Search Results - "VERBRUGGE, Mark W"
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Synergetic Effects of Inorganic Components in Solid Electrolyte Interphase on High Cycle Efficiency of Lithium Ion Batteries
Published in Nano letters (09-03-2016)“…The solid electrolyte interphase (SEI), a passivation layer formed on electrodes, is critical to battery performance and durability. The inorganic components…”
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Degradation of lithium ion batteries employing graphite negatives and nickel-cobalt-manganese oxide + spinel manganese oxide positives: Part 1, aging mechanisms and life estimation
Published in Journal of power sources (10-12-2014)“…We examine the aging and degradation of graphite/composite metal oxide cells. Non-destructive electrochemical methods were used to monitor the capacity loss,…”
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Potentiostatic Intermittent Titration Technique for Electrodes Governed by Diffusion and Interfacial Reaction
Published in Journal of physical chemistry. C (12-01-2012)“…The potentiostatic intermittent titration technique (PITT) is one of the widely used methods for determining the diffusion coefficient in electrochemical…”
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Evolution of stress within a spherical insertion electrode particle under potentiostatic and galvanostatic operation
Published in Journal of power sources (01-05-2009)“…Lithium ion battery electrode materials generally experience significant volume changes during charging and discharging caused by concentration changes within…”
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Modeling diffusion-induced stress in nanowire electrode structures
Published in Journal of power sources (01-08-2010)“…There is an intense, worldwide effort to develop durable lithium ion batteries with high energy and power densities for a wide range of applications, including…”
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Method to deduce the critical size for interfacial delamination of patterned electrode structures and application to lithiation of thin-film silicon islands
Published in Journal of power sources (15-05-2012)“…► We model delamination of patterned silicon thin film electrodes from a substrate. ► We perform plane strain and axisymmetric energy analysis of the…”
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Atomic Layered Coating Enabling Ultrafast Surface Kinetics at Silicon Electrodes in Lithium Ion Batteries
Published in The journal of physical chemistry letters (17-10-2013)“…The interfacial charge-transfer kinetics plays an important role in the rate capabilities of lithium ion batteries (LIBs). The control of the charge-transfer…”
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Optimum Particle Size in Silicon Electrodes Dictated by Chemomechanical Deformation of the SEI
Published in Advanced functional materials (01-05-2021)“…Nanostructured alloy‐forming anode materials can resist fracture that is caused by extreme volume changes during cycling. However, the higher surface area per…”
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Degradation of lithium ion batteries employing graphite negatives and nickel―cobalt―manganese oxide + spinel manganese oxide positives: Part 2, chemical―mechanical degradation model
Published in Journal of power sources (25-12-2014)“…Capacity fade is reported for 1.5 Ah Li-ion batteries containing a mixture of Li-Ni-Co-Mn oxide (NCM) + Li-Mn oxide spinel (LMO) as positive electrode material…”
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On the optimal sizing of batteries for electric vehicles and the influence of fast charge
Published in Journal of power sources (30-04-2018)“…We provide a brief summary of advanced battery technologies and a framework (i.e., a simple model) for assessing electric-vehicle (EV) architectures and…”
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Toward High Cycle Efficiency of Silicon-Based Negative Electrodes by Designing the Solid Electrolyte Interphase
Published in Advanced energy materials (01-03-2015)“…The relationship between the composition, electrochemical properties, and mechanical properties of the solid electrolyte interphase (SEI) and its impact on the…”
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Asymmetric Rate Behavior of Si Anodes for Lithium-Ion Batteries: Ultrafast De-Lithiation versus Sluggish Lithiation at High Current Densities
Published in Advanced energy materials (01-03-2015)“…The combined effect of lithium‐ion diffusion, potential‐concentration gradient, and stress plays a critical role in the rate capability and cycle life of…”
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Multifunctional Lithium-Ion-Exchanged Zeolite-Coated Separator for Lithium-Ion Batteries
Published in ACS applied energy materials (24-12-2018)“…Positive electrodes utilizing more manganese are the primary choices for lithium-ion battery applications in electric vehicles and other large-scale energy…”
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Experimental and Theoretical Characterization of Electrode Materials that Undergo Large Volume Changes and Application to the Lithium–Silicon System
Published in Journal of physical chemistry. C (12-03-2015)“…The life and performance of lithium-ion batteries are related to the mechanical expansion and contraction of the active materials, particularly for…”
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Electrochemical-Thermal Modeling of Large-Format, Thin-Film, Lithium-Ion Batteries with Cocurrent and Countercurrent Tab Connections Using a Reduced-Order Model
Published in ECS Advances (01-12-2023)“…We derive and implement a new reduced-order model for the simulation of large-format, thin-film batteries with cocurrent and countercurrent tab connections. We…”
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Potentiostatic intermittent titration technique (PITT) for spherical particles with finite interfacial kinetics
Published in Electrochimica acta (30-07-2012)“…[Display omitted] ► Modified PITT considering interfacial kinetics and spherical geometry. ► Applicable to composite electrodes consisting of particles. ►…”
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The influence of surface inhomogeneity on the overcharge and lithium plating of graphite electrodes
Published in JPhys Energy (01-01-2020)“…We seek to clarify phenomena involved in the overcharge of a graphite electrode in a lithium ion battery, including lithium (Li) plating. In Baker and…”
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Microwave-assisted hydrothermal synthesis of nanostructured spinel Li4Ti5O12 as anode materials for lithium ion batteries
Published in Electrochimica acta (29-02-2012)“…► Microwave-assisted hydrothermal (MH) method was used for the synthesis of Li4Ti5O12. ► The synthesis process by MH method was much faster than conventional…”
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Thermodynamics, stress, and Stefan-Maxwell diffusion in solids: application to small-strain materials used in commercial lithium-ion batteries
Published in Journal of solid state electrochemistry (01-01-2016)“…The life and performance of lithium-ion batteries are related to the mechanical expansion and contraction of the active materials. We develop a theory and…”
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