Search Results - "VITORICA, J"
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Cyclometallated ruthenium catalyst enables late-stage directed arylation of pharmaceuticals
Published in Nature chemistry (01-07-2018)“…Biaryls are ubiquitous core structures in drugs, agrochemicals and organic materials that have profoundly improved many aspects of our society. Although…”
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Electronic, Structural and Functional Versatility in Tetrathiafulvalene‐Lanthanide Metal–Organic Frameworks
Published in Chemistry : a European journal (25-09-2019)“…Tetrathiafulvalene‐lanthanide (TTF‐Ln) metal–organic frameworks (MOFs) are an interesting class of multifunctional materials in which porosity can be combined…”
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3
Single-Step Enantioselective Synthesis of Mechanically Planar Chiral [2]Rotaxanes Using a Chiral Leaving Group Strategy
Published in Journal of the American Chemical Society (27-05-2020)“…We report a one-step enantioselective synthesis of mechanically planar chiral [2]rotaxanes. Previous studies of such molecules have generally involved the…”
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4
A Solomon Link through an Interwoven Molecular Grid
Published in Angewandte Chemie International Edition (22-06-2015)“…A molecular Solomon link was synthesized through the assembly of an interwoven molecular grid consisting of four…”
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5
A Six‐Crossing Doubly Interlocked [2]Catenane with Twisted Rings, and a Molecular Granny Knot
Published in Angewandte Chemie International Edition (15-10-2018)“…A molecular 623 link (a six crossing, doubly interlocked, [2]catenane with twisted rings) and a 31#31 granny knot (a composite knot made up of two trefoil…”
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6
Braiding a molecular knot with eight crossings
Published in Science (American Association for the Advancement of Science) (13-01-2017)“…Knots may ultimately prove just as versatile and useful at the nanoscale as at the macroscale. However, the lack of synthetic routes to all but the simplest…”
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7
A modular design of molecular qubits to implement universal quantum gates
Published in Nature communications (25-04-2016)“…The physical implementation of quantum information processing relies on individual modules—qubits—and operations that modify such modules either individually…”
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8
Allosteric initiation and regulation of catalysis with a molecular knot
Published in Science (American Association for the Advancement of Science) (24-06-2016)“…Molecular knots occur in DNA, proteins, and other macromolecules. However, the benefits that can potentially arise from tying molecules in knots are, for the…”
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9
Spontaneous Assembly of Rotaxanes from a Primary Amine, Crown Ether and Electrophile
Published in Journal of the American Chemical Society (16-05-2018)“…We report the synthesis of crown ether-ammonium, amide and amine [2]rotaxanes via transition state stabilization of axle-forming reactions. In contrast to the…”
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10
Transamidation-Driven Molecular Pumps
Published in Journal of the American Chemical Society (31-08-2022)“…We report a new class of synthetic molecular pumps that use a stepwise information ratchet mechanism to achieve the kinetic gating required to sequester their…”
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11
Lanthanide Template Synthesis of Trefoil Knots of Single Handedness
Published in Journal of the American Chemical Society (19-08-2015)“…We report on the assembly of 2,6-pyridinedicarboxamide ligands (1) with point chirality about lanthanide metal ion (Ln3+) templates, in which the helical…”
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12
Stereoselective synthesis of a composite knot with nine crossings
Published in Nature chemistry (01-11-2018)“…The simultaneous synthesis of a molecular nine-crossing composite knot that contains three trefoil tangles of the same handedness and a 9 7 3 link (a type of…”
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13
Weak functional group interactions revealed through metal-free active template rotaxane synthesis
Published in Nature communications (06-02-2020)“…Modest functional group interactions can play important roles in molecular recognition, catalysis and self-assembly. However, weakly associated binding motifs…”
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14
Stepwise Operation of a Molecular Rotary Motor Driven by an Appel Reaction
Published in Journal of the American Chemical Society (21-02-2024)“…To date, only a small number of chemistries and chemical fueling strategies have been successfully used to operate artificial molecular motors. Here, we report…”
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15
Chemically Fueled Communication Along a Scaffolded Nanoscale Array of Squaramides
Published in Angewandte Chemie International Edition (18-09-2023)“…Relaying conformational change over several nanometers is central to the function of allosterically regulated proteins. Replicating this mechanism artificially…”
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16
A Blueprint for the Stabilization of Sub-Valent Alkaline Earth Complexes
Published in Chemistry : a European journal (26-09-2023)“…The study of sub-valent Group 2 chemistry is a relatively new research field, being established in 2007 with the report of the first Mg(I) dimers. These…”
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17
Tuning the Force, Speed, and Efficiency of an Autonomous Chemically Fueled Information Ratchet
Published in Journal of the American Chemical Society (21-09-2022)“…Autonomous chemically fueled molecular machines that function through information ratchet mechanisms underpin the nonequilibrium processes that sustain life…”
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18
Ag/Pd Cocatalyzed Direct Arylation of Fluoroarene Derivatives with Aryl Bromides
Published in ACS catalysis (07-02-2020)“…Diverse C–H functionalizations catalyzed by Pd employ Ag(I) salts added as halide abstractors or oxidants. Recent reports have shown that Ag can also perform…”
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A Chiral Cyclometalated Iridium Star of David [2]Catenane
Published in Journal of the American Chemical Society (20-01-2021)“…Although circular helicates can be assembled with a range of labile transition-metal centers, solely “chiral-at-metal” examples (i.e., systems without chiral…”
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Semiconductor Porous Hydrogen-Bonded Organic Frameworks Based on Tetrathiafulvalene Derivatives
Published in Journal of the American Chemical Society (25-05-2022)“…Herein, we report on the use of tetrathiavulvalene-tetrabenzoic acid, H4TTFTB, to engender semiconductivity in porous hydrogen-bonded organic frameworks…”
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