Search Results - "Vladimir B. Kharitonov"
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Effect of Alkoxy Substituents on the Regioselectivity of Catalytic C-H Activation in Benzoic Acids: Experimental and DFT Study
Published in Catalysts (01-02-2023)“…This work demonstrates the influence of the catalyst and alkyne nature on the regioselectivity of rhodium-catalyzed annulation of alkoxy-substituted benzoic…”
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2
Planar Chiral Rhodium Complex Based on the Tetrahydrofluorenyl Core for Enantioselective Catalysis
Published in Organic letters (15-12-2023)“…A simple four-step route to a chiral tetrahydrofluorenyl rhodium catalyst from naturally occurring (−)-α-pinene was developed. Our approach does not use…”
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Easy Access to Versatile Catalytic Systems for C−H Activation and Reductive Amination Based on Tetrahydrofluorenyl Rhodium(III) Complexes
Published in Chemistry : a European journal (26-07-2021)“…On the basis of the 1,2,3,4‐tetrahydrofluorenyl ligand, a simple approach was developed to new effective rhodium catalysts for the construction of C−C and C−N…”
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4
Triphenylcyclopentadienyl Rhodium Complexes in Catalytic C–H Annulations. Application for Synthesis of Natural Isocoumarins
Published in Journal of organic chemistry (03-03-2023)“…Efficient protocols for the synthesis of triphenylcyclopentadienyl rhodium halides [(1,2,4-C5Ph3H2)RhX2]2 (1a,b: X = Cl, I) starting from…”
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Rhodium Catalysts Based on Phenyl Substituted Cp Ligands for Indole Synthesis via Oxidative Coupling of Acetanilides and Alkynes
Published in Advanced synthesis & catalysis (19-11-2024)“…Rhodium‐catalyzed oxidative coupling of acetanilides and alkynes via C−H activation is the most powerful synthetic tool for producing the indole motif from…”
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6
Redirecting of Charge Transfer Enables the Control of the Photoactivity of Terarylenes
Published in Organic letters (21-10-2022)“…Photoinduced charge transfer affects the efficiency and selectivity of photochemical reactions. Incorporation of donating groups into the isoquinolinium core…”
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7
Fluorene Complexes of Group 9 Metals: Fluorene Effect and Application for Reductive Amination
Published in Organometallics (26-08-2019)“…The η6-fluorene cyclopentadienyl complexes [(η5-C5R5)M(η6-fluorene)](SbF6)2 (1: M = Co, R = Me; 2a: M = Rh, R = H; 2b: M = Ir, R = H) were synthesized by…”
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Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination
Published in Organometallics (13-08-2018)“…An efficient protocol for synthesis of indenyl rhodium complexes with arene ligands has been developed. The hexafluoroantimonate salts…”
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9
Indenyl complexes of Group 9 metals: Synthetic and catalytic chemistry
Published in Coordination chemistry reviews (15-11-2019)“…[Display omitted] •A review of indenyl complexes of Group 9 metals is given.•Synthesis and reactivity of indenyl cobalt, rhodium and iridium complexes are…”
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10
Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products
Published in Coordination chemistry reviews (15-11-2022)“…[Display omitted] •A comprehensive review on the use of cyclopentadienyl complexes of Group 9 metals in the total synthesis of natural products is given.•This…”
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11
Synthesis and structure of bis(indenyl)-rhodium and -iridium complexes
Published in Journal of organometallic chemistry (01-02-2019)“…Bis(indenyl)-rhodium and -iridium complexes [(η5-indenyl)M(η5-C9H2R5)]PF6 (2a: M = Rh, R = H; 2b: M = Ir, R = H; 3: M = Rh, R = Me) were synthesized by…”
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12
Indenyl rhodium complexes. Synthesis and catalytic activity in reductive amination using carbon monoxide as a reducing agent
Published in Journal of organometallic chemistry (15-07-2018)“…Indenyl-ligated rhodium(III) catalyst [(η5-indenyl)RhX2]n (1) is reported for the synthesis of alkylated amines via catalytic reductive amination using carbon…”
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13
(Indenyl)rhodacarboranes. Electronic versus steric effects on the conformation of cyclic ligands
Published in Journal of organometallic chemistry (15-06-2018)“…(Indenyl)rhodacarboranes 1,2-R2-3-(η5-indenyl)-3,1,2-RhC2B9H9 (2a: R = H; 2b: R = Me) and 3-(η5-indenyl)-4-SMe-3,1,2-RhC2B9H10 (3) were synthesized by…”
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14
Tetrahydrofluorenyl rhodium complexes: positive impact of p-methoxybenzyl substituent on catalytic annulation reactions
Published in Mendeleev communications (01-01-2024)“…[Display omitted] Rhodium complex based on 9-(p-methoxybenzyl)-1,2,3,4- tetrahydrofluorenyl ligand was found to be an efficient catalyst for various C–H…”
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15
Tris(pyrazolyl)borate rhodium complexes. Application for reductive amination and esterification of aldehydes in the presence of carbon monoxide
Published in Journal of organometallic chemistry (15-10-2020)“…The halide complexes TpRhCl2(MeOH) and TpMe2RhI2(CO) (Tp = hydrotris-(pyrazolyl)borate; TpMe2 = hydrotris-(3,5-dimethylpyrazolyl)borate) were synthesized by…”
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Mononuclear (C5R5)Ir-complexes with π-linked biaryls: Stability and fluorescence quenching
Published in Journal of organometallic chemistry (01-04-2020)“…The arene iridium complexes [(η5-C5R5)M(η6-PhX)](SbF6)2 (1a: R = H, X = CH=CHPh; 1b: R = Me, X = CH=CHPh; 2: R = Me, X = C≡CPh; 3: R = Me,…”
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17
(Indenyl)Iron Complex [(η5‐indenyl)Fe(η‐C6H6)]+: Synthesis, Arene Exchange Reactions and Bonding
Published in ChemistrySelect (Weinheim) (24-04-2017)“…The indenyl‐benzene complex [(η5‐indenyl)Fe(η‐C6H6)]+ (2) was synthesized by photochemical reaction of the cyclohexadienyl derivative [(η5‐C6H7)Fe(η‐C6H6)]+…”
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