Search Results - "VanDerveer, Donald"
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Enhanced Metal Ion Selectivity of 2,9-Di-(pyrid-2-yl)-1,10-phenanthroline and Its Use as a Fluorescent Sensor for Cadmium(II)
Published in Journal of the American Chemical Society (30-01-2008)“…The metal ion complexing properties of the ligand DPP (2,9-di-(pyrid-2-yl)-1,10-phenanthroline) were studied by crystallography, fluorimetry, and UV−visible…”
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Complexes of Greatly Enhanced Thermodynamic Stability and Metal Ion Size-Based Selectivity, Formed by the Highly Preorganized Non-Macrocyclic Ligand 1,10-Phenanthroline-2,9-dicarboxylic Acid. A Thermodynamic and Crystallographic Study
Published in Inorganic chemistry (13-11-2006)“…The metal ion-complexing properties of 1,10-phenanthroline-2,9-dicarboxylic acid (PDA) are reported. The protonation constants (pK 1 = 4.75, pK 2 = 2.53) and…”
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3
Strong Metal Ion Size Based Selectivity of the Highly Preorganized Ligand PDA (1,10-Phenanthroline-2,9-dicarboxylic Acid) with Trivalent Metal Ions. A Crystallographic, Fluorometric, and Thermodynamic Study
Published in Inorganic chemistry (17-08-2009)“…The selectivity of the rigid ligand PDA (1,10-phenanthroline-2,9-dicarboxylic acid) for some M(III) (M = metal) ions is presented. The structure of…”
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Bis-perfluorocycloalkenyl (PFCA) aryl ether monomers towards a versatile class of semi-fluorinated aryl ether polymers
Published in Tetrahedron letters (10-07-2013)“…A unique class of perfluorocycloalkenyl (PFCA) aryl ether monomers was synthesized from commercially available perfluorocycloalkenes (PFCAs) and bisphenols in…”
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Tuning the Photoinduced Electron-Transfer Thermodynamics in 1,3,5-Triaryl-2-pyrazoline Fluorophores: X-ray Structures, Photophysical Characterization, Computational Analysis, and in Vivo Evaluation
Published in Journal of the American Chemical Society (02-04-2003)“…A series of donor-substituted 1,3,5-triaryl-2-pyrazoline fluorophores were structurally characterized by X-ray analysis, and their photophysical properties…”
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Selectivity of the Highly Preorganized Tetradentate Ligand 2,9-Di(pyrid-2-yl)-1,10-phenanthroline for Metal Ions in Aqueous Solution, Including Lanthanide(III) Ions and the Uranyl(VI) Cation
Published in Inorganic chemistry (07-01-2013)“…Some metal ion complexing properties of DPP (2,9-Di(pyrid-2-yl)-1,10-phenanthroline) are reported with a variety of Ln(III) (Lanthanide(III)) ions and…”
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7
High-Resolution Chemical Imaging through Tissue with an X-ray Scintillator Sensor
Published in Analytical chemistry (Washington) (01-07-2011)“…We describe a novel method for high-resolution chemical imaging on a surface embedded in tissue. The sensor surface consists of an X-ray scintillator film…”
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Synthesis of cis and trans Bis-alkynyl Complexes of Cr(III) and Rh(III) Supported by a Tetradentate Macrocyclic Amine: A Spectroscopic Investigation of the M(III)–Alkynyl Interaction
Published in Inorganic chemistry (03-10-2011)“…Alkynyl complexes of the type [M(cyclam)(CCR)2]OTf (where cyclam = 1,4,8,11-tetraazacyclotetradecane; M = Rh(III) or Cr(III); and R = phenyl, 4-methylphenyl,…”
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9
Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt-Inclusion Vanadate Hybrids
Published in Angewandte Chemie (International ed.) (05-05-2008)“…Acentric vanadates: Three unique structure types of the vanadate‐based mixed‐metal oxide systems (salt)⋅MnII‐VV‐O and (salt)⋅CuII‐VV‐O are presented, with a…”
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Metal-Ion-Complexing Properties of 2-(Pyrid-2′-yl)-1,10-phenanthroline, a More Preorganized Analogue of Terpyridyl. A Crystallographic, Fluorescence, and Thermodynamic Study
Published in Inorganic chemistry (05-03-2012)“…Some metal-ion-complexing properties of the ligand 2-(pyrid-2′-yl)-1,10-phenanthroline (MPP) are reported. MPP is of interest in that it is a more preorganized…”
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Convenient Preparation of a Novel Class of Imidazo[1,5-a]pyridines: Decisive Role by Ammonium Acetate in Chemoselectivity
Published in Journal of organic chemistry (27-06-2003)“…A facile and one-pot straightforward methodology has been developed to prepare a novel class of imidazo[1,5-a]pyridines. A key role played by ammonium acetate…”
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Cationic five-coordinate Pt(II) complexes as donors in the formation of Pt-->Ag dative bonds
Published in Inorganic chemistry (14-11-2005)“…A unique trinuclear cluster containing two short Pt-->Ag dative bonds was prepared and characterized crystallographically. Two monocationic orthometalated…”
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13
Optical imaging in tissue with X-ray excited luminescent sensors
Published in Analyst (London) (07-09-2011)“…We report a high-spatial resolution imaging technique to measure optical absorption and detect chemical and physical changes on surfaces embedded in thick…”
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14
Preparation of a Select Tautomer of Various Unsymmetrical 1,3,5-Pentanetriones, (1Z,4Z)‑1-(Aryl)-1,5-dihydroxy-5-phenylpenta-1,4-dien-3-ones, a 4H‑1-benzothiopyran-4-one, and a 2‑(2-oxoyl)quinolin-4(1H)‑one
Published in Industrial & engineering chemistry research (29-07-2015)“…Deprotonation of 1-benzoylacetone with excess lithium hexamethyldisilazide (LHMDS) or lithium diisopropylamide (LDA) resulted in a dilithium dianion-type…”
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15
C–H Bond Activation by a Palladium(II) Thioether Complex: Formation of the Bis(nitromethanate) Complex [Pd(9S3)(CH2NO2)2]
Published in Organometallics (24-09-2012)“…Palladium(II) acetate reacts with 1 equiv of 1,4,7-trithiacyclononane (9S3) at room temperature to produce the neutral complex [Pd(9S3)(OAc)2] (1; OAc– =…”
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Excited-State Intramolecular Proton Transfer in 2-(2‘-Tosylaminophenyl)benzimidazole
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (29-08-2002)“…The spectroscopic properties of 2-(2‘-tosylaminophenyl)benzimidazole (TPBI) have been studied in a series of different solvents. As revealed by absorbance,…”
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17
Emissive Chromium(III) Complexes with Substituted Arylethynyl Ligands
Published in Inorganic chemistry (15-12-2008)“…Arylethynylchromium(III) complexes of the form trans-[Cr(cyclam)(CCC6H4R)2]OTf (where cyclam = 1,4,8,11-tetraazacyclotetradecane, R = H, CH3, or CF3 in the…”
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Cyclometallated Pt(II) and Pd(II) complexes with a trithiacrown ligand
Published in Dalton transactions : an international journal of inorganic chemistry (14-04-2008)“…We report the synthesis and full characterization for a series of cyclometallated complexes of Pt(II) and Pd(II) incorporating the fluxional trithiacrown…”
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Mercury-199 NMR Studies of Thiacrown and Related Macrocyclic Complexes: The Crystal Structures of [Hg(18S6)](PF6)2 and [Hg(9N3)2](ClO4)2
Published in Inorganic chemistry (08-08-2005)“…We wish to report the first measurements of 199Hg NMR chemical shift data for a series of homoleptic Hg(II) complexes with thiacrown ligands and related aza…”
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20
Factors Controlling Metal-Ion Selectivity in the Binding Sites of Calcium-Binding Proteins. The Metal-Binding Properties of Amide Donors. A Crystallographic and Thermodynamic Study
Published in Inorganic chemistry (14-11-2005)“…The metal-ion complexing properties of the ligand EDTAM (ethylenediamine-N,N,N‘,N‘-tetraacetamide) are investigated as a model for the role of amide oxygen…”
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