Search Results - "Vollmer, Matthew V."

Cooperative Bond Activation and Facile Intramolecular Aryl Transfer of Nickel–Aluminum Pincer‐type Complexes by Graziano, Brendan J., Vollmer, Matthew V., Lu, Connie C.

“…Pincer‐type nickel–aluminum complexes were synthesized using two equivalents of the phosphinoamide, [PhNCH2PiPr2]−. The Ni0–AlIII complexes,…”
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A Bimetallic Nickel–Gallium Complex Catalyzes CO2 Hydrogenation via the Intermediacy of an Anionic d10 Nickel Hydride by Cammarota, Ryan C, Vollmer, Matthew V, Xie, Jing, Ye, Jingyun, Linehan, John C, Burgess, Samantha A, Appel, Aaron M, Gagliardi, Laura, Lu, Connie C

“…Large-scale CO2 hydrogenation could offer a renewable stream of industrially important C1 chemicals while reducing CO2 emissions. Critical to this opportunity…”
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Cobalt-Group 13 Complexes Catalyze CO2 Hydrogenation via a Co(−I)/Co(I) Redox Cycle by Vollmer, Matthew V, Ye, Jingyun, Linehan, John C, Graziano, Brendan J, Preston, Andrew, Wiedner, Eric S, Lu, Connie C

“…The Co­(−I) dihydrogen complexes, [(η2-H2)­CoML]−, where ML is the group 13 metalloligand, N­(o-(NCH2PiPr2)­C6H4)3M, and M is Al, Ga, or In, were previously…”
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Reductive Disproportionation of CO2 Mediated by Bimetallic Nickelate(–I)/Group 13 Complexes by Vollmer, Matthew V., Cammarota, Ryan C., Lu, Connie C.

“…The reactivity of bimetallic nickel(–I)/group 13 complexes towards carbon dioxide is presented. Reaction of the anionic [NiML]– complexes, where M is Al or Ga,…”
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Formal Nickelate(−I) Complexes Supported by Group 13 Ions by Vollmer, Matthew V., Xie, Jing, Cammarota, Ryan C., Young, Victor G., Bill, Eckhard, Gagliardi, Laura, Lu, Connie C.

“…Formal nickelate(−I) complexes bearing Group 13 metalloligands (M=Al and Ga) were isolated. These 17 e− complexes were synthesized by one‐electron reduction of…”
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Rationalizing the Reactivity of Bimetallic Molecular Catalysts for CO2 Hydrogenation by Ye, Jingyun, Cammarota, Ryan C, Xie, Jing, Vollmer, Matthew V, Truhlar, Donald G, Cramer, Christopher J, Lu, Connie C, Gagliardi, Laura

“…We have recently reported the heterobimetallic nickel–gallium complex, NiGaL (where L represents the tris­(phosphinoamido)­amine ligand, [N­(o-(NCH2Pi-Pr2)…”
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Thermodynamic and kinetic studies of H2 and N2 binding to bimetallic nickel-group 13 complexes and neutron structure of a Ni(η2-H2) adduct by Cammarota, Ryan C, Xie, Jing, Burgess, Samantha A, Vollmer, Matthew V, Vogiatzis, Konstantinos D, Ye, Jingyun, Linehan, John C, Appel, Aaron M, Hoffmann, Christina, Wang, Xiaoping, Young, Victor G, Lu, Connie C

“…Understanding H2 binding and activation is important in the context of designing transition metal catalysts for many processes, including hydrogenation and the…”
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Multinuclear Copper(I) and Silver(I) Amidinate Complexes: Synthesis, Luminescence, and CS2 Insertion Reactivity by Lane, Andrew C, Vollmer, Matthew V, Laber, Charles H, Melgarejo, Doris Y, Chiarella, Gina M, Fackler, John P, Yang, Xinzheng, Baker, Gary A, Walensky, Justin R

“…Dinuclear Cu(I) and Ag(I) complexes, Cu2[(2,6-Me2C6H3­N)2C(H)]2, 1, Ag2[(2,6-Me2C6­H3N)2C(H)]2, 2, Cu2[2,6- i Pr2C6­H3N)2C(H)]2, 3, and Ag2[(2,6- i…”
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Stable Dihydrogen Complexes of Cobalt(−I) Suggest an Inverse trans-Influence of Lewis Acidic Group 13 Metalloligands by Vollmer, Matthew V, Xie, Jing, Lu, Connie C

“…A triad of d10 cobalt dihydrogen complexes was synthesized by utilizing Lewis acidic group 13 metalloligands, M­[N­((o-C6H4)­NCH2P i Pr2)3], where M = Al, Ga,…”
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Formal Nickelate(−I) Complexes Supported by Group 13 Ions by Vollmer, Matthew V., Xie, Jing, Cammarota, Ryan C., Young, Victor G., Bill, Eckhard, Gagliardi, Laura, Lu, Connie C.

“…Formal nickelate(−I) complexes bearing Group 13 metalloligands (M=Al and Ga) were isolated. These 17 e− complexes were synthesized by one‐electron reduction of…”
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One-electron bonds in copper-aluminum and copper-gallium complexes by Graziano, Brendan J, Scott, Thais R, Vollmer, Matthew V, Dorantes, Michael J, Young, Victor G, Bill, Eckhard, Gagliardi, Laura, Lu, Connie C

“…Odd-electron bonds have unique electronic structures and are often encountered as transiently stable, homonuclear species. In this study, a pair of copper…”
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Reactivity of Mononuclear and Dinuclear Gold(I) Amidinate Complexes with CS2 and CsBr3 by Lane, Andrew, Barnes, Charles, Vollmer, Matthew, Walensky, Justin

“…To probe the reactivity of gold-nitrogen bonds, we have examined the insertion chemistry with carbon disulfide (CS2) as well as oxidation with cesium…”
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Synthesis, Spectroscopy, and Electrochemistry of (α-Diimine)M(CO)3Br, M = Mn, Re, Complexes: Ligands Isoelectronic to Bipyridyl Show Differences in CO2 Reduction by Vollmer, Matthew V, Machan, Charles W, Clark, Melissa L, Antholine, William E, Agarwal, Jay, Schaefer, Henry F, Kubiak, Clifford P, Walensky, Justin R

“…The synthesis and characterization of new Mn­(I)- and Re­(I)-centered organometallic complexes fashioned with 1,4-diazabutadiene (DAB) ligands is reported. Ten…”
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Cooperative Bond Activation and Facile Intramolecular Aryl Transfer of Nickel–Aluminum Pincer‐type Complexes by Graziano, Brendan J., Vollmer, Matthew V., Lu, Connie C.

“…Pincer‐type nickel–aluminum complexes were synthesized using two equivalents of the phosphinoamide, [PhNCH2PiPr2]−. The Ni0–AlIII complexes,…”
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Thermodynamic and kinetic studies of H 2 and N 2 binding to bimetallic nickel-group 13 complexes and neutron structure of a Ni(η 2 -H 2 ) adduct by Cammarota, Ryan C, Xie, Jing, Burgess, Samantha A, Vollmer, Matthew V, Vogiatzis, Konstantinos D, Ye, Jingyun, Linehan, John C, Appel, Aaron M, Hoffmann, Christina, Wang, Xiaoping, Young, Jr, Victor G, Lu, Connie C

“…Understanding H binding and activation is important in the context of designing transition metal catalysts for many processes, including hydrogenation and the…”
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A Bimetallic Nickel-Gallium Complex Catalyzes CO 2 Hydrogenation via the Intermediacy of an Anionic d 10 Nickel Hydride by Cammarota, Ryan C, Vollmer, Matthew V, Xie, Jing, Ye, Jingyun, Linehan, John C, Burgess, Samantha A, Appel, Aaron M, Gagliardi, Laura, Lu, Connie C

“…Large-scale CO hydrogenation could offer a renewable stream of industrially important C chemicals while reducing CO emissions. Critical to this opportunity is…”
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Reductive Disproportionation of CO 2 Mediated by Bimetallic Nickelate(–I)/Group 13 Complexes by Vollmer, Matthew V., Cammarota, Ryan C., Lu, Connie C.

“…The reactivity of bimetallic nickel(–I)/group 13 complexes towards carbon dioxide is presented. Reaction of the anionic [NiML] – complexes, where M is Al or…”
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Cobalt-Group 13 Complexes Catalyze CO 2 Hydrogenation via a Co(−I)/Co(I) Redox Cycle by Vollmer, Matthew V., Ye, Jingyun, Linehan, John C., Graziano, Brendan J., Preston, Andrew, Wiedner, Eric S., Lu, Connie C.

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Formal Nickelate(-I) Complexes Supported by Group 13 Ions by Vollmer, Matthew V., Xie, Jing, Cammarota, Ryan C., Young, Victor G., Bill, Eckhard, Gagliardi, Laura, Lu, Connie C.

“…Not provided…”
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Thermodynamic and kinetic studies of H2 and N2 binding to bimetallic nickel-group 13 complexes and neutron structure of a Ni(η2-H2) adduct† †Electronic supplementary information (ESI) available: Additional data for crystallographic, thermodynamic, kinetic, and computational studies (PDF), DFT-optimized geometries (XYZ), X-ray and neutron crystallographic data for 3-H2 (CIF). CCDC 1889774 and 1889775. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc02018g by Cammarota, Ryan C., Xie, Jing, Burgess, Samantha A., Vollmer, Matthew V., Vogiatzis, Konstantinos D., Ye, Jingyun, Linehan, John C., Appel, Aaron M., Hoffmann, Christina, Wang, Xiaoping, Young, Victor G., Lu, Connie C.

“…Binding energies for H 2 and N 2 at nickel become more exergonic for the larger group 13 sigma-accepting supports. Understanding H 2 binding and activation is…”
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