Search Results - "Uria, Uxue"
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Catalytic Enantioselective Cloke–Wilson Rearrangement
Published in Angewandte Chemie International Edition (02-07-2018)“…Racemic cyclopropyl ketones undergo enantioselective rearrangement to deliver the corresponding dihydrofurans in the presence of a chiral phosphoric acid as…”
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2
Chiral Organic Contact Ion Pairs in Metal-Free Catalytic Asymmetric Allylic Substitutions
Published in Journal of the American Chemical Society (23-03-2011)“…Chiral contact ion-pair catalysis with particular focus on metal-free processes is gaining in interest. As a result, new perspectives are opened, and highly…”
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3
Catalytic Enantioselective [5+2] Cycloaddition between Oxidopyrylium Ylides and Enals under Dienamine Activation
Published in Angewandte Chemie International Edition (02-03-2015)“…Benzopyrylium ylides generated in situ from 1‐acetoxyisochroman‐4‐ones reacted with α,β‐unsaturated aldehydes in the presence of a bifunctional…”
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4
Direct Catalytic Azidation of Allylic Alcohols
Published in Organic letters (03-02-2012)“…A direct catalytic azidation of primary, secondary, and tertiary allylic alcohols has been developed. This new azidation reaction affords the corresponding…”
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5
Enantioselective Oxidative (4+3) Cycloadditions between Allenamides and Furans through Bifunctional Hydrogen‐Bonding/Ion‐Pairing Interactions
Published in Angewandte Chemie International Edition (21-08-2017)“…BINOL‐based N‐trifluoromethanesulfonyl phosphoramides catalyze the enantioselective (4+3) cycloaddition between furans and oxyallyl cations, the latter being…”
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6
Organocatalytically Generated Donor–Acceptor Cyclopropanes in Domino Reactions. One-Step Enantioselective Synthesis of Pyrrolo[1,2‑a]quinolines
Published in Organic letters (18-03-2016)“…An easy and straightforward procedure has been developed for the synthesis of highly enantioenriched pyrrolo[1,2-a]quinolines through a one-pot process that…”
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7
Catalytic Asymmetric Domino Michael Addition−Alkylation Reaction: Enantioselective Synthesis of Dihydrofurans
Published in Organic letters (17-12-2010)“…A catalytic enantioselective synthesis of dihydrofurans has been developed. 1,3-Dicarbonyl derivatives react with (E)-β,β-bromonitrostyrenes in the presence of…”
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8
Asymmetric Dual Enamine Catalysis/Hydrogen Bonding Activation
Published in Catalysts (01-07-2023)“…Asymmetric enamine base activation of carbonyl compounds is a well-known and widely used strategy for providing functionalization of organic compounds in an…”
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9
Enantioselective Synthesis of Tertiary Propargylic Alcohols under N-Heterocyclic Carbene Catalysis
Published in Chemistry : a European journal (01-06-2015)“…A straightforward procedure to carry out the enantioselective benzoin reaction between aldehydes and ynones by employing a chiral N‐heterocyclic carbene (NHC)…”
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10
Organocatalytic activation of cyclopropanes in asymmetric synthesis
Published in Tetrahedron chem (01-08-2023)“…Cyclopropanes are strained carbocycles that can undergo ring opening reactions in which one of the C–C bond present in the cycle is broken following a radical…”
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11
Favoring Trienamine Activation through Unconjugated Dienals: Organocatalytic Enantioselective Remote Functionalization of Alkenes
Published in Chemistry : a European journal (17-02-2014)“…Unconjugated 2,5‐dienals are more reactive substrates than the corresponding fully conjugated α,β,γ,δ‐unsaturated aldehydes towards organocatalytic activation…”
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12
Kinetic Resolution in Transannular Morita-Baylis-Hillman Reaction: An Approximation to the Synthesis of Sesquiterpenes from Guaiane Family
Published in Catalysts (01-01-2022)“…An approximation to the synthesis of several sesquiterpenes from the Guaiane family is described in which the core structure was obtained through a…”
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13
5-Mercaptotetrazoles as Synthetic Equivalents of Nitrogen-Contaning Functional Groups. The Case of the Organocatalytic Enantioselective aza-Michael Reaction
Published in Organic letters (21-01-2011)“…5-Mercaptotetrazoles have been identified as useful and versatile Michael donors in enantioselective amine-catalyzed aza-Michael reactions with α,β-unsaturated…”
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14
Organocatalytic and enantioselective Michael reaction between α-nitroesters and nitroalkenes. Syn/anti-selectivity control using catalysts with the same absolute backbone chirality
Published in Beilstein journal of organic chemistry (14-12-2015)“…The asymmetric and catalytic Michael reaction between α-nitroesters and nitroalkenes has been studied in the presence of two bifunctional catalysts both…”
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15
Base free catalyzed enantioselective Michael reaction of bis(phenylsulfonyl)methane to α,β -unsaturated aldehydes under iminium activation
Published in Current topics in medicinal chemistry (01-01-2014)“…The Michael reaction of bis(phenylsulfonyl)methane with α,β-unsaturated aldehydes in the presence of catalytic amounts of a chiral secondary amine is…”
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16
Catalytic Enantioselective Cloke–Wilson Rearrangement
Published in Angewandte Chemie (02-07-2018)“…Racemic cyclopropyl ketones undergo enantioselective rearrangement to deliver the corresponding dihydrofurans in the presence of a chiral phosphoric acid as…”
Get full text
Journal Article -
17
Enantioselective Oxidative (4+3) Cycloadditions between Allenamides and Furans through Bifunctional Hydrogen‐Bonding/Ion‐Pairing Interactions
Published in Angewandte Chemie (21-08-2017)“…BINOL‐based N‐trifluoromethanesulfonyl phosphoramides catalyze the enantioselective (4+3) cycloaddition between furans and oxyallyl cations, the latter being…”
Get full text
Journal Article -
18
Catalytic Enantioselective [5+2] Cycloaddition between Oxidopyrylium Ylides and Enals under Dienamine Activation
Published in Angewandte Chemie (02-03-2015)“…Benzopyrylium ylides generated in situ from 1‐acetoxyisochroman‐4‐ones reacted with α,β‐unsaturated aldehydes in the presence of a bifunctional…”
Get full text
Journal Article -
19
Catalytic Enantioselective Transannular Morita–Baylis–Hillman Reaction
Published in Journal of the American Chemical Society (19-06-2019)“…Catalytic and enantioselective approaches to transannular reactions are very limited and mostly are based on chiral Lewis acid catalyzed pericyclic reactions…”
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20
Mechanistic Insights on the Enantioselective (4+3) Cycloaddition Between Oxyallylcations and Furans Catalyzed by BINOL‐Based Phosphoramides
Published in Advanced synthesis & catalysis (20-02-2024)“…The mechanism of the enantioselective (4+3) cycloaddition between furan derivatives and oxyallylcations, which are generated from the corresponding oxiranes…”
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