Search Results - "Vargeese, Anuj A."
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Experimental and computational investigation on the decomposition kinetics and uni-molecular degradation of (Z)-N,2,2,2-tetranitroacetimidic acid
Published in Journal of analytical and applied pyrolysis (01-10-2018)“…•Tetranitroacetimidic Acid (TNAA) is a recently developed green energetic oxidizer.•average experimental activation energy for TNAA degradation is 131 kJ mol−1…”
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Isoconversional kinetic analysis of decomposition of nitropyrazoles
Published in Thermochimica acta (20-12-2012)“…► Azoles undergo peculiar decomposition mechanism. ► Pyrazole and C-nitropyrazoles decomposed by multi step kinetics. ► N-nitropyrazole decomposed by single or…”
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A kinetic investigation on the mechanism and activity of copper oxide nanorods on the thermal decomposition of propellants
Published in Combustion and flame (01-03-2016)“…The application of transition metal oxides as catalyst for many industrial processes is long known and many of them are often employed as thermal…”
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Synergistically catalysed pyrolysis of hydroxyl terminated polybutadiene binder in composite propellants and burn rate enhancement by free-standing CuO nanoparticles
Published in Combustion and flame (01-08-2017)“…Free-standing nanoparticles are a ubiquitous requirement for high-efficiency catalytic applications. Here, we report the catalytic pyrolysis of hydroxyl…”
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Dendritic Polynitrato Energetic Motifs: Development and Exploration of Physicochemical Behavior through Theoretical and Experimental Approach
Published in ACS omega (30-11-2017)“…Considering the fundamental and most desirable characteristics of energetic materials, a series of 1,2,3-triazole-based heterocyclic energetic motifs nicely…”
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Decomposition Mechanism of Hexanitrohexaazaisowurtzitane (CL-20) by Coupled Computational and Experimental Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (09-05-2019)“…A novel degradation pathway of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) was identified using computational and experimental methods…”
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Kinetics and mechanism of hydrothermally prepared copper oxide nanorod catalyzed decomposition of ammonium nitrate
Published in Applied catalysis. A, General (07-12-2012)“…[Display omitted] ► Monoclinic CuO nanorods with aspect ratio ∼5 were hydrothermally synthesized. ► Catalytic decomposition of ammonium nitrate in presence of…”
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Role of Poly(vinyl alcohol) in the Crystal Growth of Ammonium Perchlorate
Published in Crystal growth & design (01-03-2008)“…One of the key aspects in the development of new inorganic materials is the synthesis of particles with specific sizes and morphologies. Nowadays,…”
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Anatase–brookite mixed phase nano TiO₂ catalyzed homolytic decomposition of ammonium nitrate
Published in Journal of hazardous materials (15-09-2011)“…Compared to the conventional ammonium perchlorate based solid rocket propellants, burning of ammonium nitrate (AN) based propellants produce environmentally…”
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Development of Green Energetic Oxidizers for Solid Propellant Applications: Present Status
Published in Propellants, explosives, pyrotechnics (24-10-2024)“…Abstract The quest for new high‐energy materials (HEMs) with superior performance properties compared to conventional HEMs has opened up a new area of research…”
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Decomposition Kinetics of Substituted Energetic Isowurtzitane Cage Molecules Hexanitrohexaazaisowurtzitane (CL‐20) and TEX: A Comparative Study
Published in ChemistrySelect (Weinheim) (14-06-2019)“…N‐substituted hexa(N‐Nitro) compound 2,4,6,8,10,12‐Hexanitro‐2,4,6,8,10,12‐hexaazatetracyclo‐ [5.5.0.05,9.03,11] dodecane (HNIW or CL‐20) and the O‐substituted…”
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Development of bimetallic spinel catalysts for low-temperature decomposition of ammonium dinitramide monopropellants
Published in Defence technology (01-12-2023)“…Ammonium dinitramide (ADN) based liquid monopropellants have been identified as environmentally benign substitutes for hydrazine monopropellant. However, new…”
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Phase transformation of heat-resistant energetic material BDNAPM studied by Raman spectroscopy and X-ray diffraction
Published in Journal of materials science (01-03-2022)“…Bis(3,5-dinitro-4-aminopyrazolyl) methane (BDNAPM) is a new insensitive secondary explosive with a high thermal decomposition temperature. The higher thermal…”
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Kinetics of Nano Titanium Dioxide Catalyzed Thermal Decomposition of Ammonium Nitrate and Ammonium Nitrate-Based Composite Solid Propellant
Published in Propellants, explosives, pyrotechnics (01-04-2015)“…This study deals with the influence of nanosized titanium dioxide (TiO2) catalysts on the decomposition kinetics of ammonium nitrate (AN) and ammonium…”
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A Kinetics Investigation on the Nitro-Nitrite Rearrangement Mediated Thermal Decomposition of High Temperature Monoclinic Phase of 1,1-Diamino-2,2-Dinitroethylene (γ-Fox-7)
Published in Journal of chemical sciences (Bangalore, India) (01-02-2017)“…1,1-Diamino-2,2-dinitroethylene (DADNE), commonly known as FOX-7, is one of the novel high energy density molecules recently developed along with CL-20, TNAZ…”
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New High Pressure Phases of Energetic Material TEX: Evidence from Raman Spectroscopy, X‑ray Diffraction, and First-Principles Calculations
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-08-2018)“…Samples of energetic material TEX (C6H6N4O8) are studied using Raman spectroscopy and X-ray diffraction (XRD) up to 27 GPa pressure. There are clear changes in…”
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Effect of Copper Oxide, Titanium Dioxide, and Lithium Fluoride on the Thermal Behavior and Decomposition Kinetics of Ammonium Nitrate
Published in Journal of energetic materials (03-07-2014)“…Ammonium nitrate (AN) is crystallized along with copper oxide, titanium dioxide, and lithium fluoride. Thermal kinetic constants for the decomposition reaction…”
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Thermal stability of habit modified ammonium nitrate: Insights from isoconversional kinetic analysis
Published in Thermochimica acta (20-09-2011)“…► Phase and habit modified ammonium nitrate (PMAN) is synthesized. ► PMAN has similar moisture absorption characteristics of AN at 53% and 62% RH. ► AN and…”
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Use of potassium ferrocyanide as habit modifier in the size reduction and phase modification of ammonium nitrate crystals in slurries
Published in Journal of hazardous materials (15-08-2010)“…Ammonium nitrate (AN) is an inorganic crystalline compound used as a solid propellant oxidizer and as a nitrogenous fertilizer. The practical use of AN as…”
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Effect of method of crystallization on the IV–III and IV–II polymorphic transitions of ammonium nitrate
Published in Journal of hazardous materials (15-01-2009)“…A study has been undertaken on the effect of crystallization method on the IV ↔ III transition of ammonium nitrate (AN). AN is crystallized in three different…”
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