingly Convertible Catalysts
Published in ACS catalysis (06-10-2017)“…The crotonases comprise a widely distributed enzyme superfamily that has multiple roles in both primary and secondary metabolism. Many crotonases employ…”
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Autosomal Trisomy and Triploidy Are Corrected During Female Meiosis in Caenorhabditis elegans
Published in Genetics (Austin) (01-11-2017)“…Trisomy and triploidy, defined as the presence of a third copy of one or all chromosomes, respectively, are deleterious in many species including humans…”
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14
Structure activity relationship studies on rhodanines and derived enethiol inhibitors of metallo-β-lactamases
Published in Bioorganic & medicinal chemistry (15-07-2018)“…[Display omitted] Metallo-β-lactamases (MBLs) enable bacterial resistance to almost all classes of β-lactam antibiotics. We report studies on enethiol…”
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15
Stock dividends in China: signalling or liquidity explanations?
Published in Accounting and finance (Parkville) (01-06-2013)“…We test alternative hypotheses on a sample of Chinese stock dividends. The inverse Mills ratio, a signal about future performance, is positively related to…”
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13 C-Carbamylation as a mechanistic probe for the inhibition of class D β-lactamases by avibactam and halide ions
Published in Organic & biomolecular chemistry (19-07-2017)“…The class D (OXA) serine β-lactamases are a major cause of resistance to β-lactam antibiotics. The class D enzymes are unique amongst β-lactamases because they…”
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Mxene-based wearable self-powered and photothermal triboelectric nanogenerator patches for wound healing acceleration and tactile sensing
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-02-2024)“…[Display omitted] •The MXene-based wearable triboelectric nanogenerator (TENG) was applied for wound healing acceleration.•With both photothermal heating and…”
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Towards superhydrophobic coatings via thiol-ene post-modification of polymeric submicron particles
Published in Applied surface science (30-08-2018)“…[Display omitted] •Superhydrophobic coatings were achieved via the assembly of surface functionalized polymer (PVDF) microparticles.•Thiol-ene “Click” reaction…”
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Application of self powered black phosphorus nanosheets-based hydrogel skin patch in wound healing of diabetes
Published in Nano energy (01-12-2024)“…Diabetes mellitus-related chronic non-healing wounds have greatly lowered the quality of life for people afflicted and placed a heavy financial burden on the…”
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Reactive oxygen species-responsive nanotherapy for the prevention and treatment of cerebral ischemia–reperfusion injury
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-08-2024)“…•A Cu4.6O NP-based platelet membrane-coated nanoplatform (MDzCu) was developed.•Both Cu4.6O and DHA were released from the nanoplatform in the ROS-rich…”
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