Search Results - "Wakihara, Toru"
-
1
Functional Mesoporous Silica Nanomaterials for Catalysis and Environmental Applications
Published in Bulletin of the Chemical Society of Japan (15-12-2020)“…Silica materials are used in a wide range of applications such as catalysis, photocatalysis, CO2 capture, and environmental remediation. These nanomaterials…”
Get full text
Journal Article -
2
Nanoarchitectured Metal Phosphates and Phosphonates: A New Material Horizon toward Emerging Applications
Published in Chemistry of materials (13-08-2019)“…Metal phosphate- and phosphonate-based nanoarchitectured materials offer a unique opportunity to design hierarchically porous nanomaterials consisting of…”
Get full text
Journal Article -
3
Concerted Bimetallic Nanocluster Synthesis and Encapsulation via Induced Zeolite Framework Demetallation for Shape and Substrate Selective Heterogeneous Catalysis
Published in Angewandte Chemie (International ed.) (28-05-2018)“…Bimetallic nanoparticle encapsulation in microporous zeolite crystals is a promising route for producing catalysts with unprecedented reaction selectivities…”
Get full text
Journal Article -
4
Recent progress in the improvement of hydrothermal stability of zeolites
Published in Chemical science (Cambridge) (14-06-2021)“…Zeolites have been successfully employed in many catalytic reactions of industrial relevance. The severe conditions required in some processes, where high…”
Get full text
Journal Article -
5
Structure-Directing Behaviors of Tetraethylammonium Cations toward Zeolite Beta Revealed by the Evolution of Aluminosilicate Species Formed during the Crystallization Process
Published in Journal of the American Chemical Society (18-11-2015)“…Organic structure-directing agents (OSDAs) have been widely used for the synthesis of zeolites. In most cases, OSDAs are occluded in zeolites as an isolated…”
Get full text
Journal Article -
6
Understanding the high hydrothermal stability and NH3-SCR activity of the fast-synthesized ERI zeolite
Published in Journal of catalysis (01-11-2020)“…The fast-synthesized Cu-ERI with a proper copper loading exhibited unprecedented high NH3-SCR activity even after severe hydrothermal aging, which is even…”
Get full text
Journal Article -
7
Reaction Kinetics Regulated Formation of Short-Range Order in an Amorphous Matrix during Zeolite Crystallization
Published in Journal of the American Chemical Society (28-07-2021)“…The crystallization of zeolites, a disorder-to-order transformation of aluminosilicates, has not been thoroughly understood because the nucleation events in…”
Get full text
Journal Article -
8
Improve the Hydrothermal Stability of Cu-SSZ-13 Zeolite Catalyst by Loading a Small Amount of Ce
Published in ACS catalysis (05-10-2018)“…Copper-ion-exchanged SSZ-13 has been demonstrated to be an effective catalyst for the ammonia selective catalytic reduction of NO x . However, the Cu-SSZ-13 is…”
Get full text
Journal Article -
9
Improving mechanical stability of ZSM-5 zeolite by defect-healing treatment
Published in Microporous and mesoporous materials (15-05-2024)“…Aluminosilicate zeolites are a group of microporous materials widely used in numerous technical applications as catalysts, adsorbents and ion exchangers…”
Get full text
Journal Article -
10
Crystallization Behavior of Zeolite Beta in OSDA-Free, Seed-Assisted Synthesis
Published in Journal of physical chemistry. C (27-01-2011)“…Recent reports on the organic structure-directing agent (OSDA)-free synthesis of some zeolites with the aid of seed crystals have opened a new way to the…”
Get full text
Journal Article -
11
Understanding the Nucleation and Crystal Growth of Zeolites: A Case Study on the Crystallization of ZSM‑5 from a Hydrogel System Under Ultrasonication
Published in Journal of physical chemistry. C (28-05-2020)“…For the preparation of zeolites, ultrasonication is an efficient pretreatment that homogenizes the reactant mixture prior to hydrothermal synthesis. However,…”
Get full text
Journal Article -
12
Structural Evolution of Amorphous Precursors toward Crystalline Zeolites Visualized by an in Situ X‑ray Pair Distribution Function Approach
Published in Journal of physical chemistry. C (21-11-2019)“…Zeolites are microporous aluminosilicate materials that have been used as industrial catalysts and adsorbents. The mechanism of formation of crystalline…”
Get full text
Journal Article -
13
Toward Efficient Synthesis of Chiral Zeolites: A Rational Strategy for Fluoride‐Free Synthesis of STW‐Type Zeolite
Published in Angewandte Chemie International Edition (02-11-2020)“…The STW‐type zeolite is attractive for developing novel enantioselective syntheses/separation of chiral compounds because it is the only chiral zeolitic…”
Get full text
Journal Article -
14
Widening Synthesis Bottlenecks: Realization of Ultrafast and Continuous-Flow Synthesis of High-Silica Zeolite SSZ-13 for NOx Removal
Published in Angewandte Chemie International Edition (04-05-2015)“…Characteristics of zeolite formation, such as being kinetically slow and thermodynamically metastable, are the main bottlenecks that obstruct a fast zeolite…”
Get full text
Journal Article -
15
Dense Integration of Stable Aromatic Radicals within the Two-Dimensional Interlayer Space of Clay Minerals via Clay-Catalyzed Deamination of Arylammoniums
Published in Chemistry of materials (27-10-2020)“…Here, we have successfully demonstrated the dense integration of aryl radical cations within two-dimensional interlayer nanospace of abundant magnesium…”
Get full text
Journal Article -
16
Mechanism of Al Coordination Change in Alkaline-earth Aluminosilicate Glasses: An Application of Bond Valence Model
Published in ISIJ International (15-07-2023)“…Aluminum cations are generally present in four-fold ([4]Al3+) or five-fold coordination ([5]Al3+) in aluminosilicate slags, where the concentration of [5]Al3+…”
Get full text
Journal Article -
17
Encapsulation of Molybdenum Carbide Nanoclusters inside Zeolite Micropores Enables Synergistic Bifunctional Catalysis for Anisole Hydrodeoxygenation
Published in ACS catalysis (01-12-2017)“…Molybdenum carbide (MoC x ) nanoclusters were encapsulated inside the micropores of aluminosilicate FAU zeolites to generate highly active and selective…”
Get full text
Journal Article -
18
Broadening synthetic scope of SSZ-39 zeolite for NH3-SCR: A fast and direct route from amorphous starting materials
Published in Microporous and mesoporous materials (01-01-2022)“…The inevitable use of FAU-type zeolites and long synthesis time bottleneck the mass production of SSZ-39 zeolite, a next-generation catalyst for selective…”
Get full text
Journal Article -
19
Ultrafast synthesis of BEA zeolite without the aid of aging pretreatment
Published in Microporous and mesoporous materials (15-09-2018)“…The present study focuses on the ultrafast synthesis of *BEA zeolite, which constitutes one of the most industrially important zeolites. A pure *BEA phase was…”
Get full text
Journal Article -
20
Continuous flow synthesis of ZSM-5 zeolite on the order of seconds
Published in Proceedings of the National Academy of Sciences - PNAS (13-12-2016)“…The hydrothermal synthesis of zeolites carried out in batch reactors takes a time so long (typically, on the order of days) that the crystallization of…”
Get full text
Journal Article