Search Results - "Vatsadze, Sergey Z."
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Stereoelectronic Chameleons: The Donor–Acceptor Dichotomy of Functional Groups
Published in Chemistry : a European journal (08-03-2017)“…Stereoelectronic factors account for the apparent reversal of donor–acceptor properties of a variety of functional groups by a simple change of their…”
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“Stereoelectronic Deprotection of Nitrogen”: Recovering Nucleophilicity with a Conformational Change
Published in Journal of organic chemistry (02-06-2023)“…Ureas are often thought of as “double amides” due to the obvious structural similarity of these functional groups. The main structural feature of an amide is…”
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Photoprocesses in Bis-Diethylamino Derivatives of 1,4- and 1,3-Distyrylbenzene
Published in Molecules (Basel, Switzerland) (31-08-2024)“…The photoprocesses of diethylamino derivatives of 1,4- and 1,3-distyrylbenzenes in MeCN were studied using absorption, luminescence, H NMR, and laser kinetic…”
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On the design of new europium heteroaromatic carboxylates for OLED application
Published in Dyes and pigments (01-11-2019)“…The approach to the directed synthesis of lanthanide aromatic carboxylates – precursors to the electroluminescent materials, - was proposed, namely the…”
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Photoprocesses in Derivatives of 1,4- and 1,3-Diazadistyryldibenzenes
Published in International journal of molecular sciences (05-12-2022)“…Photoprocesses in 1,4-diazadistyrylbenzene ( ) and 1,3-diazadistyrylbenzene derivative ( ) diperchlorates in MeCN were studied by absorption, luminescence, and…”
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Bispidine Platform as a Tool for Studying Amide Configuration Stability
Published in Molecules (Basel, Switzerland) (10-01-2022)“…In this work, the solution conformations of seventeen 3,7-diacyl bispidines were studied by means of NMR spectroscopy including VT NMR experiments. The acyl…”
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Novel Bispidine-Monoterpene Conjugates-Synthesis and Application as Ligands for the Catalytic Ethylation of Chalcones
Published in Molecules (Basel, Switzerland) (13-12-2021)“…A number of new chiral bispidines containing monoterpenoid fragments have been obtained. The bispidines were studied as ligands for Ni-catalyzed addition of…”
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Bispidine-Based Macrocycles: Achievements and Perspectives
Published in Organics (Basel) (01-09-2023)“…This review presents all currently known macroheterocyclic compounds that include a bispidine (3,7-diazabicyclo[3.3.1]nonane) fragment in their structure. A…”
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Reaction of β-Nitrostyrene with Diethyl Malonate in the Presence of Bispidines: The Unusual Role of the Organocatalyst
Published in Chemistry an international journal (01-06-2024)“…The aim of this work was the investigation of novel organocatalysts for the Michael addition of diethyl malonate to β-nitrostyrene. The methodology of the…”
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Plier Ligands for Trapping Neurotransmitters into Complexes for Sensitive Analysis by SERS Spectroscopy
Published in Biosensors (Basel) (11-01-2023)“…Catecholamines-dopamine, noradrenaline and adrenaline are important biomarkers of neurotransmitter metabolism, indicating neuroendocrine tumors and…”
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The main protease 3CLpro of the SARS-CoV-2 virus: how to turn an enemy into a helper
Published in Frontiers in bioengineering and biotechnology (29-06-2023)“…Despite the long history of use and the knowledge of the genetics and biochemistry of , problems are still possible in obtaining a soluble form of recombinant…”
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Corrigendum: The main protease 3CLpro of the SARS-CoV-2 virus: how to turn an enemy into a helper
Published in Frontiers in bioengineering and biotechnology (06-11-2023)“…[This corrects the article DOI: 10.3389/fbioe.2023.1187761.]…”
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Structure–Property Relationships of Dibenzylidenecyclohexanones
Published in ACS omega (29-03-2022)“…A series of symmetrical dibenzylidene derivatives of cyclohexanone were synthesized with the goal of studying the physicochemical properties of…”
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Isonitriles as Stereoelectronic Chameleons: The Donor–Acceptor Dichotomy in Radical Additions
Published in Journal of the American Chemical Society (31-10-2018)“…Radical addition to isonitriles (isocyanides) starts and continues all the way to the transition state (TS) mostly as a simple addition to a polarized π-bond…”
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Ferrocene-contained metal organic frameworks: From synthesis to applications
Published in Coordination chemistry reviews (01-03-2021)“…•The Fc-contained MOFs was first reviewed.•The Fc-contained MOFs can be clearly divided into four basic categories.•The synthesis methods of Fc-contained MOFs…”
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Preparation of Ferrocene‐Terminated Dendrimers for the Thermal Decomposition of Ammonium Perchlorate
Published in Macromolecular rapid communications. (01-07-2023)“…As a common oxidizer, ammonium perchlorate (AP) is an important component in composite solid propellants (CSPs). Ferrocene (Fc)‐based compounds are often…”
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Copper–Bispidine Complexes: Synthesis and Complex Stability Study
Published in ACS omega (30-11-2016)“…A new series of dicarboxylic derivatives of bispidines have been synthesized to develop novel copper(II) complexes suitable as imaging agents for positron…”
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Supramolecular Organogels Based on N -Benzyl, N' -Acylbispidinols
Published in Nanomaterials (Basel, Switzerland) (11-01-2019)“…The acylation of unsymmetrical -benzylbispidinols in aromatic solvents without an external base led to the formation of supramolecular gels, which possess…”
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Catalytic combustion of a dendrimer containing ferrocene units with anti‐migration performance on composite propellant
Published in Applied organometallic chemistry (01-10-2023)“…Ferrocene‐based compounds are promising burning rate catalysts due to their attractive catalytic activity, flammability, and non‐toxic performance…”
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A new approach to ferrocene derived alkenes via copper-catalyzed olefination
Published in Beilstein journal of organic chemistry (03-11-2015)“…A new approach to ferrocenyl haloalkenes and bis-alkenes was elaborated. The key procedure involves copper catalyzed olefination of N-unsubstituted hydrazones,…”
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