Search Results - "Vos, Dirk E. De"
-
1
Defect-Engineered Metal-Organic Frameworks
Published in Angewandte Chemie International Edition (15-06-2015)“…Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in…”
Get full text
Journal Article -
2
Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr)
Published in Journal of the American Chemical Society (07-08-2013)“…The catalytic activity of the zirconium terephthalate UiO-66(Zr) can be drastically increased by using a modulation approach. The combined use of…”
Get full text
Journal Article -
3
Electrocarboxylation: towards sustainable and efficient synthesis of valuable carboxylic acids
Published in Beilstein journal of organic chemistry (27-10-2014)“…The near-unlimited availability of CO2 has stimulated a growing research effort in creating value-added products from this greenhouse gas. This paper presents…”
Get full text
Journal Article -
4
Enhancing Metal Separations by Liquid–Liquid Extraction Using Polar Solvents
Published in Chemistry : a European journal (11-07-2019)“…The less polar phase of liquid–liquid extraction systems has been studied extensively for improving metal separations; however, the role of the more polar…”
Get full text
Journal Article -
5
Boosting the Catalytic Performance of Metal–Organic Frameworks for Steroid Transformations by Confinement within a Mesoporous Scaffold
Published in Angewandte Chemie International Edition (16-10-2017)“…Solid‐state crystallization achieves selective confinement of metal–organic framework (MOF) nanocrystals within mesoporous materials, thereby rendering active…”
Get full text
Journal Article -
6
Three-Dimensional Visualization of Defects Formed during the Synthesis of Metal-Organic Frameworks: A Fluorescence Microscopy Study
Published in Angewandte Chemie International Edition (02-01-2013)“…Imperfections in the spotlight: Fluorescence microscopy was used to detect defects in metal–organic frameworks formed during synthesis. In contrast to…”
Get full text
Journal Article -
7
Selective Removal of N-Heterocyclic Aromatic Contaminants from Fuels by Lewis Acidic Metal-Organic Frameworks
Published in Angewandte Chemie International Edition (26-04-2011)“…Bring in the cleaner! Metal–organic frameworks (MOFs) are able to separate nitrogen and sulfur contaminants from fuel, which may lead to the production of…”
Get full text
Journal Article -
8
Probing the Lewis Acidity and Catalytic Activity of the Metal-Organic Framework [Cu3(btc)2] (BTC=Benzene-1,3,5-tricarboxylate)
Published in Chemistry : a European journal (25-09-2006)“…An optimized procedure was designed for the preparation of the microporous metal–organic framework (MOF) [Cu3(btc)2] (BTC=benzene‐1,3,5‐tricarboxylate). The…”
Get full text
Journal Article -
9
Separation of C5-Hydrocarbons on Microporous Materials: Complementary Performance of MOFs and Zeolites
Published in Journal of the American Chemical Society (03-03-2010)“…This work studies the liquid-phase separation of the aliphatic C5-diolefins, mono-olefins, and paraffins, a typical feed produced by a steam cracker, with a…”
Get full text
Journal Article -
10
A Hybrid Supercapacitor based on Porous Carbon and the Metal‐Organic Framework MIL‐100(Fe)
Published in ChemElectroChem (15-07-2014)“…Composite supercapacitor electrodes based on carbon nanotubes, carbon black, and a metal–organic framework with iron(III) coordination centers [MIL‐100(Fe),…”
Get full text
Journal Article -
11
Adsorptive Characterization of the ZIF-68 Metal-Organic Framework: A Complex Structure with Amphiphilic Properties
Published in Langmuir (22-07-2014)“…In this experimental study, the adsorption behavior of the ZIF-68 heterolinked zeolitic imidazolate framework has been explored. Vapor phase adsorption…”
Get full text
Journal Article -
12
Spatially resolved observation of crystal-face-dependent catalysis by single turnover counting
Published in Nature (02-02-2006)“…Catalytic processes on surfaces have long been studied by probing model reactions on single-crystal metal surfaces under high vacuum conditions. Yet the vast…”
Get full text
Journal Article -
13
Super-Resolution Reactivity Mapping of Nanostructured Catalyst Particles
Published in Angewandte Chemie (International ed.) (23-11-2009)“…Its a small world: Nanoscale reactivity maps of working heterogeneous catalysts are recorded under in situ conditions by localizing single fluorescent reaction…”
Get full text
Journal Article -
14
Framework Breathing in the Vapour-Phase Adsorption and Separation of Xylene Isomers with the Metal-Organic Framework MIL-53
Published in Chemistry : a European journal (03-08-2009)“…Vapour‐phase adsorption and separation of the C8 alkyl aromatic compounds p‐xylene, m‐xylene, o‐xylene, and ethylbenzene has been studied on the metal–organic…”
Get full text
Journal Article -
15
Optical Encoding of Silver Zeolite Microcarriers
Published in Advanced materials (Weinheim) (05-03-2010)“…Highly resolved fluorescent patterns are generated in an individual silver‐exchanged K‐A zeolite crystal using two‐photon excitation (see figure). The high…”
Get full text
Journal Article -
16
Palladium Catalysts on Alkaline-Earth Supports for Racemization and Dynamic Kinetic Resolution of Benzylic Amines
Published in Chemistry : a European journal (01-01-2007)“…Palladium catalysts on alkaline‐earth supports were studied as new heterogeneous catalysts for racemization of chiral benzylic amines such as…”
Get full text
Journal Article -
17
Bio-Based Nitriles from the Heterogeneously Catalyzed Oxidative Decarboxylation of Amino Acids
Published in ChemSusChem (01-01-2015)“…The oxidative decarboxylation of amino acids to nitriles was achieved in aqueous solution by in situ halide oxidation using catalytic amounts of tungstate…”
Get full text
Journal Article -
18
Polyurethane Composites Recycling with Styrene-Acrylonitrile and Calcium Carbonate Recovery
Published in Materials (11-06-2024)“…The glycolysis process of flexible polyurethane foams containing styrene-acrylonitrile and calcium carbonate as fillers was explored in detail. The use of…”
Get full text
Journal Article -
19
Heterogeneous Raney Nickel and Cobalt Catalysts for Racemization and Dynamic Kinetic Resolution of Amines
Published in Advanced synthesis & catalysis (04-01-2008)“…Raney metals were studied as heterogeneous catalysts for racemization and dynamic kinetic resolution (DKR) of chiral amines, as an alternative to metals like…”
Get full text
Journal Article -
20
Electronic Effects of Linker Substitution on Lewis Acid Catalysis with Metal-Organic Frameworks
Published in Angewandte Chemie International Edition (14-05-2012)“…Functionalized linkers can greatly increase the activity of metal–organic framework (MOF) catalysts with coordinatively unsaturated sites. A clear linear…”
Get full text
Journal Article