Search Results - "Vidal‐Gancedo, José"
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Polyphosphorhydrazone-Based Radical Dendrimers
Published in Molecules (Basel, Switzerland) (25-02-2021)“…The search for new biomedical applications of dendrimers has promoted the synthesis of new radical-based molecules. Specifically, obtaining radical dendrimers…”
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Metal-Free Radical Dendrimers as MRI Contrast Agents for Glioblastoma Diagnosis: Ex Vivo and In Vivo Approaches
Published in Biomacromolecules (11-07-2022)“…Simultaneously being a nonradiative and noninvasive technique makes magnetic resonance imaging (MRI) one of the highly required imaging approaches for the…”
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Synthesis and EPR Studies of Zinc and Copper Tris(2‐pyridylmethyl)amines (TPMA) Metal Complexes Containing TEMPO Functionalities
Published in European journal of organic chemistry (11-11-2024)“…A new family of stable radical‐containing polytopic ligands based on tris(2‐pyridylmethyl)amines TPMA architecture and their corresponding metal complexes have…”
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Redox-Active PTM Radical Dendrimers as Promising Multifunctional Molecular Switches
Published in Chemistry of materials (26-11-2019)“…Nowadays there is a great interest in using individual molecules as nanometer-scale switches and logic devices, with the aim of reaching higher power and…”
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Multifunctional Switch Based on Spin-Labeled Gold Nanoparticles
Published in Nano letters (26-01-2022)“…The fabrication of multifunctional switches is a fundamental step in the development of nanometer-scale molecular spintronic devices. The anchoring of active…”
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6
Intra- and Intermolecular Charge Transfer in Aggregates of Tetrathiafulvalene-Triphenylmethyl Radical Derivatives in Solution
Published in Journal of the American Chemical Society (08-05-2013)“…An extensive investigation of aggregation phenomena occurring in solution for a family of electron donor–acceptor derivatives, based on…”
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Design, Selection, and Characterization of Thioflavin-Based Intercalation Compounds with Metal Chelating Properties for Application in Alzheimer’s Disease
Published in Journal of the American Chemical Society (04-02-2009)“…Metal chelation is considered a rational therapeutic approach for interdicting Alzheimer’s amyloid pathogenesis. At present, enhancing the targeting and…”
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Magnetic and Electrochemical Properties of a TEMPO-Substituted Disulfide Diradical in Solution, in the Crystal, and on a Surface
Published in Chemistry : a European journal (26-01-2016)“…A study of the magnetic and electrochemical properties of a TEMPO‐substituted disulfide diradical in three different environments was carried out: in solution,…”
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Synthesis, X-Ray Structure, Magnetic Properties, and a Study of Intra/Intermolecular Radical-Radical Interactions of a Triradical TEMPO Compound
Published in Chemphyschem (26-10-2015)“…A novel triradical compound with a P=S core and three branches functionalized with 2,2,6,6‐tetramethylpiperidine‐1‐oxyl (TEMPO) radicals is synthesized and…”
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10
Fluorescent and Magnetic Radical Dendrimers as Potential Bimodal Imaging Probes
Published in Pharmaceutics (01-06-2023)“…Dual or multimodal imaging probes have emerged as powerful tools that improve detection sensitivity and accuracy in disease diagnosis by imaging techniques…”
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Tuning Spin‐Spin Interactions in Radical Dendrimers
Published in Chemphyschem (07-08-2018)“…Two generations of polyphosphorhydrazone (PPH) dendrimers were synthesized and fully functionalized with TEMPO radicals via acrylamido or imino group linkers…”
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12
Induced Self-Assembly of a Tetrathiafulvalene-Based Open-Shell Dyad through Intramolecular Electron Transfer
Published in Angewandte Chemie International Edition (29-10-2012)“…An organic switch: An open‐shell dyad, consisting of an electron acceptor perchlorotriphenylmethyl radical unit linked to an electron π‐donor…”
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13
Radical Dendrimers: A Family of Five Generations of Phosphorus Dendrimers Functionalized with TEMPO Radicals
Published in Macromolecules (25-11-2014)“…Five novel generations of phosphorus dendrimers based on a cyclotriphosphazene core with stable TEMPO radicals end groups have been synthesized and studied by…”
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Synthesis and Structural Characterization of a Dendrimer Model Compound Based on a Cyclotriphosphazene Core with TEMPO Radicals as Substituents
Published in Organic letters (19-07-2013)“…The synthesis of the 3Gc0T zero generation dendrimer with a cyclotriphosphazene core functionalized with nitroxyl radicals in its six branches has been…”
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Radical Dendrimers Based on Biocompatible Oligoethylene Glycol Dendrimers as Contrast Agents for MRI
Published in Pharmaceutics (14-08-2020)“…Finding alternatives to gadolinium (Gd)-based contrast agents (CA) with the same or even better paramagnetic properties is crucial to overcome their…”
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Coupling Tetracyanoquinodimethane to Tetrathiafulvalene: A Fused TCNQ-TTF-TCNQ Triad
Published in Angewandte Chemie International Edition (11-11-2011)“…Happy marriage: For the first time, a fused TCNQ–TTF–TCNQ triad has been synthesized and structurally characterized. Strong bending is observed in both the TTF…”
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Fully Water-Soluble Polyphosphorhydrazone-Based Radical Dendrimers Functionalized with Tyr-PROXYL Radicals as Metal-Free MRI T 1 Contrast Agents
Published in ACS applied bio materials (21-01-2020)“…The finding of alternative imaging probes to Gadolinium (Gd) and other metal based contrast agents (CA) is crucial to overcome their established toxicity…”
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18
Novel PTM–TEMPO Biradical for Fast Dissolution Dynamic Nuclear Polarization
Published in Organic letters (17-10-2014)“…The synthesis and characterization of a novel trityl-TEMPO biradical and the investigation of its properties as Dynamic Nuclear Polarization (DNP) polarizing…”
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Dithiophene-TTF Salts; New Ladder Structures and Spin-Ladder Behavior
Published in Inorganic chemistry (20-07-2015)“…(α-DT-TTF)2[Au(i-mnt)2] and (α-DT-TTF)2[Co(mnt)2] are two new salts of the donor α-dithiophene-tetrathiafulvalene with stable diamagnetic anions, both…”
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Self-Assembled Monolayers of Electroactive Polychlorotriphenylmethyl Radicals on Au(111)
Published in Journal of the American Chemical Society (23-04-2008)“…Two new polychlorotriphenylmethyl (PTM) derivatives bearing a thioacetate and a disulfide group have been synthesized to anchor on gold substrate. On the basis…”
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