Search Results - "Ubukata, Hiroki"
-
1
Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors
Published in Nature communications (08-01-2021)“…Most solid-state materials are composed of p-block anions, only in recent years the introduction of hydride anions (1s 2 ) in oxides (e.g., SrVO 2 H, BaTi(O,H)…”
Get full text
Journal Article -
2
Vanadium Hydride as an Ammonia Synthesis Catalyst
Published in ChemCatChem (12-01-2021)“…Early 3d transition metals, such as Ti, V, or Nb are known to be inactive for the Haber‐Bosch process, due to their strong M−N bonds. However, recently some…”
Get full text
Journal Article -
3
Chemical Pressure-Induced Anion Order–Disorder Transition in LnHO Enabled by Hydride Size Flexibility
Published in Journal of the American Chemical Society (12-09-2018)“…While cation order–disorder transitions have been achieved in a wide range of materials and provide crucial effects in various physical and chemical…”
Get full text
Journal Article -
4
Mixed alkali-ion transport and storage in atomic-disordered honeycomb layered NaKNi2TeO6
Published in Nature communications (02-08-2021)“…Honeycomb layered oxides constitute an emerging class of materials that show interesting physicochemical and electrochemical properties. However, the…”
Get full text
Journal Article -
5
Trihalide Mixing by Size-Flexible H– Ions in Layered Ba2H3 (Cl, Br, I)
Published in Chemistry of materials (08-06-2022)“…According to the Hume-Rothery rule, anions with a large difference in ionic radii, for example, chloride and iodide anions, cannot form solid solutions. In…”
Get full text
Journal Article -
6
Highly Electron-Doped TaON Single-Crystal Growth by a High-Pressure Flux Method
Published in Inorganic chemistry (25-07-2022)“…Transition-metal oxynitrides have a variety of functions such as visible light-responsive catalysts and dielectric materials, but acquiring single crystals…”
Get full text
Journal Article -
7
Photocatalytic Water Oxidation by Phosphotungstate and Mg-Al Layered Double Hydroxide Hybrid
Published in Chemistry letters (05-02-2022)“…Immobilization of phosphotungstate ([PW12O40]3−) in the interlayer space of a Mg-Al layered double hydroxide (LDH) resulted in an absorption edge at ∼350 nm,…”
Get full text
Journal Article -
8
Honeycomb‐Layered Oxides With Silver Atom Bilayers and Emergence of Non‐Abelian SU(2) Interactions
Published in Advanced science (01-02-2023)“…Honeycomb‐layered oxides with monovalent or divalent, monolayered cationic lattices generally exhibit myriad crystalline features encompassing rich…”
Get full text
Journal Article -
9
Kinetic Control of Anion Stoichiometry in Hexagonal BaTiO3
Published in Inorganics (01-06-2022)“…The cubic oxyhydride perovskite BaTiO3−xHx, where the well-known ferroelectric oxide BaTiO3 is partially hydridized, exhibits a variety of functions such as…”
Get full text
Journal Article -
10
Hydride Conductivity in an Anion-Ordered Fluorite Structure LnHO with an Enlarged Bottleneck
Published in Chemistry of materials (24-09-2019)“…We report on the hydride (H–) conductivity in fluorite-type LnHO oxyhydrides (Ln = lanthanide) using samples prepared under high pressure. It is found that,…”
Get full text
Journal Article -
11
Pressure-Induced Anion Order-Disorder Transition in Layered Perovskite Sr 2 LiHOCl 2
Published in Inorganic chemistry (22-05-2023)“…While cation order-disorder transitions have been extensively investigated because of their decisive impact on chemical and physical properties, only few anion…”
Get full text
Journal Article -
12
Pressure-Induced Anion Order–Disorder Transition in Layered Perovskite Sr2LiHOCl2
Published in Inorganic chemistry (22-05-2023)“…While cation order–disorder transitions have been extensively investigated because of their decisive impact on chemical and physical properties, only few anion…”
Get full text
Journal Article -
13
Tuning Proton Conduction by Staggered Arrays of Polar Preyssler-Type Oxoclusters
Published in Journal of the American Chemical Society (25-09-2024)“…Polyoxometalates (POMs), anionic nanosized oxoclusters that can be considered as fragments of metal oxides, have been extensively studied for their diverse…”
Get full text
Journal Article -
14
Structural Transformation in LnHS (Ln = La, Nd, Gd, and Er) with Coordination Change between an S‑Centered Octahedron and a Trigonal Prism
Published in Inorganic chemistry (01-05-2023)“…Lanthanide hydride chalcogenides LnHSe and LnHTe (Ln = lanthanides) crystallize in two polymorphs, 2H and 1H structures (ZrBeSi-type and filled-WC-type…”
Get full text
Journal Article -
15
Pressure-induced structural phase transition in BaHCl
Published in Journal of solid state chemistry (01-08-2022)“…We have investigated the structural evolution of BaHCl under high pressure using in-situ synchrotron X-ray diffraction up to 30 GPa. The in-situ observation…”
Get full text
Journal Article -
16
High-pressure phase behavior of LnHO (Ln = lanthanides): Entropy stabilization of the fluorite structure
Published in Solid state sciences (01-08-2023)“…In this study, we investigate the phase behavior in LnHO (Ln = Nd, Gd, and Er) at external pressures up to 5 GPa. In contrast to LaHO, we observed a direct…”
Get full text
Journal Article -
17
High-pressure X-ray study of NbON oxynitride: direct transition from baddeleyite to cotunnite structure
Published in Chemistry letters (24-06-2024)“…Abstract The structural properties of NbON oxynitride under high pressure were investigated through in situ synchrotron X-ray diffraction (SXRD) up to 43 GPa…”
Get full text
Journal Article -
18
Mechanochemical Synthesis of Perovskite Oxyhydrides: Insights from Shear Modulus
Published in Journal of the American Chemical Society (01-05-2024)“…Perovskite oxyhydrides have attracted recent attention due to their intriguing properties such as ionic conductivity and catalysis, but their repertoire is…”
Get full text
Journal Article -
19
Intersite Charge Transfer through Eu 4f Band Engineering in Eu 1– x Sr x VO 2 H Oxyhydride Films
Published in Chemistry of materials (23-04-2024)Get full text
Journal Article -
20
Intersite Charge Transfer through Eu 4f Band Engineering in Eu1–x Sr x VO2H Oxyhydride Films
Published in Chemistry of materials (23-04-2024)“…Perovskite oxyhydride EuVO2H exhibits a Mott insulating state derived from VIIIO2 layers and a ferromagnetic state derived from EuIIH layers, with compressive…”
Get full text
Journal Article