Search Results - "Wächtler, Erik"
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Tin(IV) Compounds with 2‑C6F4PPh2 Substituents and Their Reactivity toward Palladium(0): Formation of Tin–Palladium Complexes via Oxidative Addition
Published in Inorganic chemistry (01-05-2017)“…The tin(IV) compounds Me x Sn(2-C6F4PPh2)4–x (1, x = 1; 2, x = 2) and ClSn(2-C6F4PPh2)3 (3) were obtained from the reactions of 2-LiC6F4PPh2 with MeSnCl3…”
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2
Trivalent Antimony as L-, X-, and Z-Type Ligand: The Full Set of Possible Coordination Modes in Pt–Sb Bonds
Published in Inorganic chemistry (19-10-2020)Get full text
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3
Metallophilic Contacts in 2‑C6F4PPh2 Bridged Heterobinuclear Complexes: A Crystallographic and Computational Study
Published in Inorganic chemistry (20-07-2015)“…Treatment of the bis(chelate) complex trans-[Pd(κ2-2-C6F4PPh2)2] (7) with PMe3 gave trans-[Pd(κC-2-C6F4PPh2)2(PMe3)2] (13) as a mixture of syn- and…”
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4
Molecular structures of pyridinethiolato complexes of Sn(II), Sn(IV), Ge(IV), and Si(IV)
Published in Main group metal chemistry (01-12-2013)“…Complexes of Sn(II), Sn(IV), Ge(IV), and Si(IV) with the ambidentate pyridine-2-thiolato ligand (PyS-) were synthesized and characterized by multinuclear NMR…”
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5
Stannylene or Metallastanna(IV)ocane: A Matter of Formalism
Published in Angewandte Chemie International Edition (09-05-2011)Get full text
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6
Synthesis and Oxidation of a Paddlewheel‐Shaped Rhodium/Antimony Complex Featuring Pyridine‐2‐Thiolate Ligands
Published in Chemistry : a European journal (08-03-2017)“…The paddlewheel‐shaped complex [Sb(μ‐pyS)4Rh]2 (1) (pyS−= 2‐S‐C5H4N−) was synthesized from [Rh(pyS)(cod)]2 (cod=1,5‐cyclooctadiene) and Sb(pyS)3. Upon…”
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Dichotomy between Palladium(II)-Tin(II) and Palladium(0)-Tin(IV) in Complexes of a Sn,As-Based Chelate Ligand
Published in European journal of inorganic chemistry (01-04-2013)“…A dinuclear Pd–Sn bonded complex is reported, in which the interaction of the formally tin(II)‐based ligand, [2‐MeBrSnC6F4AsPh2]–, with palladium appears to be…”
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Compounds of the types Pn (pyS) 3 ( Pn = P, As, Bi; pyS: pyridine-2-thiolate) and Sb(pyS) x Ph 3– x ( x = 3–1); molecular structures and electronic situations of the Pn atoms
Published in Zeitschrift für Naturforschung. B, A journal of chemical sciences (23-02-2021)“…Abstract The compounds Pn (pyS) 3 ( Pn = P, As, Sb, Bi) were synthesized from the respective chloride ( Pn = P, As, Sb) or nitrate (Bi), pyridine-2-thiol…”
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Compounds of the types Pn(pyS)3 (Pn = P, As, Bi; pyS: pyridine-2-thiolate) and Sb(pyS)xPh3–x (x = 3–1); molecular structures and electronic situations of the Pn atoms
Published in Zeitschrift für Naturforschung. B, A journal of chemical sciences (01-01-2021)“…The compounds (pyS) ( = P, As, Sb, Bi) were synthesized from the respective chloride ( = P, As, Sb) or nitrate (Bi), pyridine-2-thiol (pySH) and…”
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10
Stannylen oder Metallastanna(IV)-ocan - eine Sache des Formalismus
Published in Angewandte Chemie (09-05-2011)Get full text
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11
Metallophilic Contacts in 2-C 6 F 4 PPh 2 Bridged Heterobinuclear Complexes: A Crystallographic and Computational Study
Published in Inorganic chemistry (20-07-2015)Get full text
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12
Tin(IV) Compounds with 2-C 6 F 4 PPh 2 Substituents and Their Reactivity toward Palladium(0): Formation of Tin-Palladium Complexes via Oxidative Addition
Published in Inorganic chemistry (01-05-2017)“…The tin(IV) compounds Me Sn(2-C F PPh ) (1, x = 1; 2, x = 2) and ClSn(2-C F PPh ) (3) were obtained from the reactions of 2-LiC F PPh with MeSnCl (3:1), Me…”
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13
Hypercoordinate Silacycloalkanes: Step-by-Step Tuning of N→Si Interactions
Published in Organometallics (28-09-2009)“…The silacycloalkanes (ON)2Si(CH2) n (ON = 8-oxyquinolinate, n = 3, 4, 5, 6) reveal stepwise decreasing N→Si coordination with increasing ring size. Whereas for…”
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New Insights into Hexacoordinated Silicon Complexes with 8- Oxyquinolinato Ligands: 1,3-Shift of Si-Bound Hydrocarbyl Substituents and the Influence of Si-Bound Halides on the 8-Oxyquinolinate Coordination Features
Published in Zeitschrift für Naturforschung. B, A journal of chemical sciences (01-12-2014)“…The transsilylation reaction between allyltrichlorosilane and 8-trimethylsiloxyquinoline in the molar ratio 1 : 3 yields the hexacoordinated silicon…”
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15
Stannylene or Metallastanna(IV)ocane: A Matter of Formalism
Published in Angewandte Chemie International Edition (09-05-2011)“…Pushmi‐pullyu with palladium: Although created by σ donation from SnCl2 to a PdII complex, the SnPd bonds in the compounds depicted exhibit formal σ donation…”
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Stannylen oder Metallastanna(IV)‐ocan – eine Sache des Formalismus
Published in Angewandte Chemie (09-05-2011)“…σ‐Akzeptorliganden: Obwohl aus der σ‐Donorwirkung von SnCl2 auf den PdII‐Komplex hervorgegangen, weisen die Sn‐Pd‐Bindungen in den gezeigten Verbindungen eine…”
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