Search Results - "Tsuyoshi A. Kohlgruber"

Assembly of Uranyl Peroxides from Ball Milled Solids by Julien, Patrick A., Castle, Grace, Theriault, Jordan, Kohlgruber, Tsuyoshi A., Oliver, Allen G., Burns, Peter C.

“…Mechanochemistry enables transformations of highly insoluble materials such as uranium dioxide or the mineral studtite [(UO2)­(O2)­(H2O)2]·(H2O)2 into uranyl…”
Get full text

Exploring the Role of Organic Functional Groups in the Ionothermal Synthesis of Uranyl Phosphate Materials by Kohlgruber, Tsuyoshi A., Felton, Daniel E., Traustason, Hrafn, Burns, Peter C.

“…Four new hybrid organic‐inorganic uranyl phosphate compounds were structurally characterized after single crystals were grown via ionothermal synthesis using…”
Get full text

The Role of Alkalis in Orchestrating Uranyl‐Peroxide Reactivity Leading to Direct Air Capture of Carbon Dioxide by Arteaga, Ana, Arino, Trevor, Moore, Guy C., Bustos, Jenna L., Horton, Matthew K., Persson, Kristin A., Li, Jun, Stickle, William F., Kohlgruber, Tsuyoshi A., Surbella, Robert G., Nyman, May

“…Spectator ions have known and emerging roles in aqueous metal‐cation chemistry, respectively directing solubility, speciation, and reactivity. Here, we isolate…”
Get full text

Cover Feature: The Role of Alkalis in Orchestrating Uranyl‐Peroxide Reactivity Leading to Direct Air Capture of Carbon Dioxide (Chem. Eur. J. 27/2024) by Arteaga, Ana, Arino, Trevor, Moore, Guy C., Bustos, Jenna L., Horton, Matthew K., Persson, Kristin A., Li, Jun, Stickle, William F., Kohlgruber, Tsuyoshi A., Surbella, Robert G., Nyman, May

“…Nuclear double duty? When coupled with heavy alkali counter‐cations, depleted uranium (from nuclear fuel production) in the form of a uranyl triperoxide is a…”
Get full text

(NH4)2[UO2Cl4]·2H2O, a new uranyl tetrachloride with ammonium charge-balancing cations by Tsuyoshi A. Kohlgruber, Robert G. Surbella III

“…A new uranyl tetrachloride salt with chemical formula, (NH4)2[UO2Cl4]·2H2O, namely, diammonium uranyl tetrachloride dihydrate, 1, was prepared and crystallized…”
Get full text

(NH4)2[UO2Cl4]·2H2O, a new uranyl tetra-chloride with ammonium charge-balancing cations by Kohlgruber, Tsuyoshi A, Surbella Iii, Robert G

“…While several actinyl tetra­halides have been synthesized and their structures reported, (NH 4 ) 2 (UO 2 Cl 4 )·2H 2 O represents a new uranyl tetra­chloride…”
Get full text

Effect of Ionothermal Conditions on the Crystallization of Organically Templated Uranyl Sulfate Compounds by Kohlgruber, Tsuyoshi A, Felton, Daniel E, Perry, Samuel N, Oliver, Allen G, Burns, Peter C

“…Seven novel uranyl sulfate compounds were crystallized by ionothermal synthesis methods through systematic changes in experimental conditions. The parameters…”
Get full text

Ionothermal Synthesis of Uranyl Vanadate Nanoshell Heteropolyoxometalates by Kohlgruber, Tsuyoshi A, Senchyk, Ganna A, Rodriguez, Virginia G, Mackley, Stephanie A, Dal Bo, Fabrice, Aksenov, Sergey M, Szymanowski, Jennifer E. S, Sigmon, Ginger E, Oliver, Allen G, Burns, Peter C

“…Two uranyl vanadate heteropolyoxometalates (h-POMs) have been synthesized by ionothermal methods using the ionic liquid 1-ethyl-3-methylimidazolium diethyl…”
Get full text

In situ deca-rbonylation of N , N -di-methyl-formamide to form di-methyl-ammonium cations in the hybrid framework compound {[(CH 3 ) 2 NH 2 ] 2 [Zn{O 3 PC 6 H 2 (OH) 2 PO 3 }]} n by Soriano, Josemaria S, Galeas, Bryan E, Garrett, Paul, Flores, Ryan A, Pinedo, Juan L, Kohlgruber, Tsuyoshi A, Felton, Daniel, Adelani, Pius O

“…The title phospho-nate-based organic-inorganic hybrid framework, poly[bis(dimethylammonium) [(μ -2,5-dihydroxybenzene-1,4-diphosphonato)zinc(II)]], {(C H N)…”
Get full text

In situ decarbonylation of N , N -dimethylformamide to form dimethylammonium cations in the hybrid framework compound {[(CH 3 ) 2 NH 2 ] 2 [Zn{O 3 PC 6 H 2 (OH) 2 PO 3 }]} n by Soriano, Josemaria S., Galeas, Bryan E., Garrett, Paul, Flores, Ryan A., Pinedo, Juan L., Kohlgruber, Tsuyoshi A., Felton, Daniel, Adelani, Pius O.

“…The title phosphonate-based organic–inorganic hybrid framework, poly[bis(dimethylammonium) [(μ 4 -2,5-dihydroxybenzene-1,4-diphosphonato)zinc(II)]], {(C 2 H 8…”
Get full text

(NH 4 ) 2 [UO 2 Cl 4 ]·2H 2 O, a new uranyl tetrachloride with ammonium charge-balancing cations by Kohlgruber, Tsuyoshi A., Surbella III, Robert G.

“…A new uranyl tetrachloride salt with chemical formula, (NH 4 ) 2 [UO 2 Cl 4 ]·2H 2 O, namely, diammonium uranyl tetrachloride dihydrate, 1 , was prepared and…”
Get full text

Utilizing Ionic Liquids as Bifunctional Reagents for the Ionothermal Synthesis of Uranyl Compounds by Felton, Daniel E., Kohlgruber, Tsuyoshi A., Tucker, Zachary D., Gulotty, Eva M., Ashfeld, Brandon L., Burns, Peter C.

“…The extraction of actinides, specifically uranyl and other actinyl ions, from fission products is a critical aspect of spent nuclear fuel reprocessing. In this…”
Get full text

Hydrogen bond network and bond valence analysis on uranyl sulfate compounds with organic-based interstitial cations by Kohlgruber, Tsuyoshi A., Perry, Samuel N., Sigmon, Ginger E., Oliver, Allen G., Burns, Peter C.

“…Seven new uranyl sulfate compounds with organic charge-balancing cations have been synthesized and structurally characterized. The structural unit topologies…”
Get full text

Hydrogen bond network and bond valence analysis on uranyl sulfate compounds with organic-based interstitial cations by Kohlgruber, Tsuyoshi A., Perry, Samuel N., Sigmon, Ginger E., Oliver, Allen G., Burns, Peter C.

“…Seven new uranyl sulfate compounds with organic charge-balancing cations have been synthesized and structurally characterized. The structural unit topologies…”
Get full text

The role of 1-ethyl-3-methylimidazolium diethyl phosphate ionic liquid in uranyl phosphate compounds by Kohlgruber, Tsuyoshi A., Mackley, Stephanie A., Bo, Fabrice Dal, Aksenov, Sergey M., Burns, Peter C.

“…The ionic liquid 1-ethyl-3-methylimidazolium diethyl phosphate (EMIM-Et2PO4) was used in the synthesis of four new hybrid organic-inorganic uranyl phosphates…”
Get full text

The role of 1-ethyl-3-methylimidazolium diethyl phosphate ionic liquid in uranyl phosphate compounds by Kohlgruber, Tsuyoshi A., Mackley, Stephanie A., Bo, Fabrice Dal, Aksenov, Sergey M., Burns, Peter C.

“…Not provided…”
Get full text