Search Results - "Vyazovkin, Vladimir L."

Sorption of light gases in glassy poly(ethyl methacrylate) by Bol'shakov, Boris V., Syutkin, Vladimir M., Vyazovkin, Vladimir L., Grebenkin, Sergey

“…ABSTRACT Although gas sorption in glassy polymers is a well‐studied phenomenon, no general microscopical model is developed which is able to describe the gas…”
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On the Origin of Heterogeneous Diffusion in Glassy Poly(alkyl methacrylates) by Syutkin, Vladimir M., Vyazovkin, Vladimir L., Bol'shakov, Boris V., Grebenkin, Sergey

“…ABSTRACT The diffusion of small molecules through amorphous polymers proceeds by the thermally activated jumps whose rate changes from one region to another…”
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Oxygen Diffusion in Glassy Poly(ethyl methacrylate): Spatial Correlation of Jump Rates by Syutkin, Vladimir M., Vyazovkin, Vladimir L., Grebenkin, Sergey

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Isotope effect in diffusion of methyl radicals in glassy ethanol-1,2 d5 at low temperatures by Vyazovkin, Vladimir L., Tolkatchev, Vladimir A.

“…The kinetics of methyl radicals decay has been studied at 77 K and at 90 K in glassy mixtures 0.9( xC 2H 5OH+(1− x)C 2D 5OH)+0.1H 2O. It has been shown that in…”
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Isotope effect in diffusion of methyl radicals in glassy ethanol-1,2d5 at low temperatures by Vyazovkin, Vladimir L., Tolkatchev, Vladimir A.

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Methyl radicals migration in glassy ethanol-1,2d5 at 90 K as studied by hydrogen atom abstraction from the additives by Vyazovkin, Vladimir L., Tolkatchev, Vladimir A.

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Methyl radicals migration in glassy ethanol-1,2 d5 at 90 K as studied by hydrogen atom abstraction from the additives by Vyazovkin, Vladimir L., Tolkatchev, Vladimir A.

“…ESR technique has been used to study the kinetics of methyl radicals decay at 90K in glassy ethanol-1,2d 5 with an admixture of diethyl ether and C 2H 5OH…”
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H-atom abstraction from alcohols by alkyl radicals. Cooperative effects in the reactions of alkyl radicals in glassy methanol-d3 by Vyazovkin, Vladimir L., Tolkatchev, Vladimir A.

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