Chemical dehydrochlorination of polytrichlorobutadienes—A new route to carbynes

The chemical dehydrochlorination of polytrichlorobutadiene isomers, viz. poly(1,1,2-trichlorobutadiene) and poly(1,2,3-trichlorobutadiene) has been studied as a possible route to carbyne. The structure of the reaction products has been studied by IR, XPS, and Auger electron spectroscopy. The dehydro...

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Bibliographic Details
Published in:	European polymer journal Vol. 32; no. 1; pp. 61 - 68
Main Authors:	Vointseva, I.I., Gilman, L.M., Kudryavtsev, Yu.P., Evsyukov, S.E., Pesin, L.A., Gribov, I.V., Moskvina, N.A., Khvostov, V.V.
Format:	Journal Article
Language:	English
Published:	Elsevier Ltd 1996
Online Access:	Get full text
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Summary:	The chemical dehydrochlorination of polytrichlorobutadiene isomers, viz. poly(1,1,2-trichlorobutadiene) and poly(1,2,3-trichlorobutadiene) has been studied as a possible route to carbyne. The structure of the reaction products has been studied by IR, XPS, and Auger electron spectroscopy. The dehydrochlorination of poly(1,1,2- and 1,2,3-trichlorobutadiene) has been shown to result in the formation of the polyyne and cumulene forms of carbyne, respectively.
ISSN:	0014-3057 1873-1945
DOI:	10.1016/0014-3057(95)00104-2