Search Results - "Vil', Vera A"
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1
Rearrangements of organic peroxides and related processes
Published in Beilstein journal of organic chemistry (03-08-2016)“…This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the…”
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2
Cross-dehydrogenative coupling for the intermolecular C-O bond formation
Published in Beilstein journal of organic chemistry (20-01-2015)“…The present review summarizes primary publications on the cross-dehydrogenative C-O coupling, with special emphasis on the studies published after 2000. The…”
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3
Peroxides with Anthelmintic, Antiprotozoal, Fungicidal and Antiviral Bioactivity: Properties, Synthesis and Reactions
Published in Molecules (Basel, Switzerland) (02-11-2017)“…The biological activity of organic peroxides is usually associated with the antimalarial properties of artemisinin and its derivatives. However, the analysis…”
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4
Electrochemically Induced Synthesis of Imidazoles from Vinyl Azides and Benzyl Amines
Published in Molecules (Basel, Switzerland) (09-11-2022)“…An electrochemically induced synthesis of imidazoles from vinyl azides and benzyl amines was developed. A wide range of imidazoles were obtained, with yields…”
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5
Ozone-Free Synthesis of Ozonides: Assembling Bicyclic Structures from 1,5-Diketones and Hydrogen Peroxide
Published in Journal of organic chemistry (20-04-2018)“…Reactions of 1,5-diketones with H2O2 open an ozone-free approach to ozonides. Bridged ozonides are formed readily at room temperature in the presence of strong…”
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6
Interrupted Baeyer–Villiger Rearrangement: Building A Stereoelectronic Trap for the Criegee Intermediate
Published in Angewandte Chemie International Edition (19-03-2018)“…The instability of hydroxy peroxyesters, the elusive Criegee intermediates of the Baeyer–Villiger rearrangement, can be alleviated by selective deactivation of…”
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7
Electrochemical Synthesis of Fluorinated Ketones from Enol Acetates and Sodium Perfluoroalkyl Sulfinates
Published in Organic letters (02-07-2021)“…The electrochemical synthesis of fluorinated ketones from enol acetates and RfSO2Na in an undivided cell under constant current conditions was developed. The…”
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8
Synthetic Strategies for Peroxide Ring Construction in Artemisinin
Published in Molecules (Basel, Switzerland) (11-01-2017)“…The present review summarizes publications on the artemisinin peroxide fragment synthesis from 1983 to 2016. The data are classified according to the…”
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9
Electrochemically Induced Intermolecular Cross-Dehydrogenative C–O Coupling of β‑Diketones and β‑Ketoesters with Carboxylic Acids
Published in Journal of organic chemistry (01-02-2019)“…The electrochemically induced cross-dehydrogenative C–O coupling of β-diketones and β-ketoesters (C–H reagents) with carboxylic acids (O–H reagents) was…”
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10
Alkene, Bromide, and ROH – How To Achieve Selectivity? Electrochemical Synthesis of Bromohydrins and Their Ethers
Published in Advanced synthesis & catalysis (21-06-2021)“…Bromohydrins and their ethers were electrochemically synthesized via hydroxy‐ and alkoxybromination of alkenes using potassium bromide and water or alcohols…”
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11
Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell
Published in Organic letters (12-01-2024)“…The generation of peroxy radicals from hydroperoxides with subsequent selective peroxidation of 1,3-dicarbonyls in an undivided electrochemical cell under…”
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12
Activation of O‑Electrophiles via Structural and Solvent Effects: SN2@O Reaction of Cyclic Diacyl Peroxides with Enol Acetates
Published in Journal of organic chemistry (04-11-2022)“…The reactions of O-electrophiles, such as organic peroxides, with carbon nucleophiles are an umpolung alternative to the common approaches to C–O bond…”
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13
Electrochemical thiocyanation of barbituric acids
Published in Organic & biomolecular chemistry (04-05-2022)“…The electrochemical thiocyanation of barbituric acids with NH SCN was disclosed in an undivided cell under constant current conditions. The electrosynthesis is…”
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14
Five Roads That Converge at the Cyclic Peroxy-Criegee Intermediates: BF3‑Catalyzed Synthesis of β‑Hydroperoxy-β-peroxylactones
Published in Journal of organic chemistry (02-11-2018)“…We have discovered synthetic access to β-hydroperoxy-β-peroxylactones via BF3-catalyzed cyclizations of a variety of acyclic precursors, β-ketoesters and their…”
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15
The Ozone and Hydroperoxide Teamwork: Synthesis of Unsymmetrical Geminal Bisperoxides from Alkenes
Published in Organic letters (30-06-2023)“…Alkene ozonolysis is mostly known as a textbook reaction, resulting in carbonyl compounds. The combination of ozone and hydroperoxide was found to lead to the…”
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16
Macrocyclic Organic Peroxides: Constructing Medium and Large Cycles with O-O Bonds
Published in Chemistry an international journal (01-10-2024)“…Macrocycles bridge the gap between conventional small molecules and polymers. Drawing inspiration from successful carbon heteroatom-containing macrocycles,…”
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17
C−O coupling of Malonyl Peroxides with Enol Ethers via [5+2] Cycloaddition: Non‐Rubottom Oxidation
Published in Advanced synthesis & catalysis (02-07-2019)“…Malonyl peroxides act both as oxidants and reagents for C−O coupling in reactions with methyl and silyl enol ethers. In the proposed conditions, the oxidative…”
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18
Synthesis of five- and six-membered cyclic organic peroxides: Key transformations into peroxide ring-retaining products
Published in Beilstein journal of organic chemistry (08-01-2014)“…The present review describes the current status of synthetic five and six-membered cyclic peroxides such as 1,2-dioxolanes, 1,2,4-trioxolanes (ozonides),…”
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19
Lanthanide-Catalyzed Oxyfunctionalization of 1,3-Diketones, Acetoacetic Esters, And Malonates by Oxidative C–O Coupling with Malonyl Peroxides
Published in Journal of organic chemistry (05-02-2016)“…The lanthanide-catalyzed oxidative C–O coupling of 1,3-dicarbonyl compounds with diacyl peroxides, specifically the cyclic malonyl peroxides, has been…”
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20
Co‐Catalyzed Peroxidation of Cyclic β‐Dicarbonyls
Published in European journal of organic chemistry (02-04-2024)“…A Co‐catalyzed peroxidation of cyclic β‐dicarbonyls (cyclic 1,3‐diketones, 4‐hydroxy‐2(5H)‐furanones and Meldrum's acids) with TBHP has been disclosed. A…”
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