Search Results - "Wadsworth, Brian L."
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Electrocatalytic Properties of Binuclear Cu(II) Fused Porphyrins for Hydrogen Evolution
Published in ACS catalysis (05-10-2018)“…Binuclear copper(II) porphyrins in which two copper(II) porphyrin macrocycles are doubly fused at the meso-beta positions are shown to be active…”
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2
Electron–Nuclear Dynamics Accompanying Proton-Coupled Electron Transfer
Published in Journal of the American Chemical Society (03-03-2021)“…Although photoinduced proton-coupled electron transfer (PCET) plays an essential role in photosynthesis, a full understanding of the mechanism is still lacking…”
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3
Molecular-Modified Photocathodes for Applications in Artificial Photosynthesis and Solar-to-Fuel Technologies
Published in Chemical reviews (09-11-2022)“…Nature offers inspiration for developing technologies that integrate the capture, conversion, and storage of solar energy. In this review article, we highlight…”
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4
Expanding the Redox Range of Surface-Immobilized Metallocomplexes Using Molecular Interfaces
Published in ACS applied materials & interfaces (22-01-2020)“…Rationally designed material interfaces offer opportunities to control matter and energy across multiple length scales, yet remain challenging to synthetically…”
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5
Interplay between Light Flux, Quantum Efficiency, and Turnover Frequency in Molecular-Modified Photoelectrosynthetic Assemblies
Published in Journal of the American Chemical Society (09-10-2019)“…We report on the interplay between light absorption, charge transfer, and catalytic activity at molecular-catalyst-modified semiconductor liquid junctions…”
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6
Proton-Coupled Electron Transfer Drives Long-Range Proton Translocation in Bioinspired Systems
Published in Journal of the American Chemical Society (11-09-2019)“…Proton-coupled electron transfer (PCET) combines the movement of fundamental charged species to form an essential link between electron- and proton-transport…”
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7
Controlling Proton-Coupled Electron Transfer in Bioinspired Artificial Photosynthetic Relays
Published in Journal of the American Chemical Society (14-11-2018)“…Bioinspired constructs consisting of benzimidazole-phenol moieties bearing N-phenylimines as proton-accepting substituents have been designed to mimic the…”
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8
Electrocatalytic and Optical Properties of Cobaloxime Catalysts Immobilized at a Surface-Grafted Polymer Interface
Published in ACS catalysis (02-12-2016)“…We report on the electrocatalytic and optical properties of cobaloxime hydrogen production catalysts assembled on a polymer-modified nanostructured indium tin…”
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9
Role of Intact Hydrogen-Bond Networks in Multiproton-Coupled Electron Transfer
Published in Journal of the American Chemical Society (30-12-2020)“…The essential role of a well-defined hydrogen-bond network in achieving chemically reversible multiproton translocations triggered by one-electron…”
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10
Proton-coupled electron transfer across benzimidazole bridges in bioinspired proton wires
Published in Chemical science (Cambridge) (15-04-2020)“…Designing molecular platforms for controlling proton and electron movement in artificial photosynthetic systems is crucial to efficient catalysis and solar…”
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11
Understanding and Controlling the Performance-Limiting Steps of Catalyst-Modified Semiconductors
Published in The journal of physical chemistry letters (14-01-2021)“…Understanding and controlling factors that restrict the rates of fuel-forming reactions are essential to designing effective catalyst-modified semiconductors…”
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12
Concerted Electron-Nuclear Motion in Proton-Coupled Electron Transfer-Driven Grotthuss-Type Proton Translocation
Published in The journal of physical chemistry letters (26-05-2022)“…Photoinduced proton-coupled electron transfer and long-range two-proton transport via a Grotthuss-type mechanism are investigated in a biomimetic construct…”
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13
Photoelectrochemistry of metalloporphyrin-modified GaP semiconductors
Published in Photosynthesis research (01-02-2022)“…Photoelectrosynthetic materials provide a bioinspired approach for using the power of the sun to produce fuels and other value-added chemical products…”
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14
Six‐Electron Chemistry of a Binuclear Fe(III) Fused Porphyrin
Published in ChemElectroChem (01-10-2021)“…In this special collection dedicated to Prof. Jean‐Michel Savéant, we report on the synthesis and characterization of a novel binuclear Fe(III) fused…”
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15
Addressing the Origin of Photocurrents and Fuel Production Activities in Catalyst-Modified Semiconductor Electrodes
Published in ACS applied energy materials (24-08-2020)“…The direct integration of electrocatalysts with photovoltaic materials provides a strategy to photoelectrochemically power chemical transformations and store…”
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16
Understanding and Controlling the Performance-Limiting Steps of Catalyst-Modified Semiconductors
Published in The journal of physical chemistry letters (16-12-2020)“…Understanding and controlling factors that restrict the rates of fuel-forming reactions are essential to designing effective catalyst-modified semiconductors…”
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17
Photoelectrochemistry of metalloporphyrin-modified GaP semiconductors
Published in Photosynthesis research (22-05-2021)“…Photoelectrosynthetic materials provide a bioinspired approach for using the power of the sun to produce fuels and other value-added chemical products…”
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Journal Article -
18
Electron–Nuclear Dynamics Accompanying Proton-Coupled Electron Transfer
Published in Journal of the American Chemical Society (18-02-2021)“…Although photoinduced proton-coupled electron transfer (PCET) plays an essential role in photosynthesis, a full understanding of the mechanism is still lacking…”
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19
Proton-coupled electron transfer across benzimidazole bridges in bioinspired proton wires
Published in Chemical science (Cambridge) (01-01-2020)“…Experimental and theoretical methods characterize the thermodynamics of electrochemically driven proton-coupled electron transfer processes in bioinspired…”
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20
Six‐Electron Chemistry of a Binuclear Fe(III) Fused Porphyrin
Published in ChemElectroChem (01-10-2021)“…Invited for this month's cover picture is the group of Prof. Gary F. Moore at Arizona State University, USA, and their collaborators, Dr. Benedikt…”
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