Search Results - "WORTMANN, Rüdiger"
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1
Dimerization of Merocyanine Dyes. Structural and Energetic Characterization of Dipolar Dye Aggregates and Implications for Nonlinear Optical Materials
Published in Journal of the American Chemical Society (14-08-2002)“…Aggregation of polar merocyanine dyes has been identified as an important problem in the fabrication of organic materials for photonic applications. In this…”
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2
Electrochemistry and Photophysics of Donor-Substituted Triarylboranes: Symmetry Breaking in Ground and Excited State
Published in Chemistry : a European journal (01-03-2006)“…We synthesized a series of amino substituted triarylboranes (TABs) 1–3 by copper(I)‐catalyzed cross‐coupling reactions. The title compounds were investigated…”
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3
Chromophore Design for Photorefractive Organic Materials
Published in Chemphyschem (18-01-2002)“…During the last years, significant progress has been achieved in understanding the mechanism of the photorefractive effect in amorphous organic materials. New…”
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Hydrogen-Bond-Directed Head-to-Tail Orientation of Dipolar Merocyanine Dyes: A Strategy for the Design of Electrooptical Materials
Published in Angewandte Chemie International Edition (02-06-2006)“…Two merocyanine dyes are assembled by multiple hydrogen bonds with summation of their dipole moments (see formula; R=2‐ethylhexyl). It exhibits a strongly…”
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5
Synthesis and Photophysics of a Neutral Organic Mixed-Valence Compound
Published in Angewandte Chemie International Edition (05-11-2004)“…Maintaining neutrality: A perchlorinated triarylmethyl radical and a triarylamine redox center were combined in the design of a neutral organic mixed‐valence…”
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6
Three-Branched Dendritic Dipolar Nonlinear Optical Chromophores, More than Three Times a Single-Strand Chromophore?
Published in The journal of physical chemistry. B (27-11-2008)“…To elucidate the dependence of the nonlinear optical (NLO) response on the conformation of triply branched derivatives, a new series of D-π-A dendrimers has…”
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7
Electrooptical Chromophores for Nonlinear Optical and Photorefractive Applications
Published in Advanced materials (Weinheim) (01-05-1999)“…A new series of dyes for nonlinear optical (NLO) and photorefractive (PR) applications investigated by optical and electrooptical absorption spectroscopy…”
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Elongated push–pull diphenylpolyenes for nonlinear optics: molecular engineering of quadratic and cubic optical nonlinearities via tuning of intramolecular charge transfer
Published in Chemical physics (01-07-1999)“…Push–pull polyenes are of particular interest for nonlinear optics (NLO) as well as model compounds for long-distance intramolecular charge transfer (ICT). In…”
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9
Improved performance of photorefractive polymers based on merocyanine dyes in a polar matrix
Published in Applied physics letters (06-07-1998)“…Recently, chromophores with a large figure-of-merit for incorporation into photorefractive polymers with low glass-transition temperature have become…”
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10
Fluorescent H-Aggregates of Merocyanine Dyes
Published in Angewandte Chemie International Edition (27-10-2006)“…Unexpected lighting up: A slight rotational twist and rigidification of merocyanine dyes in a face‐to‐face π‐π‐stacked dimer aggregate resulted in an…”
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11
Effect of S1 Torsional Dynamics on the Time-Resolved Fluorescence Spectra of 9,9‘-Bianthryl in Solution
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (13-03-1997)“…Time-resolved fluorescence spectra of 9,9‘-bianthryl (BA) were measured in methylcyclohexane (MCH) and a Decalin−isooctane (D−ISOO) mixture at several…”
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12
Optical Properties of Spiroconjugated Charge-Transfer Dyes
Published in Journal of the American Chemical Society (14-02-1996)“…A new type of intramolecular charge-transfer dye has been prepared. The LUMO of the acceptor part (1,3-indandione) in these compounds is spiroconjugated with…”
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13
Hydrogen-Bond-Directed Head-to-Tail Orientation of Dipolar Merocyanine Dyes: A Strategy for the Design of Electrooptical Materials
Published in Angewandte Chemie (02-06-2006)“…Zwei Merocyanin‐Farbstoffe ordnen sich mithilfe mehrerer Wasserstoffbrücken unter Summation ihrer Dipolmomente an (siehe Formel; R=2‐Ethylhexyl). Durch…”
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14
Spectral and electrooptical absorption and emission studies on internally hydrogen bonded benzoxazole `double' derivatives: 2,5-bis(benzoxazolyl)hydroquinone (BBHQ) and 3,6-bis(benzoxazolyl)pyrocatechol (BBPC). Single versus double proton transfer in the excited BBPC revisited
Published in Chemical physics (15-05-1999)“…Ground and excited state dipole moments and polarizabilities of 2,5-bis(benzoxazolyl)hydroquinone (BBHQ) and 3,6-bis(benzoxazolyl)pyrocatechol (BBPC) are…”
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15
Dimers of Dipyrrometheneboron Difluoride (BODIPY) with Light Spectroscopic Applications in Chemistry and Biology
Published in Journal of the American Chemical Society (16-01-2002)“…A ground-state dimer (denoted DI ) exhibiting a strong absorption maximum at 477 nm (ε = 97 000 M-1cm-1) can form between adjacent BODIPY groups attached to…”
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16
Effect of Polarity and Structural Design on Molecular Photorefractive Properties of Heteroaromatic-Based Push-Pull Dyes
Published in Chemistry : a European journal (18-09-2006)“…A combined experimental (optical and electro‐optical absorption measurements) and computational (ab initio RHF and DFT) approach has been used to investigate…”
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A Distinctive Example of the Cooperative Interplay of Structure and Environment in Tuning of Intramolecular Charge Transfer in Second-Order Nonlinear Optical Chromophores
Published in Chemistry : a European journal (09-05-2003)“…The strongly enhanced cooperative influence of medium polarity and organic structural design on the first hyperpolarizability β of a novel family of highly…”
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18
Hexasubstituted Donor-Acceptor Benzenes as Nonlinear Optically Active Molecules with Multiple Charge-Transfer Transitions
Published in Chemistry : a European journal (05-03-2004)“…The synthesis of three novel nonlinear optical (NLO) chromophores with threefold symmetry, namely…”
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Optimized Two-Dimensional NLO Chromophores with a Threefold Symmetry Axis
Published in Angewandte Chemie International Edition (17-04-2000)“…A new NLO standard has been set by compound 1 for the substance class of analines: Their second‐order polarizability β is two orders of magnitude higher than…”
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Nonlinear optical properties of pyridinium-betaines of squaric acid: Experimental and theoretical study
Published in Chemical physics (02-06-2008)“…The linear and nonlinear optical properties of six pyridinium-betaines of squaric acid were characterized by means of electro-optical absorption measurements…”
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