Search Results - "Turovskaya, M. K."
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Reactivity of Inorganic α-Nucleophiles in Acyl Transfer in Aqueous and Micellar Media: IV. Peroxyhydrolysis of Acyl Derivatives in Organized Microheterogeneous Systems1
Published in Russian journal of organic chemistry (01-02-2024)“…The micellar effects in the perhydrolysis and base-catalyzed hydrolysis of 4-nitrophenyl esters of phosphoric, phosphonic, and toluenesulfonic acids in…”
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Reactivity of Inorganic α-Nucleophiles in Acyl Transfer Processes in Water and Surfactant Micelles: III. Systems Based on Dimeric Cationic Imidazolium Surfactants in Alkaline Hydrolysis of Ethyl 4-Nitrophenyl Ethylphosphonate
Published in Russian journal of organic chemistry (01-03-2021)“…The kinetics of alkaline hydrolysis of ethyl 4-nitrophenyl ethylphosphonate in micelles formed by cationic dimeric imidazolium surfactants [AlkIm + (CH 2 ) m…”
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Supernucleophilic Systems Underlain by Functionalized Surfactants in Cleavage of 4-Nitrophenyl Esters of Phosphorus and Sulfur Acids: IV. Micellar Effects of Functionalized Surfactants with a Variable Nature of the Head Group and Hydrophobicity in Transfer Reactions of the Phosphonyl Group
Published in Russian journal of organic chemistry (01-11-2018)“…[2-(Hydroxyimino)]dimethylalkylammonium bromides (Alk = C 16 H 33 , C 14 H 29 , C 12 H 25 ) were synthesized and their reactivity was investigated in the…”
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Reactivity of co-micellar systems based on dimeric functionalized tetraalkylammonium surfactant in phosphoryl and sulfonyl group transfer processes
Published in Russian journal of organic chemistry (2017)“…The reactivity of co-micellar systems based on dimeric functionalized tetraalkylammonium surfactant in phosphoryl and sulfonyl group transfer processes is…”
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Reactivity of inorganic α-nucleophiles in acyl group transfer processes in water and surfactant micelles: I. Systems based on organic complexes of tribromide anion
Published in Russian journal of organic chemistry (2017)“…Systems based on organic complexes of tribromide anion generate upon dissolution in water nucleophile–oxidant couple HOBr/BrO – and accelerate hydrolysis of…”
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Supernucleophilic systems based on functionalized surfactants in the decomposition of 4-nitrophenyl esters derived from phosphorus and sulfur acids. III. Reactivity of mixed micellar systems based on tetraalkylammonium and imidazolium surfactants
Published in Russian journal of organic chemistry (01-08-2015)“…Reactivity of mixed micellar systems based on the functionalized imidazolium and tetraalkylammonium surfactanats in the reaction of cleavage of 4-nitrophenyl…”
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Reactivity of micellar systems based on supernucleophilic functional surfactants in processes of acyl group transfer
Published in Russian journal of organic chemistry (01-05-2012)“…Processes of cleavage of 4-nitrophenyl esters of diethylphosphoric, diethylphosphonic, and 4-toluenesulfonic acids were investigated occurring in micelles of…”
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Peroxyhydrolysis of 4-nitrophenyl diethyl phosphate in micellar systems based on imidazolium gemini surfactants
Published in Theoretical and experimental chemistry (01-05-2012)“…The nucleophilic reactivity of HO – and HOO – ions in the presence of imidazole gemini surfactants toward 4-nitrophenyl diethyl phosphate (NPDEP) was studied…”
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New sources of “active” halogen bis(dialkylamide)hydrogen dibromobromates, efficient reagents for destruction of ecotoxicants
Published in Russian journal of organic chemistry (01-05-2008)“…Bis(dialkylamide)hydrogen dibromobromates were synthesized and their reactivity was investigated in decomposition of diethylphosphonic, diethylphosphoric, and…”
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Role of the hydrophobic properties of functional detergents on micellar effects in the dissociation of environmental toxicants
Published in Theoretical and experimental chemistry (01-11-2010)“…1-Alkyl-3-(2-oximinopropyl)imidazolium chlorides were prepared with different alkyl chain lengths (Alk = C 12 H 25 , C 14 H 29 ). Some physicochemical indices…”
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Characteristic features of the change in reactivity of supernucleophilic functional surfactants in acyl group transfer processes
Published in Theoretical and experimental chemistry (01-07-2010)“…We consider the factors responsible for the nucleophilicity and micellar effects of surfactants based on imidazole and pyridine, functionalized by an oximate…”
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Reactivity of micelle-forming 1-alkyl-3(1-oximinoethyl)pyridinium bromides in acyl group transfer reactions
Published in Theoretical and experimental chemistry (01-03-2011)“…The reactivity of a series of micelle-forming 1-alkyl-3-(1-oximinoethyl)pyridinium bromides in the cleavage of typical acyl substrates was studied and…”
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Structure of the head group, nucleophilicity, and micellar effects of functional detergents in acyl transfer reactions
Published in Theoretical and experimental chemistry (01-04-2008)“…The micellar effects of 1-cetyl-2-methyl-3-(2-hydroxyiminopropyl)imidazolium and 1-cetyl-3-hydroxyiminomethylpyridinium halides in acyl transfer reactions…”
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Micellar effects of cetyltrimethylammonium dibromobromate in phosphoryl group transfer reactions
Published in Theoretical and experimental chemistry (01-07-2007)Get full text
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Nucleophilicity of functional surface active substances in the transfer of phosphoryl groups
Published in Theoretical and experimental chemistry (01-09-2006)Get full text
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Kinetics and mechanism of the reaction of benzoyl chloride with 4-(4?-N,N-dimethylaminostyryl)pyridine-N-oxide in toluene
Published in Theoretical and experimental chemistry (01-09-1995)Get full text
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Bis(dialkylamide)hydrogen Dibromobromate Precursors of Hypobromite Ion in Reactions with Nerve and Blister Agent Simulants
Published in Journal of organic chemistry (24-12-2004)“…Hypobromite ion, BrO-, is an effective α-nucleophile that reacts rapidly with activated phosphorus(V) and sulfonate esters. The parent acid rapidly oxidizes…”
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