Search Results - "Vornholt, Simon M"
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Relative Kinetics of Solid-State Reactions: The Role of Architecture in Controlling Reactivity
Published in Journal of the American Chemical Society (13-07-2022)“…Countless inorganic materials are prepared via high temperature solid-state reaction of mixtures of reagents powders. Understanding and controlling the…”
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Impedance-Based Detection of NO2 Using Ni-MOF-74: Influence of Competitive Gas Adsorption
Published in ACS applied materials & interfaces (09-08-2023)“…Chemically robust, low-power sensors are needed for the direct electrical detection of toxic gases. Metal–organic frameworks (MOFs) offer exceptional chemical…”
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In situ single-crystal synchrotron X-ray diffraction studies of biologically active gases in metal-organic frameworks
Published in Communications chemistry (01-03-2023)“…Metal-organic frameworks (MOFs) are well known for their ability to adsorb various gases. The use of MOFs for the storage and release of biologically active…”
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Node Distortions in UiO-66 Inform Negative Thermal Expansion Mechanisms: Kinetic Effects, Frustration, and Lattice Hysteresis
Published in Journal of the American Chemical Society (26-06-2024)“…In metal–organic frameworks (MOFs) the interplay between the dynamics of individual components and how these are constrained by the extended lattice can yield…”
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Dynamic two-dimensional covalent organic frameworks
Published in Nature chemistry (01-08-2024)“…Porous covalent organic frameworks (COFs) enable the realization of functional materials with molecular precision. Past research has typically focused on…”
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Separating out the middle
Published in Nature materials (01-09-2019)“…A chemically and thermally stable metal–organic framework achieves exceptional separation of styrene from a complex mixture containing larger (ethylbenzene)…”
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Unveiling Unexpected Modulator-CO2 Dynamics within a Zirconium Metal–Organic Framework
Published in Journal of the American Chemical Society (24-05-2023)“…Carbon capture, storage, and utilization (CCSU) represents an opportunity to mitigate carbon emissions that drive global anthropogenic climate change…”
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Real-Time Multiscale Imaging of Heterogeneous Multistage Reactions: Insights into Nanoscale TiO 2 Synthesis
Published in Journal of the American Chemical Society (17-04-2024)“…Hydrothermal methods are widely used to synthesize functional inorganic materials. The interplay between the reactive species, solution chemistry, and the…”
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Tailoring Hydrophobicity and Pore Environment in Physisorbents for Improved Carbon Dioxide Capture under High Humidity
Published in Journal of the American Chemical Society (14-02-2024)“…CALF-20, a Zn-triazolate-based metal–organic framework (MOF), is one of the most promising adsorbent materials for CO2 capture. However, competitive adsorption…”
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Probing Structural Transformations and Degradation Mechanisms by Direct Observation in SIFSIX-3-Ni for Direct Air Capture
Published in Journal of the American Chemical Society (13-03-2024)“…Despite global efforts to reduce carbon dioxide (CO2) emissions, continued industrialization threatens to exacerbate climate change. This work investigates…”
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11
Resolving Fast Relative Kinetics in Inorganic Solid-State Synthesis
Published in Journal of the American Chemical Society (13-12-2023)“…Solid-state syntheses are generally regarded as being slow, limited by transport, and, as such, are often only stopped to check the products after many hours…”
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In Situ Single-crystal X‑ray Diffraction Studies of Physisorption and Chemisorption of SO2 within a Metal–Organic Framework and Its Competitive Adsorption with Water
Published in Journal of the American Chemical Society (07-02-2024)“…Living on an increasingly polluted planet, the removal of toxic pollutants such as sulfur dioxide (SO2) from the troposphere and power station flue gas is…”
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Real-Time Multiscale Imaging of Heterogeneous Multistage Reactions: Insights into Nanoscale TiO2 Synthesis
Published in Journal of the American Chemical Society (17-04-2024)“…Hydrothermal methods are widely used to synthesize functional inorganic materials. The interplay between the reactive species, solution chemistry, and the…”
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15
In Situ Single-crystal X-ray Diffraction Studies of Physisorption and Chemisorption of SO 2 within a Metal-Organic Framework and Its Competitive Adsorption with Water
Published in Journal of the American Chemical Society (07-02-2024)“…Living on an increasingly polluted planet, the removal of toxic pollutants such as sulfur dioxide (SO ) from the troposphere and power station flue gas is…”
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A Titanium-Based Metal–Organic Framework For Tandem Metallaphotocatalysis
Published in ACS applied materials & interfaces (03-07-2024)“…Metal–organic frameworks (MOFs) have garnered substantial attention for their unique properties, such as high porosity and tunable structures, making them…”
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The RAPTR furnace: a rapid heating and cooling sample furnace for in situ X-ray scattering studies of temperature-induced reactions
Published in Journal of applied crystallography (01-02-2024)“…In situ X-ray scattering provides valuable insights into the mechanisms and kinetics of reactions and structural transformations. For reactions and structural…”
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Surface-Functionalized Metal–Organic Frameworks for Binding Coronavirus Proteins
Published in ACS applied materials & interfaces (14-02-2023)“…Since the outbreak of SARS-CoV-2, a multitude of strategies have been explored for the means of protection and shielding against virus particles: filtration…”
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Multifaceted Study of the Interactions between CPO-27-Ni and Polyurethane and Their Impact on Nitric Oxide Release Performance
Published in ACS applied materials & interfaces (30-12-2020)“…A multifaceted study involving focused ion beam scanning electron microscopy techniques, mechanical analysis, water adsorption measurements, and molecular…”
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Mixed Metal–Organic Framework Mixed-Matrix Membranes: Insights into Simultaneous Moisture-Triggered and Catalytic Delivery of Nitric Oxide using Cryo-scanning Electron Microscopy
Published in ACS applied materials & interfaces (25-10-2023)“…The fundamental chemical and structural diversity of metal–organic frameworks (MOFs) is vast, but there is a lack of industrial adoption of these extremely…”
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