Search Results - "VLAD, M"
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Design and properties of 3D scaffolds for bone tissue engineering
Published in Acta biomaterialia (15-09-2016)“…[Display omitted] In this study, the Voronoi tessellation method has been used to design novel bone like three dimension (3D) porous scaffolds. The Voronoi…”
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[2+2] Cycloadditions with an Iron Carbene: A Critical Step in Enyne Metathesis
Published in Journal of the American Chemical Society (21-04-2021)“…Ruthenium carbenes, famously used in olefin metathesis, have impacted numerous research areas, ranging from synthesis to materials and biology. Although in the…”
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Synthesis and Reactivity of a Nucleophilic Palladium(II) Carbene
Published in Organometallics (10-11-2014)“…Two formal palladium carbene complexes, [PC(sp2)P]Pd(PR3) (3: R = Me; 4: R = Ph) were isolated and characterized from [PC(sp3)H2P] ([PC(sp3)H2P] =…”
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Iron Olefin Metathesis: Unlocking Reactivity and Mechanistic Insights
Published in Journal of the American Chemical Society (03-07-2024)“…Olefin metathesis catalyzed by iron complexes has garnered substantial interest due to iron’s abundance and nontoxicity relative to ruthenium, yet its full…”
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5
C–H Activation Reactions of a Nucleophilic Palladium Carbene
Published in Organometallics (12-10-2015)“…The reactivity of a nucleophilic palladium carbene, [PC(sp2)P]Pd(PMe3) (1; [PC(sp2)P] = bis[2-(diisopropylphosphino)phenyl]methylene), toward the C–H…”
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Redox-induced umpolung of transition metal carbenes
Published in Chemical science (Cambridge) (01-01-2015)“…Metal carbene complexes have been at the forefront of organic and organometallic synthesis and are instrumental in guiding future sustainable chemistry…”
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Fast generation of Gaussian random fields for direct numerical simulations of stochastic transport
Published in Statistics and computing (01-09-2021)“…We propose a novel discrete method of constructing Gaussian Random Fields based on a combination of modified spectral representations, Fourier and Blob. The…”
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An Adaptable Chelating Diphosphine Ligand for the Stabilization of Palladium and Platinum Carbenes
Published in Organometallics (13-02-2017)“…Group 10 metal carbenes are proposed in catalytic transformations; however, their isolation remains difficult without the presence of a heteroatom donor. The…”
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9
Random and quasi-coherent aspects in particle motion and their effects on transport and turbulence evolution
Published in New journal of physics (28-02-2017)“…The quasi-coherent effects in two-dimensional incompressible turbulence are analyzed starting from the test particle trajectories. They can acquire coherent…”
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10
Hidden drifts in turbulence
Published in Europhysics letters (01-12-2018)“…The paper defines and discusses the concept of hidden drifts in two-dimensional turbulence. These are ordered components of the trajectories that average to…”
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Three-Coordinate Nickel Carbene Complexes and Their One-Electron Oxidation Products
Published in Journal of the American Chemical Society (30-04-2014)“…The synthesis and characterization of two new carbene complexes, (dtbpe)NiCH(dmp) (1; dtbpe = 1,2-bis(di-tert-butylphosphino)ethane; dmp =…”
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12
Budd‐chiari syndrome causing acute liver failure: A multicenter case series
Published in Liver transplantation (01-02-2017)“…Budd‐Chiari syndrome (BCS) is a rare disease resulting from obstruction of the hepatic venous outflow tract that typically presents with abdominal pain,…”
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13
Flexible Coordination of Diphosphine Ligands Leading to cis and trans Pd(0), Pd(II), and Rh(I) Complexes
Published in Inorganic chemistry (18-08-2014)“…A series of diphosphine ligands i Pr2P–C6H4–X–C6H4–P i Pr2 (for ligand L1, X = CH2; for ligand L2, X = CH2CH2) was investigated to determine the preference for…”
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Ag(I) and Tl(I) Precursors as Transfer Agents of a Pyrrole-Based Pincer Ligand to Late Transition Metals
Published in Inorganic chemistry (01-12-2014)“…A PNP ligand, PNpyrP ((PNpyrP)H = 2,5-bis((di-iso-propylphosphino)methyl)pyrrole), which employs a pyrrole unit as a central anionic nitrogen donor, was…”
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Platelet-Rich Plasma in Dermatology: New Insights on the Cellular Mechanism of Skin Repair and Regeneration
Published in Life (Basel, Switzerland) (01-12-2023)“…The skin's recognised functions may undergo physiological alterations due to ageing, manifesting as varying degrees of facial wrinkles, diminished tautness,…”
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Plasma MicroRNAs as Novel Biomarkers for Endometriosis and Endometriosis-Associated Ovarian Cancer
Published in Clinical cancer research (01-03-2013)“…Endometriosis, a largely benign, chronic inflammatory disease, is an independent risk factor for endometrioid and clear cell epithelial ovarian tumors. We…”
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Hydrogen-Atom Abstraction from Ni(I) Phosphido and Amido Complexes Gives Phosphinidene and Imide Ligands
Published in Journal of the American Chemical Society (03-11-2010)“…Hydrogen-atom abstraction from M−E(H) to generate ME-containing complexes (E = PR, NR) is not well studied because only a few complexes are known to undergo…”
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Synthesis and Reactivity of Two-Coordinate Ni(I) Alkyl and Aryl Complexes
Published in Journal of the American Chemical Society (11-12-2013)“…Reaction of [(IPr)Ni(μ-Cl)]2 (1-Cl; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with ClMg{CH(SiMe3)2}·Et2O affords (IPr)Ni{CH(SiMe3)2} (2), a…”
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Coordination of a Hemilabile Pincer Ligand with an Olefinic Backbone to Mid-to-Late Transition Metals
Published in Inorganic chemistry (21-07-2014)“…The coordination chemistry of a neutral tPCHCHP pincer (tPCHCHP = 2,2′-bis(di-iso-propylphosphino)-trans-stilbene) with metals that form stable complexes…”
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Synthesis and Characterization of Three-Coordinate Ni(III)-Imide Complexes
Published in Journal of the American Chemical Society (24-08-2011)“…A new family of low-coordinate nickel imides supported by 1,2-bis(di-tert-butylphosphino)ethane was synthesized. Oxidation of nickel(II) complexes led to the…”
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