Search Results - "Villiers, Claude"
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A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2
Published in Angewandte Chemie International Edition (02-01-2012)“…Lateral thinking: A diagonal approach to CO2 recycling has been explored for the formation of both functionalized and energetic chemicals featuring a reduced…”
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Isolated CO₂ Adduct of a Nitrogen Base: Crystal and Electronic Structures
Published in Angewandte Chemie (International ed.) (03-05-2010)“…In a crystal at last: CO2 binds reversibly to the guanidine molecule TBD. The zwitterionic structure of the adduct is demonstrated by X‐ray diffraction…”
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Evaluation of traffic management strategies for special events using probe data
Published in Transportation research interdisciplinary perspectives (01-09-2019)“…Special events can impose burdens to local roads. As these events are temporary and even seasonal in nature, concerned agencies need to identify cost-effective…”
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Lanthanide(III) and Actinide(III) Complexes [M(BH4)2(THF)5][BPh4] and [M(BH4)2(18-crown-6)][BPh4] (M = Nd, Ce, U): Synthesis, Crystal Structure, and Density Functional Theory Investigation of the Covalent Contribution to Metal-Borohydride Bonding
Published in Inorganic chemistry (05-01-2009)“…Treatment of [M(BH4)3(THF)3] with NEt3HBPh4 in THF afforded the cationic complexes [M(BH4)2(THF)5][BPh4] [M = U (1), Nd (2), Ce (3)] which were transformed…”
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Cover Picture: A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2 (Angew. Chem. Int. Ed. 1/2012)
Published in Angewandte Chemie International Edition (02-01-2012)“…A blooming tree illustrates how CO2 can be recycled to a variety of chemicals based on a strategy discussed by T. Cantat and co‐workers in their Communication…”
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Evaluation of Driver Behavior to Hydroplaning in the State of Florida Using Driving Simulation
Published in CSID journal of infrastructure development (31-12-2019)“…This project used a driving simulator to investigate patterns of drivers’ behavior during rainfall events using different geometries. We conducted a literature…”
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A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2
Published in Angewandte Chemie (02-01-2012)“…Quergedacht: Mit einem diagonalen Ansatz zur Wiederverwertung von CO2 können funktionalisierte Chemikalien erhalten werden. Der Einsatz eines…”
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An Isolated CO2 Adduct of a Nitrogen Base: Crystal and Electronic Structures
Published in Angewandte Chemie (03-05-2010)“…Jetzt auch im Kristall: CO2 bindet reversibel an das Guanidinderivat TBD. Die Struktur des zwitterionischen Addukts wurde durch Röntgenbeugung und Rechnungen…”
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Reactivity and Structural Diversity in the Reaction of Guanidine 1,5,7‐Triazabicyclo[4.4.0]dec‐5‐ene with CO2, CS2, and Other Heterocumulenes
Published in European journal of organic chemistry (18-01-2017)“…The guanidine 1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene (TBD) reacted with the heterocumulenes CO2, CS2, iPr2NCNiPr2, p‐tolylNCO, and p‐tolylNCS to give three types…”
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Reactivity and Structural Diversity in the Reaction of Guanidine 1,5,7‐Triazabicyclo[4.4.0]dec‐5‐ene with CO 2 , CS 2 , and Other Heterocumulenes
Published in European journal of organic chemistry (18-01-2017)“…The guanidine 1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene (TBD) reacted with the heterocumulenes CO 2 , CS 2 , i Pr 2 NCN i Pr 2 , p ‐tolylNCO, and p ‐tolylNCS to give…”
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First cis-Dioxido Uranyl Compound under Scrutiny
Published in Angewandte Chemie (International ed.) (28-07-2008)“…The identity of a cis‐dioxido uranyl compound recently reported by P. B. Duval et al., is questioned on the basis of the structural characterization of three…”
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A Comparison of Analogous 4f- and 5f-Element Compounds: Syntheses, X-ray Crystal Structures and Catalytic Activity of the Homoleptic Amidinate Complexes [M{MeC(NCy)2}3] (M = La, Nd or U)
Published in European journal of inorganic chemistry (01-12-2004)“…Reaction of UCl4 with [Li{RC(NCy)2}(THF)]2 (R = Me, 1a; R = nBu, 1b) in THF gave the tris(amidinate) compounds [U{RC(NCy)2}3Cl] (R = Me, 2a; R = nBu, 2b) which…”
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Uranyl complexes with 1,2-diols and tetrahydrofurfuryl alcohols
Published in Polyhedron (09-10-2012)“…The first complexes of an f element with tetrahydrofurfuryl alcohol ligands have been isolated. The uranyl ion coordination in these complexes is similar to…”
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Di-2-pyridyl ketone in actinide chemistry: Dinuclear uranyl complexes
Published in Polyhedron (19-04-2010)“…The first structurally characterized actinide compounds with a (py) 2CO-based ligand, [(UO 2X) 2{μ-(py) 2C(OMe)O} 2] (X = OAc, Cl, NO 3, OMe) were isolated…”
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University of Stellenbosch Legal Aid Clinic V Minister of Justice and Correctional Services: Proactive Judicial Application of Principle 3 of the G20 High Level Principles of Financial Consumer Protection
Published 01-01-2018“…Following the global financial crisis of 2008 and the role played by so-called “easy credit” in the build-up to the crisis, there has been a renewed focus…”
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Dissertation -
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Evaluation of a new approach to life-long learning in civil and environmental engineering curricula
Published in 2014 IEEE Frontiers in Education Conference (FIE) Proceedings (01-10-2014)“…Lifelong learning (LLL) has been long recognized by educators as a valuable attribute that can be an impetus for improved student learning. The Accreditation…”
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Conference Proceeding -
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Uranyl-Based Metallamacrocycles: Tri- and Tetranuclear Complexes with (2R,3R,4S,5S)-Tetrahydrofurantetracarboxylic Acid
Published in Journal of the American Chemical Society (09-06-2004)“…The trinuclear [UO2L]3 6- and tetranuclear [UO2L]4 8- metallamacrocycles, obtained by reaction of uranyl nitrate with the rigidly angular ligand…”
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