Silica gel modified with tetraalkylammonium halides as an available and efficient catalyst for the synthesis of cyclic organic carbonates from epoxides and CO2

Silica gel modified with tetraalkylammonium halides as an available and efficient catalyst for the synthesis of cyclic organic carbonates from epoxides and CO2

Silica gel with the additives of tetraalkylammonium halides serves as an efficient catalyst for the solvent-free insertion of carbon dioxide into epoxides (10–56 atm of CO 2 , 105–100 °C), leading to cyclic carbonates with quantitative conversion.

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Bibliographic Details
Published in:Russian chemical bulletin Vol. 68; no. 10; pp. 1866 - 1868
Main Authors: Lyubimov, S. E., Sokolovskaya, M. V., Chowdhury, B., Arzumanyan, A. V., Tukhvatshin, R. S., Ibragimova, L. F., Tyutyunov, A. A., Davankov, V. A., Muzafarov, A. M.
Format: Journal Article
Language:English
Published: New York Springer US 01-10-2019
Springer Nature B.V
Subjects:
Additives
Carbon dioxide
Carbonates
Catalysts
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Halides
Inorganic Chemistry
Organic Chemistry
Silica gel
Silicon dioxide
carbon dioxide
epoxides
silica gel
cyclic carbonates
carbon dioxide fixation
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Description
Summary:Silica gel with the additives of tetraalkylammonium halides serves as an efficient catalyst for the solvent-free insertion of carbon dioxide into epoxides (10–56 atm of CO 2 , 105–100 °C), leading to cyclic carbonates with quantitative conversion.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-019-2637-6