Search Results - "Van Hecke, Kristof"
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Metal‐Free Cyclization of ortho‐Nitroaryl Ynamides and Ynamines towards Spiropseudoindoxyls
Published in Angewandte Chemie International Edition (14-05-2018)“…An efficient metal‐free cascade reaction between 1‐dibromovinyl‐2‐nitro‐substituted arenes and secondary amines results in the formation of polycyclic…”
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2
Direct Synthesis of the 2D Copper(II) 5‐Prop‐2‐ynoxyisophthalate MOF: Comment on “Surface Functionalization of Porous Coordination Nanocages Via Click Chemistry and Their Application in Drug Delivery”
Published in Advanced materials (Weinheim) (01-05-2019)“…Synthesis of metal–organic materials is often dependent on the reaction conditions of suitable solvent/solvent mixture and temperature. A new finding based on…”
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3
Stereoselective and Modular Assembly Method for Heterocycle‐Fused Daucane Sesquiterpenoids
Published in Chemistry : a European journal (18-09-2018)“…A stereoselective synthetic method is reported for the molecular framework found in common daucane and isodaucane sesquiterpenoid natural products. The…”
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4
Pyrrolidinium Ionic Liquid Crystals
Published in Chemistry : a European journal (01-01-2009)“…N‐Alkyl‐N‐methylpyrrolidinium cations have been used for the design of ionic liquid crystals, including a new type of uranium‐containing metallomesogen…”
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5
A Robust Molecular Catalyst Generated In Situ for Photo‐ and Electrochemical Water Oxidation
Published in ChemSusChem (09-03-2017)“…Water splitting is the key step towards artificial photosystems for solar energy conversion and storage in the form of chemical bonding. The oxidation of water…”
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6
In vitro Anti‐atherogenic Properties of N‐Heterocyclic Carbene Aurate(I) Compounds
Published in ChemMedChem (06-12-2018)“…The anti‐atherogenic (anti‐inflammatory) properties of various aurate(I) salts, of the general formula [NHC⋅H][AuCl2] (NHC=N‐heterocyclic carbene) were…”
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7
Copper(I)-Containing Ionic Liquids for High-Rate Electrodeposition
Published in Chemistry : a European journal (26-04-2011)“…New metal‐containing ionic liquids [Cu(CH3CN)n][Tf2N] (n=2, 4; Tf2N=bis(trifluoromethylsulfonyl)‐ amide) have been synthesised and used as a non‐aqueous…”
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8
Total Synthesis of (+/−)-Frondosin B and (+/−)-5-epi-Liphagal by Using a Concise (4+3) Cycloaddition Approach
Published in Chemistry : a European journal (03-01-2014)“…A recently developed (4+3) cycloaddition between dienes and furfuryl alcohols, as precursors of oxyallyl‐type cations, has been used as a key step in the…”
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9
Visible and Near-Infrared Emission by Samarium(III)-Containing Ionic Liquid Mixtures
Published in Inorganic chemistry (06-04-2009)“…Highly luminescent anionic samarium(III) β-diketonate and dipicolinate complexes were dissolved in the imidazolium ionic liquid 1-hexyl-3-methylimidazolium…”
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10
Polynuclear Metal Complexes Obtained from the Task-Specific Ionic Liquid Betainium Bistriflimide
Published in Crystal growth & design (01-04-2008)“…The task-specific ionic liquid betainium bis(trifluoromethylsulfonyl)imide, [Hbet][Tf2N], was used to dissolve metal oxides and hydroxides. The crystal…”
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11
Speciation of Rare-Earth Metal Complexes in Ionic Liquids: A Multiple-Technique Approach
Published in Chemistry : a European journal (26-01-2009)“…The dissolution process of metal complexes in ionic liquids was investigated by a multiple‐technique approach to reveal the solvate species of the metal in…”
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12
Synthesis of pyrrolidine-based hamamelitannin analogues as quorum sensing inhibitors in Staphylococcus aureus
Published in Beilstein journal of organic chemistry (12-11-2018)“…Interfering with bacterial cell-to-cell communication is a promising strategy to combat antimicrobial resistance. The natural product hamamelitannin and…”
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13
Synthesis of Non‐Symmetrical Nitrogen‐Containing Curcuminoids in the Pursuit of New Anticancer Candidates
Published in ChemistryOpen (Weinheim) (01-02-2019)“…Curcumin is known to display pronounced anticancer effects and a variety of other biological activities. However, the low bioavailability and fast metabolism…”
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14
Boron Complexes of Glyoxal‐Derived Ugi Adducts as a New Class of Aggregation‐Induced Emission Photoluminescent Materials
Published in Chemistry, an Asian journal (18-04-2017)“…A series of O,O‐chelated boron complexes was prepared through a four‐component Ugi reaction followed by complexation of the resulting 1,3‐dicarbonyl compounds…”
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15
Enantioselective Assembly of a Ruthenium(II) Polypyridyl Complex into a Double Helix
Published in Angewandte Chemie International Edition (18-08-2014)“…Evolution can increase the complexity of matter by self‐organization into helical architectures, the best example being the DNA double helix. One common…”
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16
Efficient Synthesis of the Indoloazocine Framework via Intramolecular Alkyne Carbocyclization
Published in Organic letters (20-08-2009)“…A microwave-assisted protocol based on an Hg(OTf)2 catalyzed intramolecular alkyne carbocyclization reaction was developed for selective construction of the…”
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17
Cobalt(II) Complexes of Nitrile-Functionalized Ionic Liquids
Published in Chemistry : a European journal (08-02-2010)“…A series of nitrile‐functionalized ionic liquids were found to exhibit temperature‐dependent miscibility (thermomorphism) with the lower alcohols. Their…”
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18
Diazadithia[7]helicenes: Synthetic Exploration, Solid-State Structure, and Properties
Published in Chemistry : a European journal (02-09-2013)“…Diazadithia[7]helicenes were synthesized from the readily available building block ethyl 7‐chloro‐8‐formylthieno[3,2‐f]quinoline‐2‐carboxylate by a Wittig…”
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19
Visible Light‐fueled Mechanical Motions with Dynamic Phosphorescence Induced by Topochemical [2+2] Reactions in Organoboron Crystals
Published in Angewandte Chemie International Edition (10-07-2023)“…In the quest for essential energy solutions towards an ecological friendly future, the transformation of visible light/solar energy into mechanical motions in…”
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20
Deformation-induced phosphorescence shift in a 2D elastically flexible organic single crystal: role of chalcogen-centered weak interactions
Published in Chemical science (Cambridge) (14-09-2022)“…Mechanically responsive organic luminescent crystals are one of the promising choices of materials for flexible photonic devices. However, the change in…”
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