Search Results - "Vittal, J. J."
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Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications
Published in Chemical reviews (14-04-2021)“…Among the recent developments in metal-organic frameworks (MOFs), porous layered coordination polymers (CPs) have garnered attention due to their modular…”
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Single-Crystal-to-Single-Crystal [2 + 2] Photocycloaddition Reaction in a Photosalient One-Dimensional Coordination Polymer of Pb(II)
Published in Journal of the American Chemical Society (25-11-2020)“…In a remarkable example, we report a one-dimensional coordination polymer (CP) of Pb(II) showing photosalient (PS) properties triggered by [2 + 2]…”
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One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications
Published in Chemical reviews (09-02-2011)“…One-dimensional coordination polymers are discussed. These are used as the building blocks for supramolecular structures…”
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Mechanical Bending and Modulation of Photoactuation Properties in a One-Dimensional Pb(II) Coordination Polymer
Published in Chemistry of materials (22-06-2021)“…With emerging research on stimuli-responsive materials, dynamic crystals are at the forefront of investigation. However, research on the mechanical properties…”
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Solid-state polymerisation via [2+2] cycloaddition reaction involving coordination polymers
Published in Chemical communications (Cambridge, England) (14-03-2016)“…Highly crystalline metal ions containing organic polymers are potentially useful to manipulate the magnetic and optical properties to make advanced…”
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Chemical Patterning in Single Crystals of Metal–Organic Frameworks by [2+2] Cycloaddition Reaction
Published in Angewandte Chemie International Edition (14-10-2019)“…Conventional chemical patterning involves films of polymeric materials. Herein, we demonstrate that the presence or absence of guest solvents in the crystal…”
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Coordination Polymers Versus Metal−Organic Frameworks
Published in Crystal growth & design (01-07-2009)“…Different terminologies such as coordination polymers, metal−organic frameworks, and hybrid inorganic and organic framework materials have been used to…”
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Enhancement in Two-Photon Absorption and Photoluminescence in Single Crystals of Cd(II) Metal Organic Frameworks
Published in ACS applied materials & interfaces (07-06-2023)“…The emergence of metal organic frameworks (MOFs) as advanced photonic materials has placed them at the forefront of exploration. Nonlinear optical (NLO)…”
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Single Crystals Popping Under UV Light: A Photosalient Effect Triggered by a [2+2] Cycloaddition Reaction
Published in Angewandte Chemie International Edition (02-06-2014)“…The extremely rare examples of dynamic single crystals where excitation by light or heat induces macroscopic motility present not only a visually appealing…”
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Reversible Single-Crystal-to-Single-Crystal Photochemical Formation and Thermal Cleavage of a Cyclobutane Ring
Published in Angewandte Chemie International Edition (17-02-2014)“…A [2+2] cycloaddition reaction has been observed in a number of solids. The cyclobutane ring in a photodimerized material can be cleaved into olefins by UV…”
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Tunable Electrical Conductivity and Magnetic Property of the Two Dimensional Metal Organic Framework [Cu(TPyP)Cu2(O2CCH3)4]
Published in ACS applied materials & interfaces (29-06-2016)“…The coordination chemistry between copper acetate [Cu2(OAc)4] and 5,10,15,20-tetra-4-pyridyl-21H,23H-porphine (porphyrin, H2TPyP) is found to give rise to…”
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Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates
Published in Nature communications (04-10-2016)“…The Rauhut–Currier (RC) reaction represents an efficient method for the construction of carbon–carbon bond in organic synthesis. However, the RC reactions…”
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Multiphoton harvesting metal–organic frameworks
Published in Nature communications (06-08-2015)“…Multiphoton upconversion is a process where two or more photons are absorbed simultaneously to excite an electron to an excited state and, subsequently, the…”
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Distortional Supramolecular Isomers of Polyrotaxane Coordination Polymers: Photoreactivity and Sensing of Nitro Compounds
Published in Angewandte Chemie International Edition (26-05-2014)“…Distortional isomers, or bond‐stretch isomers, differ only in the length of one or more bonds, which is due to crystallographic disorder in most cases. The…”
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Efficient Third Harmonic Generation in a Metal–Organic Framework
Published in Chemistry of materials (24-05-2016)“…As a recently emerged class of inorganic–organic hybrid crystals, metal–organic frameworks (MOFs) have been investigated for their capabilities for doubling…”
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Formation of a Syndiotactic Organic Polymer Inside a MOF by a [2+2] Photo-Polymerization Reaction
Published in Angewandte Chemie International Edition (15-06-2015)“…Getting suitable crystals for single‐crystal X‐ray crystallographic analysis still remains an art. Obtaining single crystals of metal–organic frameworks (MOFs)…”
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Helix inside a Helix: Encapsulation of Hydrogen-Bonded Water Molecules in a Staircase Coordination Polymer
Published in Angewandte Chemie International Edition (05-11-2004)“…A stream of water molecules, held together by hydrogen bonding, forms a left‐handed helix within the helical channels of a left‐handed staircaselike metal…”
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Solid-State Structural Transformations from 2D Interdigitated Layers to 3D Interpenetrated Structures
Published in Angewandte Chemie International Edition (11-11-2011)“…Construction by shining light! A [2+2] cycloaddition reaction in a 2D coordination polymer accompanied by single‐crystal‐to‐single‐crystal structural…”
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Metal-Organic Organopolymeric Hybrid Framework by Reversible [2+2] Cycloaddition Reaction
Published in Angewandte Chemie International Edition (07-01-2014)“…Organic polymers are usually amorphous or possess very low crystallinity. The metal complexes of organic polymeric ligands are also difficult to crystallize by…”
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Solid‐State Photochemical [2+2] Cycloaddition Reaction of MnII Complexes
Published in Chemistry : a European journal (06-08-2019)“…Three MnII complexes have been synthesized under similar experimental conditions. Of these [Mn2(benzoate)4(L)2] (where L=4‐styrylpyridine or 4spy, 1 and…”
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