Search Results - "Vojtech, Jancik"
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Coordination-driven assemblies based on meso-substituted porphyrins: Metal-organic cages and a new type of meso-metallaporphyrin macrocycles
Published in Coordination chemistry reviews (15-03-2020)“…[Display omitted] •Coordination-driven self-assembly allows the formation of porphyrin-based cages and meso-metallaporphyrin macrocycles.•The factors that…”
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MOF Materials for the Capture of Highly Toxic H2S and SO2
Published in Organometallics (13-04-2020)“…Metal–organic frameworks (MOFs) are some of the most interesting and promising candidates to sequester toxic H2S and SO2 gases. MOFs show interesting…”
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Benzene and Borazine, so Different, yet so Similar: Insight from Experimental Charge Density Analysis
Published in Inorganic chemistry (09-05-2022)“…Although benzene and borazine are isoelectronic and isostructural, they have very different electronic structures, mainly due to the polar nature of the B-N…”
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Bottleneck Effect of N,N‑Dimethylformamide in InOF-1: Increasing CO2 Capture in Porous Coordination Polymers
Published in Inorganic chemistry (15-05-2017)“…The bottleneck effect of confined N,N-dimethylformamide (DMF) molecules was observed in InOF-1 for the first time: CO2 capture was remarkably enhanced in…”
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Structural Induction via Solvent Variation in Assemblies of Triphenylboroxine and PiperazinePotential Application as Self-Assembly Molecular Sponge
Published in Crystal growth & design (03-05-2017)“…This study examined the direct effect of solvent on the chemical composition and structure of supramolecular assemblies formed from triphenylboroxine ((PhBO)3)…”
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Synthesis, characterization, antimicrobial and theoretical studies of the first main group tris(ephedrinedithiocarbamate) complexes of As(III), Sb(III), Bi(III), Ga(III) and In(III)
Published in Polyhedron (25-09-2017)“…We report the synthesis of the first main group complexes involving the ephedrinedithiocarbamate ligand, the X-ray single crystal structure of two of the…”
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A Synthetic Route to a Molecular Galloxane Dihydroxide and Its Group 4 Heterobimetallic Compounds
Published in Inorganic chemistry (17-06-2013)“…Controlled hydrolysis of MeLGaCl2 (MeL = HC[(CMe)N(2,4,6-Me3C6H2)]2 –) (1) in the presence of a N-heterocyclic carbene, as a HCl acceptor, led to the…”
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A Structurally Diverse Series of Aluminum Chloride Alkoxides [Cl x Al(μ-OR) y ] n (R = n Bu, c Hex, Ph, 2,4- t Bu2C6H3)
Published in Inorganic chemistry (07-09-2009)“…A diverse series of aluminum chloride alkoxides, [Cl x Al(μ-OR) y ] n (R = n Bu, c Hex, Ph, 2,4- t Bu2C6H3), was synthesized using the reactions of…”
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Preparation of Molecular Alumoxane Hydrides, Hydroxides, and Hydrogensulfides
Published in Angewandte Chemie International Edition (01-01-2007)“…Suppressed aggregation: The unprecedented alumoxane hydrogensulfide [{LAl(SH)}2(μ‐O)] and the unique sulfide‐bridged compound [{LAl(SH)}2(μ‐S)] can be prepared…”
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Coordination Diversity of Aluminum Centers Molded by Triazole Based Chalcogen Ligands
Published in Inorganic chemistry (06-07-2009)“…Equimolar and excess ratio reactions of AlMe3 and Al i Bu3 with the ligands 4,5-(P(E)Ph2)2tzH (tz = 1,2,3-triazole; E = O (1), S (2), Se(3)) were performed,…”
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Preparation of Monomeric LGa(NH2)2 and of LGa(OH)2 in the Presence of a N-Heterocyclic Carbene as HCl Acceptor
Published in Organometallics (28-03-2005)“…The reactions of LGaCl2 (L = HC[C(Me)N(Ar)]2, Ar = 2,6-iPr2C6H3) with NH3 and H2O, respectively, in the presence of a 1,3-bis-tert-butylimidazol-2-ylidene…”
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OH Functionality of Germanium(II) Compounds for the Formation of Heterobimetallic Oxides
Published in Inorganic chemistry (16-05-2005)“…Two novel germanium(II) μ-oxo heterobimetallic oxides with different oxidation states at the metal centers have been reported. The reaction of LGeOH [L =…”
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Bonding properties and crystal packing in β-(SeCl 4 ) 4 derived from Hirshfeld Atom Refinement
Published in Acta crystallographica. Section C, Structural chemistry (01-12-2024)“…Binary chalcogen halogen EX 4 species represent intriguing systems in terms of chemical bonding theories, such as hypervalency and stereoactivity of lone…”
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Capture of toxic gases in MOFs: SO2, H2S, NH3 and NOx
Published in Chemical science (Cambridge) (28-05-2021)“…MOFs are promising candidates for the capture of toxic gases since their adsorption properties can be tuned as a function of the topology and chemical…”
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(1 S ,3 R )- N -{(3 S ,10 S ,12 S ,13 R ,17 R )-12-Hy-droxy-17-[( R )-5-hy-droxy-pentan-2-yl]-10,13-di-methyl-hexa-deca-hydro-1 H -cyclo-penta-[ a ]phenanthren-3-yl}adamantane-1-carboxamide 0.25-hydrate
Published in IUCrData (01-10-2022)“…The title compound, C H NO ·0.25H O, was synthesized from de-oxy-cholic acid followed by a protection, a Mitsonobu substitution, a Staudinger reduction,…”
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Formation of Titanosilicate N , N ‐dialkyl Carbamates by CO 2 Insertion into the [( t BuO) 3 SiO] 3 TiNR 2 Scaffold
Published in European journal of inorganic chemistry (12-09-2024)“…Molecular titanosilicates {( t BuO 3 ) 3 SiO} 2 Ti(NR 2 ) 2 ( 1 , R=Et; 2 , R=Me) and {( t BuO 3 ) 3 SiO} 3 TiNR 2 ( TSA1 , R=Et; 3 , R=Me) were obtained from…”
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SO2 Capture Using Porous Organic Cages
Published in Angewandte Chemie International Edition (02-08-2021)“…We report the first experimental investigation of porous organic cages (POCs) for the demanding challenge of SO2 capture. Three structurally related…”
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Preparation of [LAl(μ-S)2MCp2] (M=Ti, Zr) from the Structurally Characterized Lithium Complexes [{LAl(SH)[SLi(thf)2]}2] and [{LAl[(SLi)2(thf)3]}2]⋅2 THF
Published in Angewandte Chemie International Edition (19-11-2004)“…Sulfur bridges: The reactions of [LAl(SH)2] (L=HC(CMeNAr)2, Ar=2,6‐iPr2C6H3) with LiN(SiMe3)2 in molar ratio 1:2 and 1:1, respectively, lead to species with…”
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Formation of Titanosilicate N,N‐dialkyl Carbamates by CO2 Insertion into the [(tBuO)3SiO]3TiNR2 Scaffold
Published in European journal of inorganic chemistry (01-10-2024)“…Molecular titanosilicates {(tBuO3)3SiO}2Ti(NR2)2 (1, R=Et; 2, R=Me) and {(tBuO3)3SiO}3TiNR2 (TSA1, R=Et; 3, R=Me) were obtained from the reaction between…”
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Ligand‐directed assembly of multimetallic aluminum complexes: Synthesis, Structure and ROP catalysis
Published in European journal of inorganic chemistry (08-09-2024)“…Multinuclear aluminum complexes are useful catalysts for the ring opening polymerization (ROP) of ε‐caprolactone (ε‐CL), often outperforming monometallic…”
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