Search Results - "Villa, Danielle Y"
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Controlling Magnetic Anisotropy in a Zero-Dimensional S = 1 Magnet Using Isotropic Cation Substitution
Published in Journal of the American Chemical Society (31-03-2021)“…The [Zn1–x Ni x (HF2)(pyz)2]SbF6 (x = 0.2; pyz = pyrazine) solid solution exhibits a zero-field splitting (D) that is 22% larger [D = 16.2(2) K (11.3(2)…”
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Magneto-structural Correlations in Ni2+–Halide···Halide–Ni2+ Chains
Published in Inorganic chemistry (10-01-2022)“…We present the magnetic properties of a new family of S = 1 molecule-based magnets, NiF2(3,5-lut)4·2H2O and NiX2(3,5-lut)4, where X = HF2, Cl, Br, or I (lut =…”
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Magneto-structural Correlations in Ni 2+ -Halide···Halide-Ni 2+ Chains
Published in Inorganic chemistry (10-01-2022)“…We present the magnetic properties of a new family of = 1 molecule-based magnets, NiF (3,5-lut) ·2H O and NiX (3,5-lut) , where X = HF , Cl, Br, or I (lut =…”
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4
Near-ideal molecule-based Haldane spin chain
Published in Physical review research (27-01-2020)“…The molecular coordination complex NiI_{2}(3,5-lut)_{4} [where (3,5-lut) = (3,5-lutidine) =(C_{7}H_{9}N)] has been synthesized and characterized by several…”
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Magneto-structural Correlations in Ni 2+ –Halide···Halide–Ni 2+ Chains
Published in Inorganic chemistry (23-12-2021)Get full text
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Enhancing easy-plane anisotropy in bespoke Ni(II) quantum magnets
Published in Polyhedron (01-04-2020)“…By design, targeted pseudo-octahedral Ni(II) complexes composed of simple ligands L show easy-plane anisotropy with 8 ≤ D ≤ 25 K. For small donor-atoms; e.g.,…”
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A Near-Ideal Molecule-Based Haldane Spin-Chain
Published 17-09-2019“…Phys. Rev. Research 2, 013082 (2020) The molecular coordination complex NiI$_2$(3,5-lut)$_4$ [where (3,5-lut) $=$ (3,5-lutidine) $=$ (C$_7$H$_9$N)] has been…”
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Determining the anisotropy and exchange parameters of polycrystalline spin-1 magnets
Published 24-06-2019“…Although low-dimensional $S = 1$ antiferromagnets remain of great interest, difficulty in obtaining high-quality single crystals of the newest materials…”
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