Search Results - "Wade, Casey R."
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Facile Deposition of Multicolored Electrochromic Metal-Organic Framework Thin Films
Published in Angewandte Chemie International Edition (09-12-2013)“…Metal–organic frameworks: The solvothermal reaction of Zn2+ ions and bis‐ (pyrazolyl)naphthalene diimide readily affords strongly adhering, electroactive…”
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2
Fluoride Ion Complexation and Sensing Using Organoboron Compounds
Published in Chemical reviews (14-07-2010)“…The complexation and sensing of fluoride ions via organoboron compounds is discussed. While fluoride in drinking water presents significant dental benefits,…”
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Sensing of Aqueous Fluoride Anions by Cationic Stibine-Palladium Complexes
Published in Angewandte Chemie International Edition (09-01-2012)“…Turn on the lantern! The stibine donor ligand of a cationic palladium complex acts as a Lewis acid and reacts with a fluoride anion to afford the corresponding…”
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Cyanide Anion Binding by a Triarylborane at the Outer Rim of a Cyclometalated Ruthenium(II) Cationic Complex
Published in Inorganic chemistry (18-01-2010)“…As part of our ongoing interest in the design of boron-based cyanide anion receptors, we have synthesized a triaryl borane decorated by a cationic Ru(II)…”
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5
Two-Electron Redox Chemistry and Reversible Umpolung of a Gold-Antimony Bond
Published in Angewandte Chemie International Edition (01-08-2011)“…A two‐way street! The two‐electron oxidation of a novel binuclear stibine gold compound induces an umpolung of the SbAu dative bond which switches from Sb→Au…”
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Guilty on Two Counts: Stepwise Coordination of Two Fluoride Anions to the Antimony Atom of a Noninnocent Stibine Ligand
Published in Organometallics (08-06-2015)“…In our efforts to investigate the coordination noninnocent behavior of transition-metal stibine complexes, we have prepared a series of platinum complexes…”
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Synthesis and Lewis Acidic Behavior of a Cationic 9-Thia-10-boraanthracene
Published in Organometallics (08-11-2010)“…As part of our efforts in the chemistry of Lewis acidic organoboron compounds, we have synthesized a cationic borane ([1]+) featuring a…”
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Mercury[rightward arrow]Antimony Interaction
Published in Angewandte Chemie (International ed.) (23-08-2010)“…Fatal attraction: As a result of a unique iodide push–stibonium pull effect, the dinuclear complex (see picture) displays an unprecedented Hg→Sb interaction…”
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Assessing the Role of Metal Identity on CO2 Adsorption in MOFs Containing M–OH Functional Groups
Published in Chemistry of materials (14-01-2020)“…Heterobimetallic analogues of CFA-1 [Zn1+z M4‑z X4(bibta)3, bibta2– = 5,5′-bibenzotriazolate, M = Co (z = 0), Ni (z = 1), Cu (z = 2.3), X = Cl–, Br–, CH3CO2 –]…”
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Insights into CO2 Adsorption in M–OH Functionalized MOFs
Published in Chemistry of materials (26-05-2020)“…A series of benzotriazolate MOFs containing nucleophilic transition metal hydroxide (M–OH) groups has been synthesized to compare the effects of framework…”
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High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal–Organic Graphene Analogue
Published in Journal of the American Chemical Society (25-06-2014)“…Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni3(HITP)2 (HITP =…”
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Using Postsynthetic X‑Type Ligand Exchange to Enhance CO2 Adsorption in Metal–Organic Frameworks with Kuratowski-Type Building Units
Published in Inorganic chemistry (16-08-2021)“…Postsynthetic modification methods have emerged as indispensable tools for tuning the properties and reactivity of metal–organic frameworks (MOFs). In…”
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13
Direct NO Reduction by a Biomimetic Iron(II) Pyrazolate MOF
Published in Angewandte Chemie International Edition (20-09-2021)“…A novel metal‐organic framework (MOF) containing one‐dimensional, Fe2+ chains bridged by dipyrazolate linkers and N,N‐dimethylformamide (DMF) ligands has been…”
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Comparative study of metal-organic frameworks synthesized via imide condensation and coordination assembly
Published in RSC advances (29-08-2024)“…A series of metal-organic frameworks (1-XDI) have been synthesized by imide condensation reactions between an amine-functionalized pentanuclear zinc cluster,…”
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Bioinspired Metal–Organic Framework for Trace CO2 Capture
Published in Journal of the American Chemical Society (10-10-2018)“…A Zn benzotriazolate metal–organic framework (MOF), [Zn(ZnO2CCH3)4(bibta)3] (1, bibta2– = 5,5′-bibenzotriazolate), has been subjected to a mild CH3CO2 –/HCO3…”
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Improved Catalytic Activity and Stability of a Palladium Pincer Complex by Incorporation into a Metal–Organic Framework
Published in Journal of the American Chemical Society (17-02-2016)“…A porous metal–organic framework Zr6O4(OH)4(L-PdX)3 (1-X) has been constructed from Pd diphosphinite pincer complexes ([L-PdX]4– = [(2,6-(OPAr2)2C6H3)PdX]4–,…”
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Rh → Sb Interactions Supported by Tris(8-quinolyl)antimony Ligands
Published in Organometallics (09-09-2024)“…The ligands tris(8-quinolyl)stibine and tris(6-methyl-8-quinolyl)stibine have been synthesized and complexed to rhodium using (MeCN)3RhCl3. The resulting…”
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18
Strong CO2 Chemisorption in a Metal–Organic Framework with Proximate Zn–OH Groups
Published in Inorganic chemistry (21-11-2022)“…A novel Zn benzotriazolate metal–organic framework (MOF), [Zn9(OAc)6(bbtm)6] (1, bbtm2– = bis(benzotriazolyl)methanone, OAc– = acetate), has been synthesized…”
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19
C2H2/CO2 Separation with a Chain‐Type Zn Pyrazolate MOF
Published in European journal of inorganic chemistry (02-01-2024)“…A novel Zn dipyrazolate metal‐organic framework (MOF), Zn(azbpz) (azbpz2−=4,4′‐azobis(3,5‐dimethylpyrazolate), has been synthesized and structurally…”
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Redox and Anion Exchange Chemistry of a Stibine-Nickel Complex: Writing the L, X, Z Ligand Alphabet with a Single Element
Published in Angewandte Chemie International Edition (18-08-2014)“…According to the covalent bond classification (CBC) method, two‐electron donors are defined as L‐type ligands, one‐electron donors as X‐type ligands, and…”
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