Search Results - "Tsunashima, Ryo"
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Ferroelectric Behavior of a Hexamethylenetetramine‐Based Molecular Perovskite Structure
Published in Angewandte Chemie International Edition (01-07-2019)“…We report the development of a molecular ferroelectric material inspired by the hexamethylenetetramine (hmta) non‐centrosymmetric molecular rotator. The…”
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The multigene classifiers 95GC/42GC/155GC for precision medicine in ER‐positive HER2‐negative early breast cancer
Published in Cancer science (01-04-2021)“…In clinical decision‐making, to decide the indication for adjuvant chemotherapy for estrogen receptor‐positive (ER+), human epidermal growth factor…”
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Anisotropic Polyoxometalate Cages Assembled via Layers of Heteroanion Templates
Published in Journal of the American Chemical Society (28-08-2019)“…The synthesis of anisotropic redox-active polyoxometalates (POMs) that can switch between multiple states is critical for understanding the mechanism of…”
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Synthesis, Structure, and Electrochemical Properties of [Na(SO3)2(RPO3)4MoV4MoVI14O49]5− (R = Propyl or t-Butyl)
Published in Bulletin of the Chemical Society of Japan (15-05-2019)“…New mixed-valence polyoxometalate (POM)-organic hybrids, i.e., [Na(SO3)2(PrPO3)4MoV4MoVI14O49]5− and [Na(SO3)2(t-BuPO3)4MoV4MoVI14O49]5−, were synthesised and…”
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Emergence of the super antenna effect in mixed crystals of ytterbium and lutetium complexes showing near-infrared luminescence
Published in RSC advances (26-10-2022)“…The synthesis of luminescent molecular crystalline materials requires a good understanding of the luminescence properties of crystals in which many molecules…”
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Spin Crossover between the High-Spin and Low-Spin States and Dielectric Switching in the Ionic Crystals of a Fe(II) [2 × 2] Molecular Grid
Published in Bulletin of the Chemical Society of Japan (2020)“…We synthesized an Fe(II) [2 × 2] molecular grid with pyridyl-substituted bis-terdentate ligands. The molecular grid showed abrupt spin crossover between fully…”
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Structural Phase Transitions of a Molecular Metal Oxide
Published in Angewandte Chemie International Edition (07-12-2020)“…The structural phase of a metal oxide changes with temperature and pressure. During phase transitions, component ions move in multidimensional metal–oxygen…”
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Synthesis, Characterization, and Structure of a Reduced Preyssler-type Polyoxometalate
Published in Chemistry letters (2017)“…We report the synthesis of a reduced Preyssler-type polyoxometalate (POM), using Ag-containing POM. Both parent and reduced clusters were obtained in the…”
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Construction of a novel multi-gene assay (42-gene classifier) for prediction of late recurrence in ER-positive breast cancer patients
Published in Breast cancer research and treatment (01-08-2018)“…Purpose Prediction models for late (> 5 years) recurrence in ER-positive breast cancer need to be developed for the accurate selection of patients for extended…”
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Structural Phase Transition Behavior Observed for a Single Crystal of the Tetrabutylammonium Salt of a Mo18 Polyoxometalate
Published in European journal of inorganic chemistry (31-01-2019)“…Ionic single crystals of the polyoxometalate [MoV2MoVI16O54(SO3)2]6– salted with tetrabutylammonium were found to exhibit dielectric anomalies at 235 and 302…”
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Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring-Shaped Polyoxometalate Cluster
Published in Angewandte Chemie (International ed.) (02-11-2009)“…Functional inner space: A gigantic ring‐shaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA)…”
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Endocrine sensitivity of estrogen receptor‐positive breast cancer is negatively correlated with aspartate‐β‐hydroxylase expression
Published in Cancer science (01-12-2017)“…Although prognostic markers for early estrogen receptor (ER)‐positive breast cancer have been extensively developed, predictive markers for adjuvant endocrine…”
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13
Shrinkable muscular crystal with chemical logic gates driven by external ion environment
Published in Communications materials (16-10-2024)“…Biomimetic chemical logic gates that can reversibly transform their shape and physical properties in response to their environment are an important research…”
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Construction of multi-gene classifier for prediction of response to and prognosis after neoadjuvant chemotherapy for estrogen receptor positive breast cancers
Published in Cancer letters (01-09-2015)“…Highlights • Metabolic pathways were found to be involved in sensitivity to neoadjuvant chemotherapy (NAC) in ER+ breast cancer. • Prediction model (MPCP155)…”
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Multi-gene assay 95- and 155-gene classifiers for prognosis prediction and chemotherapy omission in lymphnode positive luminal-type breast cancer
Published in Cancer treatment and research communications (01-01-2023)“…•95GC/155GC can predict prognosis of lymph node-positive luminal-type breast cancer.•Prognosis analysis was done on lymph node-positive endocrine only luminal…”
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Supramolecular Silver Polyoxometalate Architectures Direct the Growth of Composite Semiconducting Nanostructures
Published in Angewandte Chemie International Edition (01-01-2009)“…Nanosilver on a string: Crystalline silver polyoxovanadate supramolecular architectures are employed as precursors for the synthesis of composite nanowires…”
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Development of 95-gene classifier as a powerful predictor of recurrences in node-negative and ER-positive breast cancer patients
Published in Breast cancer research and treatment (01-08-2011)“…Our aim was to develop an accurate diagnostic system using gene expression analysis by means of DNA microarray for prognosis of node-negative and estrogen…”
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A giant esophageal liposarcoma radically resected by the cervical approach: a case report
Published in Clinical journal of gastroenterology (01-02-2022)“…Primary esophageal liposarcoma is an extremely rare malignancy, whereas liposarcoma is one of the most common soft tissue sarcomas, which develop mainly in the…”
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Conductive Nanoscopic Fibrous Assemblies Containing Helical Tetrathiafulvalene Stacks
Published in Chemistry, an Asian journal (01-09-2009)“…Tetrathiafulvalenes (TTF) S‐TTF and R‐TTF having four chiral amide end groups self‐organize into helical nanofibers in the presence of…”
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Heterocyclic bismuth carboxylates based on a diphenyl sulfone scaffold: Synthesis and antifungal activity against Saccharomyces cerevisiae
Published in European journal of medicinal chemistry (01-05-2013)“…A series of heterocyclic organobismuth(III) carboxylates 4 and 5 [RCO2Bi(C6H4-2-SO2C6H4-1′-)] derived from diphenyl sulfone was synthesized to determine the…”
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