Search Results - "Vivona, Nicolo"

Fluorinated Heterocyclic Compounds. An Expedient Route to 5-Perfluoroalkyl-1,2,4-triazoles via an Unusual Hydrazinolysis of 5-Perfluoroalkyl-1,2,4-oxadiazoles:  First Examples of an ANRORC-Like Reaction in 1,2,4-Oxadiazole Derivatives by Buscemi, Silvestre, Pace, Andrea, Pibiri, Ivana, Vivona, Nicolò, Spinelli, Domenico

“…The hydrazinolysis reaction of 5-perfluoroalkyl-1,2,4-oxadiazoles has been investigated. Nucleophilic addition of the reagent to the C(5)−N(4) double bond of…”
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Heterocyclic Rearrangements in Constrained Media. A Zeolite-Directed Photorearrangement of 1,2,4-Oxadiazoles by Pace, Andrea, Buscemi, Silvestre, Vivona, Nicolò

“…The first intrazeolite-photoinduced rearrangement of a five-membered heterocycle is reported. A completely different behavior compared to solution irradiations…”
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Exploiting the CNC Side Chain in Heterocyclic Rearrangements: Synthesis of 4(5)-Acylamino-imidazoles by Piccionello, Antonio Palumbo, Buscemi, Silvestre, Vivona, Nicolò, Pace, Andrea

“…A new variation on the Boulton−Katritzky reaction is reported, namely, involving use of a CNC side chain. A novel Montmorillonite-K10 catalyzed nonreductive…”
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Synthesis of Amino-1,2,4-triazoles by Reductive ANRORC Rearrangements of 1,2,4-Oxadiazoles by Palumbo Piccionello, Antonio, Guarcello, Annalisa, Buscemi, Silvestre, Vivona, Nicolò, Pace, Andrea

“…The reaction of various 1,2,4-oxadiazoles with an excess of hydrazine in DMF has been investigated. 3-Amino-1,2,4-triazoles are produced through a reductive…”
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Experimental and DFT Studies on Competitive Heterocyclic Rearrangements. 3. A Cascade Isoxazole−1,2,4-Oxadiazole−Oxazole Rearrangement by Pace, Andrea, Pierro, Paola, Buscemi, Silvestre, Vivona, Nicolò, Barone, Giampaolo

“…The thermal rearrangements of 3-acylamino-5-methylisoxazoles 1 have been investigated under basic and neutral conditions and interpreted with the support of…”
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1,2,4-Oxadiazole Rearrangements Involving an NNC Side-Chain Sequence by Piccionello, Antonio Palumbo, Pace, Andrea, Buscemi, Silvestre, Vivona, Nicolò

“…The thermal rearrangement of N-1,2,4-oxadiazol-3-yl-hydrazones into 1,2,4-triazole derivatives is reported. This represents the first example of a three-atom…”
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Synthesis, characterization, cellular uptake and interaction with native DNA of a bis(pyridyl)-1,2,4-oxadiazole copper(II) complex by Terenzi, Alessio, Barone, Giampaolo, Piccionello, Antonio Palumbo, Giorgi, Gianluca, Guarcello, Annalisa, Portanova, Patrizia, Calvaruso, Giuseppe, Buscemi, Silvestre, Vivona, Nicolò, Pace, Andrea

“…The copper(II) complex of 3,5-bis(2'-pyridyl)-1,2,4-oxadiazole was synthesized and characterized. X-Ray crystallography revealed that the complex consists of a…”
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Fluorinated Heterocyclic Compounds. An Effective Strategy for the Synthesis of Fluorinated Z-Oximes of 3-Perfluoroalkyl-6-phenyl-2H-1,2,4-triazin- 5-ones via a Ring-Enlargement Reaction of 3-Benzoyl-5-perfluoroalkyl-1,2,4-oxadiazoles and Hydrazine by Buscemi, Silvestre, Pace, Andrea, Palumbo Piccionello, Antonio, Macaluso, Gabriella, Vivona, Nicolò, Spinelli, Domenico, Giorgi, Gianluca

“…The reaction of 3-benzoyl-5-perfluoroalkyl-1,2,4-oxadiazoles with hydrazine has been investigated, evidencing the possibility of competitive reaction paths…”
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Five-to-Six Membered Ring-Rearrangements in the Reaction of 5-Perfluoroalkyl-1,2,4-oxadiazoles with Hydrazine and Methylhydrazine by Buscemi, Silvestre, Pace, Andrea, Piccionello, Antonio Palumbo, Pibiri, Ivana, Vivona, Nicolò, Giorgi, Gianluca, Mazzanti, Andrea, Spinelli, Domenico

“…The hydrazinolysis reaction of 5-perfluoroalkyl-1,2,4-oxadiazoles with hydrazine or methylhydrazine as bidentate nucleophiles has been investigated. The…”
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Synthesis of fluorinated 1,2,4-oxadiazin-6-ones through ANRORC rearrangement of 1,2,4-oxadiazoles by Piccionello, Antonio Palumbo, Pace, Andrea, Buscemi, Silvestre, Vivona, Nicolò, Giorgi, Gianluca

“…The reaction of 3-ethoxycarbonyl-5-perfluoroalkyl-1,2,4-oxadiazoles with hydroxylamines has been investigated, evidencing the possibility of competitive…”
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On the reaction of some 5-polyfluoroaryl-1,2,4-oxadiazoles with methylhydrazine: synthesis of fluorinated indazoles by Palumbo Piccionello, Antonio, Pace, Andrea, Pierro, Paola, Pibiri, Ivana, Buscemi, Silvestre, Vivona, Nicolò

“…The reaction of 5-polyfluoroaryl-1,2,4-oxadiazoles with methylhydrazine has been studied and the synthesis of fluorinated N-methylindazoles has been realized…”
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Synthesis of fluorinated indazoles through ANRORC-like rearrangement of 1,2,4-oxadiazoles with hydrazine by Palumbo Piccionello, Antonio, Pace, Andrea, Pibiri, Ivana, Buscemi, Silvestre, Vivona, Nicolò

“…A series of 6-substituted fluorinated indazoles has been obtained through an ANRORC-like rearrangement (Addition of Nucleophile, Ring-Opening and Ring-Closure)…”
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Synthesis of trifluoromethylated 2-benzoyl- and 2-aminoimidazoles from ring rearrangement of 1,2,4-oxadiazole derivatives by Palumbo Piccionello, Antonio, Pace, Andrea, Buscemi, Silvestre, Vivona, Nicolò, Pani, Marcella

“…Fluoroalkylated 2-ylamino-imidazoles have been synthesized by reaction of 3-amino-5-phenyl-1,2,4-oxadiazole with fluorinated β-dicarbonyl compounds and…”
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Experimental and DFT studies on competitive heterocyclic rearrangements. Part 2: A one-atom side-chain versus the classic three-atom side-chain (boulton-katritzky) ring rearrangement of 3 -Acylamino-1,2,4 -oxadiazoles by PACE, Andrea, PIBIRI, Ivana, PICCIONELLO, Antonio Palumbo, BUSCEMI, Silvestre, VIVONA, Nicolo, BARONE, Giampaolo

“…The experimental investigation of the base-catalyzed rearrangements of 3-acylamino-1,2,4-oxadiazoles evidenced a new reaction pathway which competes with the…”
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Photooxidations of Alkenes in Fluorinated Constrained Media:  Fluoro-organically Modified NaY as Improved Reactors for Singlet Oxygen “Ene” Reactions by Pace, Andrea, Pierro, Paola, Buscemi, Silvestre, Vivona, Nicolò, Clennan, Edward L

“…Creating a stationary fluorinated environment inside the zeolite cavity can increase the reactivity observed for intrazeolite photooxidation of alkenes…”
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Synthesis of fluorinated first generation starburst molecules containing a triethanolamine core and 1,2,4-oxadiazoles by Buscemi, Silvestre, Pace, Andrea, Piccionello, Antonio Palumbo, Vivona, Nicolò

“… 5-Pentafluorophenyl-1,2,4-oxadiazoles, differently substituted at C(3), have been synthesized and used to functionalize the aliphatic primary hydroxyl…”
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THE SYNTHESIS OF FLUORINATED HETEROAROMATIC COMPOUNDS. PART 2. FIVE-MEMBERED RINGS WITH TWO HETEROATOMS. A REVIEW by Pace, Andrea, Buscemi, Silvestre, Vivona, Nicolò

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Photochemistry of Fluorinated Heterocyclic Compounds. An Expedient Route for the Synthesis of Fluorinated 1,3,4-Oxadiazoles and 1,2,4-Triazoles by Pace, Andrea, Pibiri, Ivana, Buscemi, Silvestre, Vivona, Nicolò, Malpezzi, Luciana

“…The photochemistry of some 3-N-alkylamino-5-perfluoroalkyl-1,2,4-oxadiazoles in the presence of nitrogen nucleophiles such as ammonia and primary and secondary…”
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An ANRORC approach to the synthesis of perfluoroalkylated 1,2,4-triazole-carboxamides by Piccionello, Antonio Palumbo, Pace, Andrea, Buscemi, Silvestre, Vivona, Nicolò

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Photochemistry of 1,2,4-Oxadiazoles. A DFT Study on Photoinduced Competitive Rearrangements of 3-Amino- and 3-N-Methylamino-5-perfluoroalkyl-1,2,4-oxadiazoles by Pace, Andrea, Buscemi, Silvestre, Vivona, Nicolò, Silvestri, Arturo, Barone, Giampaolo

“…The photoinduced competitive rearrangements of 5-perfluoroalkyl-3-amino(N-alkylamino)-1,2,4-oxadiazoles have been investigated by DFT calculations and UV−vis…”
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