Search Results - "Velkos, Georgios"
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Single-Electron Lanthanide-Lanthanide Bonds Inside Fullerenes toward Robust Redox-Active Molecular Magnets
Published in Accounts of chemical research (15-10-2019)“…Conspectus A characteristic phenomenon of lanthanide–fullerene interactions is the transfer of metal valence electrons to the carbon cage. With early…”
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Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
Published in Nature communications (04-02-2019)“…Engineering intramolecular exchange interactions between magnetic metal atoms is a ubiquitous strategy for designing molecular magnets. For lanthanides, the…”
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3
Substrate‐Independent Magnetic Bistability in Monolayers of the Single‐Molecule Magnet Dy2ScN@C80 on Metals and Insulators
Published in Angewandte Chemie International Edition (27-03-2020)“…Magnetic hysteresis is demonstrated for monolayers of the single‐molecule magnet (SMM) Dy2ScN@C80 deposited on Au(111), Ag(100), and MgO|Ag(100) surfaces by…”
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4
Nd─Nd Bond in Ih and D5h Cage Isomers of Nd2@C80 Stabilized by Electrophilic CF3 Addition
Published in Advanced science (01-01-2024)“…Synthesis of molecular compounds with metal–metal bonds between 4f elements is recognized as one of the fascinating milestones in lanthanide metallochemistry…”
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5
Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy‐Oxide Clusterfullerene Dy2O@C82
Published in Advanced science (16-10-2019)“…A new class of single‐molecule magnets (SMMs) based on Dy‐oxide clusterfullerenes is synthesized. Three isomers of Dy2O@C82 with Cs(6), C3v(8), and C2v(9) cage…”
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6
Magnetic Hysteresis at 10 K in Single Molecule Magnet Self‐Assembled on Gold
Published in Advanced science (01-03-2021)“…Tremendous progress in the development of single molecule magnets (SMMs) raises the question of their device integration. On this route, understanding the…”
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Electrophilic Trifluoromethylation of Dimetallofullerene Anions en Route to Air-Stable Single-Molecule Magnets with High Blocking Temperature of Magnetization
Published in Journal of the American Chemical Society (03-11-2021)“…Lanthanide dimetallofullerenes with single-electron M–M bonds are an important class of single molecular magnets and qubit candidates, but stabilization of…”
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High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb 2 @C 79 N with a Single-Electron Terbium-Terbium Bond
Published in Angewandte Chemie International Edition (23-04-2019)“…The azafullerene Tb @C N is found to be a single-molecule magnet with a high 100-s blocking temperature of magnetization of 24 K and large coercivity. Tb…”
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9
Robust Single Molecule Magnet Monolayers on Graphene and Graphite with Magnetic Hysteresis up to 28 K
Published in Advanced functional materials (01-11-2021)“…The chemical functionalization of fullerene single molecule magnet Tb2@C80(CH2Ph) enables the facile preparation of robust monolayers on graphene and highly…”
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Covalency magnetic axiality in Nd molecular magnets: Nd-photoluminescence, strong ligand-field, and unprecedented nephelauxetic effect in fullerenes NdMN@C (M = Sc, Lu, Y)
Published in Chemical science (Cambridge) (07-02-2024)“…Nd-based nitride clusterfullerenes NdM 2 N@C 80 with rare-earth metals of different sizes (M = Sc, Y, Lu) were synthesized to elucidate the influence of the…”
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11
Covalency versus magnetic axiality in Nd molecular magnets: Nd-photoluminescence, strong ligand-field, and unprecedented nephelauxetic effect in fullerenes NdM 2 N@C 80 (M = Sc, Lu, Y)
Published in Chemical science (Cambridge) (07-02-2024)“…Nd-based nitride clusterfullerenes NdM N@C with rare-earth metals of different sizes (M = Sc, Y, Lu) were synthesized to elucidate the influence of the cluster…”
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12
Nd─Nd Bond in I h and D 5h Cage Isomers of Nd 2 @C 80 Stabilized by Electrophilic CF 3 Addition
Published in Advanced science (01-01-2024)“…Synthesis of molecular compounds with metal-metal bonds between 4f elements is recognized as one of the fascinating milestones in lanthanide metallochemistry…”
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13
Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy2O@C72 and Dy2O@C74 with fused pentagon pairs and flexible Dy–(μ2-O)–Dy angle
Published in Chemical science (Cambridge) (14-05-2020)“…Dysprosium oxide clusterfullerenes Dy2O@Cs(10528)–C72 and Dy2O@C2(13333)–C74 are synthesized and characterized by single-crystal X-ray diffraction. Carbon…”
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14
Covalency versus magnetic axiality in Nd molecular magnets: Nd-photoluminescence, strong ligand-field, and unprecedented nephelauxetic effect in fullerenes NdM2N@C80 (M = Sc, Lu, Y)
Published in Chemical science (Cambridge) (07-02-2024)“…Nd-based nitride clusterfullerenes NdM2N@C80 with rare-earth metals of different sizes (M = Sc, Y, Lu) were synthesized to elucidate the influence of the…”
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15
Nd─Nd Bond in Ih and D5h Cage Isomers of Nd2 @C80 Stabilized by Electrophilic CF3 Addition
Published in Advanced science (01-01-2024)“…Synthesis of molecular compounds with metal-metal bonds between 4f elements is recognized as one of the fascinating milestones in lanthanide metallochemistry…”
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16
Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy2O@C72 and Dy2O@C74 with fused pentagon pairs and flexible Dy–(μ2-O)–Dy angle† †Electronic supplementary information (ESI) available. CCDC 1974305 and 1974314. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/d0sc00624f
Published in Chemical science (Cambridge) (20-04-2020)“…Clusterfullerenes Dy 2 O@C 72 and Dy 2 O@C 74 demonstrate a fine balance of exchange and dipolar interactions and slow relaxation of magnetization. Dysprosium…”
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17
Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy 2 O@C 72 and Dy 2 O@C 74 with fused pentagon pairs and flexible Dy-(μ 2 -O)-Dy angle
Published in Chemical science (Cambridge) (14-05-2020)“…Dysprosium oxide clusterfullerenes Dy O@C (10528)-C and Dy O@C (13333)-C are synthesized and characterized by single-crystal X-ray diffraction. Carbon cages of…”
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18
Substrate-Independent Magnetic Bistability in Monolayers of the Single-Molecule Magnet Dy 2 ScN@C 80 on Metals and Insulators
Published in Angewandte Chemie International Edition (27-03-2020)“…Magnetic hysteresis is demonstrated for monolayers of the single-molecule magnet (SMM) Dy ScN@C deposited on Au(111), Ag(100), and MgO|Ag(100) surfaces by…”
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19
High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb2@C79N with a Single‐Electron Terbium–Terbium Bond
Published in Angewandte Chemie International Edition (23-04-2019)“…The azafullerene Tb2@C79N is found to be a single‐molecule magnet with a high 100‐s blocking temperature of magnetization of 24 K and large coercivity. Tb…”
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20
Single Molecule Magnets: Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy‐Oxide Clusterfullerene Dy2O@C82 (Adv. Sci. 20/2019)
Published in Advanced science (16-10-2019)“…In article number 1901352, Fupin Liu, Stanislav M. Avdoshenko, Alexey A. Popov, Ning Chen, and co‐workers synthesize a new class of single‐molecule magnets…”
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