Search Results - "Volkers, Phillip I."
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Ferrous Carbonyl Dithiolates as Precursors to FeFe, FeCo, and FeMn Carbonyl Dithiolates
Published in Organometallics (24-02-2014)“…Reported are complexes of the formula Fe(dithiolate)(CO)2(diphos) and their use to prepare homo- and heterobimetallic dithiolato derivatives. The starting…”
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Journal Article -
2
Characterization of the Fe Site in Iron−Sulfur Cluster-Free Hydrogenase (Hmd) and of a Model Compound via Nuclear Resonance Vibrational Spectroscopy (NRVS)
Published in Inorganic chemistry (19-05-2008)“…We have used 57Fe nuclear resonance vibrational spectroscopy (NRVS) to study the iron site in the iron−sulfur cluster-free hydrogenase Hmd from the…”
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Journal Article -
3
Extending the motif of the [FeFe]-hydrogenase active site models: protonation of Fe2(NR)2(CO)6-xLx species
Published in Journal of inorganic biochemistry (01-11-2007)“…Studies on diiron dithiolato complexes have proven fruitful for modeling the active site of the [FeFe]-hydrogenases. Here we present a departure from the…”
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Journal Article -
4
Assessing chiral self-recognition using chiral stationary phases
Published in Tetrahedron (16-09-2011)“…Chiral stationary phases were synthesized and their ability to separate racemic precursors from which they were derived was assessed. Taken in conjunction with…”
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Journal Article -
5
Strong Enantioselective Self-Recognition of a Small Chiral Molecule
Published in Organic letters (07-06-2007)“…In the present report, we have crystallized a single enantiomer and the racemate of N-3,5-dinitrobenzoyl (DNB) leucine. In both cases, the X-ray structures…”
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Journal Article -
6
Extending the motif of the [FeFe]-hydrogenase active site models: Protonation of Fe2(NR)2(CO)6−L species
Published in Journal of inorganic biochemistry (01-11-2007)Get full text
Journal Article -
7
Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe2(SR)2(CO)6 from CO-Free Iron Sources
Published in Inorganic chemistry (04-08-2008)“…This report describes routes to iron dithiolato carbonyls that do not require preformed iron carbonyls. The reaction of FeCl2, Zn, and Q2S2C n H2n (Q+ = Na+,…”
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Journal Article -
8
Coordination Chemistry of 3-Mercapto-2-(mercaptomethyl)propanoic Acid (Dihydroasparagusic Acid) with Iron and Nickel
Published in European Journal of Inorganic Chemistry (01-12-2006)“…The first transition‐metal complexes bearing the natural product dihydroasparagusic acid, (HSCH2)2CHCO2H, as a ligand are reported. Various coordination modes…”
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Book Review Journal Article -
9
Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe 2 (SR) 2 (CO) 6 from CO-Free Iron Sources
Published in Inorganic chemistry (04-08-2008)Get full text
Journal Article -
10
Extending the motif of the [FeFe]-hydrogenase active site models: Protonation of Fe 2(NR) 2(CO) 6− x L x species
Published in Journal of inorganic biochemistry (2007)“…Studies on diiron dithiolato complexes have proven fruitful for modeling the active site of the [FeFe]-hydrogenases. Here we present a departure from the…”
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Journal Article -
11
X-ray photochemistry in iron complexes from Fe(0) to Fe(IV) – Can a bug become a feature?
Published in Inorganica Chimica Acta (03-03-2008)“…Soft X-ray irradiation of Fe coordination complexes can cause, at least initially, well-defined changes in their soft X-ray spectra. These are shown to arise…”
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Journal Article -
12
Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe sub(2)(SR) sub(2)(CO) sub(6) from CO-Free Iron Sources
Published in Inorganic chemistry (04-08-2008)“…This report describes routes to iron dithiolato carbonyls that do not require preformed iron carbonyls. The reaction of FeCl sub(2), Zn, and Q sub(2)S sub(2)C…”
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Journal Article -
13
Hydrogenase models and studies based on iron carbonyl chelate complexes
Published 01-01-2007“…The hydrogenase (H2ase) family of enzymes catalyzes the reduction of protons to dihydrogen or the reverse reaction of dihydrogen oxidation to protons. The two…”
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Dissertation -
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Hydrogenase models and studies based on iron carbonyl chelate complexes
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Dissertation