Search Results - "Vorholt, A.J."
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Kinetic investigation of lean aqueous hydroformylation – An engineer’s view on homogeneous catalysis
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-10-2017)“…Fluctuat nec mergitur: The kinetics for the aqueous biphasic hydroformylation of 1-octene is derived in cooperating procedural aspects to accelerate the…”
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Acceleration of lean aqueous hydroformylation in an innovative jet loop reactor concept
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-12-2017)“…Rhodium in a hamster wheel: An innovative jet loop reactor concept is applied to the lean aqueous biphasic hydroformylation of long chain olefins. The…”
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Recyclable homogeneous catalyst for the hydroesterification of methyl oleate in thermomorphic solvent systems
Published in Chemical engineering science (09-08-2013)“…In the development of commodity markets alternatives to fossil resources are of high interest. One alternative is the usage of oleo compounds. In this paper an…”
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Isomerization/hydroformylation tandem reaction of a decene isomeric mixture with subsequent catalyst recycling in thermomorphic solvent systems
Published in Applied catalysis. A, General (25-02-2017)“…[Display omitted] •Development of a selective isomerization/hydroformylation tandem reaction of a technical grade decene isomeric mixture.•The…”
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Homogeneously catalyzed hydroamination in a Taylor–Couette reactor using a thermormorphic multicomponent solvent system
Published in Chemical engineering research & design (01-08-2016)“…•Catalyst recycling of a palladium catalyst via a thermomorphic solvent system.•Theoretically supported design of the solvent system by PC-SAFT.•First…”
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Process development of the continuously operated synthesis of N,N-dimethylformamide based on carbon dioxide
Published in Journal of CO2 utilization (01-12-2017)“…[Display omitted] •A process is developed for the synthesis of N,N-dimethylformamide based on CO2.•The immobilization of a homogeneous catalyst in a nonpolar…”
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Reductive hydroformylation with a selective and highly active rhodium amine system
Published in Journal of catalysis (01-08-2021)“…[Display omitted] •Direct synthesis of alcohols from olefins via reductive hydroformylation using Rh/trialkylamine catalysts.•Extensive study of role of the…”
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Toward Water-Based Recycling Techniques: Methodologies for Homogeneous Catalyst Recycling in Liquid/Liquid Multiphase Media and Their Implementation in Continuous Processes
Published in Industrial & engineering chemistry research (20-02-2019)“…Biphasic water-based solvent systems offer the opportunity of efficient recycling of homogeneous catalysts. Water separates well from most organic solvents;…”
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Considerations on film reactivity in the aqueous biphasic hydroformylation
Published in AIChE journal (01-01-2018)“…In experiments and kinetic models it was shown that the reaction rate of the biphasic aqueous hydroformylation of 1‐octene is linear dependent on the created…”
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Increasing selectivity of the hydroformylation in a miniplant: Catalyst, solvent, and olefin recycle in two loops
Published in AIChE journal (01-12-2016)“…The application of thermomorphic solvent systems offers the combination of homogeneous catalysis in a single phase and catalyst recovery via phase separation…”
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In‐situ measurement of interfacial areas in the biphasic hydroformylation of long‐chain olefins
Published in Chemie ingenieur technik (01-09-2020)Get full text
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Process Intensification of Aqueous Biphasic Hydroformylation of 1-Octene in a Jet Loop Reactor
Published in Chemie ingenieur technik (01-09-2016)Get full text
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