Preparation, Characterization, and Mechanistic Considerations for 1,1,1-Tri(thioacetyl)ethane and 1,1-Di(thioacetyl)ethene

Two new compounds, 1,1,1-tri(thioacetyl)ethane and 1,1-di(thioacetyl)ethene, arose during reactions of acetyl methoxy(thiocarbonyl) sulfide with potassium methyl xanthate. Relevant mechanisms were elucidated, which in turn suggested novel streamlined routes to these same compounds. Several furt...

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Bibliographic Details
Published in:	Journal of organic chemistry Vol. 88; no. 11; pp. 7535 - 7538
Main Authors:	Goebel, Erik S., Turcotte, Matthew J., Henley, Madeleine J., Young, Victor G., Barany, George
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 02-06-2023
Online Access:	Get full text
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Summary:	Two new compounds, 1,1,1-tri(thioacetyl)ethane and 1,1-di(thioacetyl)ethene, arose during reactions of acetyl methoxy(thiocarbonyl) sulfide with potassium methyl xanthate. Relevant mechanisms were elucidated, which in turn suggested novel streamlined routes to these same compounds. Several further transformations of the title compounds were demonstrated, suggesting their potential synthetic utility.
Bibliography:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	0022-3263 1520-6904
DOI:	10.1021/acs.joc.3c00377